### All MCAT Physical Resources

## Example Questions

### Example Question #6 : Physical Chemistry

A cubical block has a mass of and a density of . Which of the following values most closely approximates the height of the block?

**Possible Answers:**

**Correct answer:**

To solve this question, you need to know the definition of density:

The question gives us the mass of the block and the density of the block. We can use these values to solve for the volume of the block.

Density has to be converted from to (SI units). Recall that ; therefore, .

Solving for volume of the block gives us:

A liter is defined as ; therefore, .

Remember that the volume of a cube is calculated as follows:

Since the cube has the same length, width, and height, the equation above can be rewritten in terms of height as follows:

This means that the height of the cube can be calculated by taking the cube root of volume:

The length, the width, and the height of this cubical block is .

### Example Question #7 : Physical Chemistry

Which of the following is true regarding the density of solids?

**Possible Answers:**

Solid water has a higher density than liquid water

Solids usually have greater density than liquids because they have larger volumes

Density of a solid can be calculated by dividing the weight of the solid by the volume of the solid

A sample of a substance in its solid phase will have the same mass as the same sample in its liquid phase

**Correct answer:**

A sample of a substance in its solid phase will have the same mass as the same sample in its liquid phase

Density is defined as mass divided by volume. Recall that the solid phase is usually characterized by tightly packed molecules. As a result, solids usually take up less volume than liquids and, consequently, have greater densities than liquids.

The most common exception to this rule is water. Liquid water has a density of , whereas solid water (ice) has a density of .

Density of any substance (solid or liquid) is calculated as follows:

is density of the substance, is mass, and is volume. The density of a substance does not depend on the weight of the object.

Changing a substance from its solid phase to its liquid phase only alters volume; it does not change the mass. Remember that the mass of a substance depends on the amount of molecules. Changing from solid to liquid will increase the spacing between the molecules (volume), but it will not change the amount of molecules (mass); therefore, the solid phase and the liquid phase of a sample of substance will have the same mass.

### Example Question #8 : Physical Chemistry

What will happen to the density of iron if you increase the temperature to its melting point?

**Possible Answers:**

The density will decrease because the mass will decrease

The density will decrease because the volume will increase

The density will increase because the mass will increase

The density will increase because the volume will decrease

**Correct answer:**

The density will decrease because the volume will increase

Increasing a substance’s temperature to its melting point will convert the substance from a solid to a liquid. This will increase the volume of the substance because the molecules within the substance will be farther apart from each other; however, the amount of molecules (mass of the substance) will remain unchanged.

Recall the definition of density:

Since the volume increases and the mass stays the same, the density of iron will decrease when you change the temperature to its melting point.

### Example Question #9 : Physical Chemistry

Consider the following factors:

I. Temperature

II. Pressure

Which of these two factors will alter the density of a substance?

**Possible Answers:**

Only II because it changes the mass of the substance

Both I and II because both change the volume of the substance

Both I and II because I changes the volume and II changes the mass of the substance

Only I because it changes the volume of the substance

**Correct answer:**

Both I and II because both change the volume of the substance

Density is defined as follows:

To alter density, we need to alter mass and/or volume. Remember that mass can only be altered by removing from or adding to the sample. Temperature and pressure do not change the amount of substance; therefore, they do not alter the mass of the substance.

Changing temperature will alter the distance between the molecules within the substance. Increasing the temperature will increase the distance between the molecules, which will increase the volume taken up by the substance. Similarly, decreasing the temperature will decrease the distance between the molecules, which will decrease the volume taken up by the substance. This means that changing temperature will alter the volume of the substance and, subsequently, the density of the substance.

Applying pressure also changes the distance between the molecules. Increasing the pressure will force the molecules to be closer together, whereas decreasing the pressure will enable the molecules to spread and separate from each other; therefore, pressure also alters density by changing the volume of the substance.

### Example Question #10 : Physical Chemistry

Consider a horizontal tube that has a length of and a diameter of . You stretch this tube by applying of force on each end of the tube. What is happening to the tube when you are applying the force?

**Possible Answers:**

The tube is experiencing a stress of and is undergoing tension

The tube is experiencing a stress of and is undergoing compression

The tube is experiencing a stress of and is undergoing compression

The tube is experiencing a stress of and is undergoing tension

**Correct answer:**

The tube is experiencing a stress of and is undergoing tension

To answer this question, you need to solve for the stress experienced by the tube. Stress is defined as:

Since this is a tube, the area we are concerned with is the circular cross-sectional area of the tube. The question states that the diameter is . This means that the radius (which is half the length of the diameter) is . Recall that meters is the SI unit for distance; therefore, we need to convert the radius to meters:

This means that the radius of the tube, in meters, is . The area of a circle is:

Using this formula and our radius, we can find the cross-sectional area:

The stress experienced by the tube is:

The closest answer choice is .

The question states that the tube is being stretched by the force. This means that the tube is undergoing tension because you are pulling the tube and applying a force outwards. If the force was applied in the opposite direction (inwards), then the tube would be undergoing compression (the tube would shorten).

### Example Question #11 : Physical Chemistry

The strain on an object __________ when initial length is increased and __________ when final length is increased.

**Possible Answers:**

increases . . . increases

increases . . . decreases

decreases . . . increases

decreases . . . decreases

**Correct answer:**

decreases . . . increases

Strain of an object is defined as:

is the final length and is the initial length. The equation implies that increasing the initial length of an object () would decrease the strain. Similarly, the equation also implies that increasing the final length of an object () would increase the strain; therefore, increasing the initial length decreases strain, whereas increasing the final length increases strain.

### Example Question #12 : Physical Chemistry

Which of the following will result in the greatest increase in length of a rubber band at its maximum stretch point, as compared to an unaltered control?

Assume the rubber band will experience the same constant force.

**Possible Answers:**

Using a rubber band that is twice as long and is twice as elastic

Using a rubber band that has half the length

Using a rubber band that has twice the cross-sectional area

Using a rubber band that is twice as elastic

**Correct answer:**

Using a rubber band that is twice as elastic

To answer this question, we need to know the equation for Young’s modulus, :

Recall the definitions of stress and strain:

Here, is force, is cross-sectional area, is change in length, and is initial length. Plugging these two equations into the definition of Young’s modulus gives us:

Rearranging this equation to solve for change in length gives us:

Since we want to increase we look for answer choices that increase and , or decrease and . Among the answer choices, the greatest increase occurs when you double the elasticity of the rubber band. Recall that Young’s modulus is a measure of the stiffness of a material; therefore, a more elastic (flexible, or less stiff) material will lower Young’s modulus. Having a material twice as elastic will decrease by one half and will give the greatest increase in the change in length of the rubber band.

Using half the length () and using twice the cross-sectional area will decrease the change in length. Using a rubber band twice as long, but twice as elastic, will not alter the change in length.

### Example Question #13 : Physical Chemistry

Which of the following is **false** regarding Young’s modulus?

**Possible Answers:**

Young’s modulus is defined as the slope of the stress vs. strain plot

Young’s modulus increases as stress increases

Young’s modulus is only valid for certain stresses

Young’s modulus has the same units as stress

**Correct answer:**

Young’s modulus increases as stress increases

Young’s modulus is a constant that is calculated by generating a stress vs. strain plot. The slope of the linear region of the stress vs. strain plot is defined as the Young’s modulus. Recall that the stress vs. strain plot is nonlinear past the elastic limit (stress at which the material starts to plastically deform). This means that we cannot calculate the slope past the elastic limit; Young’s modulus is invalid for stresses beyond the elastic limit.

Young’s modulus is defined as follows:

To calculate strain, you divide change in length by initial length. Since both change in length and initial length have the same units, the units cancel and strain becomes a dimensionless quantity. This means that the Young’s modulus will have the same units as stress alone.

Young’s modulus is a material property. This means that the Young’s modulus is constant for a given type of material. It does not depend on the stress experienced by the material. Any changes to stress will be compensated for by a change in strain, which will allow Young’s modulus to be constant for the material. Similarly, Young’s modulus does not depend on strain or on the geometrical properties (length and area) of the material. It will only change if you change the type of material being used.

### Example Question #1 : Phase Changes

A scientist prepares an experiment to demonstrate the second law of thermodynamics for a chemistry class. In order to conduct the experiment, the scientist brings the class outside in January and gathers a cup of water and a portable stove.

The temperature outside is –10 degrees Celsius. The scientist asks the students to consider the following when answering his questions:

Gibbs Free Energy Formula:

ΔG = ΔH – TΔS

Liquid-Solid Water Phase Change Reaction:

H_{2}O(l) ⇌ H_{2}O(s) + X

The scientist prepares two scenarios.

Scenario 1:

The scientist buries the cup of water outside in the snow, returns to the classroom with his class for one hour, and the class then checks on the cup. They find that the water has frozen in the cup.

Scenario 2:

The scientist then places the frozen cup of water on the stove and starts the gas. The class finds that the water melts quickly.

After the water melts, the scientist asks the students to consider two hypothetical scenarios as a thought experiment.

Scenario 3:

Once the liquid water at the end of scenario 2 melts completely, the scientist turns off the gas and monitors what happens to the water. Despite being in the cold air, the water never freezes.

Scenario 4:

The scientist takes the frozen water from the end of scenario 1, puts it on the active stove, and the water remains frozen.

Which of the following are possible quantities for the “X” present on the right side of the Liquid-Solid Water Phase Change Reaction?

I. Entropy

II. Heat

III. Water Vapor

**Possible Answers:**

II only

I only

I and II

I, II, and III

I and III only

**Correct answer:**

II only

As water freezes, it releases heat into the universe to balance the local loss of entropy encountered by ordering atoms into a rigid solid structure. Entropy, in contrast, is not a commodity that can be released by a reaction in the same way as heat. Also, water vapor would not be released on only one side of the equation. Water vapor would exist with in equilibrium with both solid and liquid, but would not appear as an additional product with the solid phase in this reaction.

### Example Question #1 : Thermodynamics Of Phase Changes

of energy is added to a sample, which undergoes a phase change from liquid to gas as a result. The temperature remains constant throughout the process. What does the quantity represent?

**Possible Answers:**

Enthalpy of vaporization

Specific heat of vaporization

Specific heat capacity

Heat of vaporization

**Correct answer:**

Specific heat of vaporization

The energy required to cause a liquid-gas phase change is called the heat of vaporization, and is usually given in the units of kilojoules per mole. Enthalpy of vaporization and heat of vaporization are the same quantity.

When the heat of vaporization is given for a single gram of substance, with the units of Joules per gram, it is termed the specific heat of vaporization. This is the quantity given in the question: the energy required to vaporize exactly one gram of the sample.

Specific heat capacity refers to the energy needed to raise the temperature of one gram of a sample by one degree Celsius.

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