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Test: MCAT Physical
Boiling point is the temperature a liquid needs to achieve in order to begin its transformation into a gaseous state. Campers and hikers who prepare food during their trips have to account for differences in atmospheric pressure as they ascend in elevation. During the ascent, the decrease in atmospheric pressure changes the temperature at which water boils.
Further complicating the matter is the observation that addition of a solute to a pure liquid also changes the boiling point. Raoult’s Law can be used to understand the changes in boiling point if a non-volatile solute is present, as expressed here.
In this law, is the mole fraction of the solvent,
is the vapor pressure of the pure solvent, and
is the vapor pressure of the solution. When this vapor pressure is equal to the local atmospheric pressure, the solution boils.
| 3. | A scientist is testing Raoult's Law, but accidently adds a volatile solute instead of a non-volatile solute. Which of the following is true? |
Vapor pressure must decrease compared to the pure solvent
Vapor pressure will remain unchanged compared to the pure solvent
A volatile solute will not dissolve into solution
Vapor pressure may either increase or decrease compared to the pure solvent
Vapor pressure must increase compared to the pure solvent