Properties of Liquids - Physical Chemistry

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Question

Which of the following are responsible for the high boiling point of water, compared to molecules of similar size?

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Answer

Hydrogen bonding occurs between water molecules. While intermolecular forces between molecules exist for most molecules, these forces are much weaker than the bond formed between a hydrogen from one molecule and an oxygen, fluorine, and/or nitrogen atom of another molecule. Since the molecules are held more tightly together, more energy is required to break those bonds. This results in a higher temperature required to boil water (boiling breaks bonds between molecules, and this causes the molecules to escape into the gas phase).

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