Oxidation-Reduction Fundamentals - Physical Chemistry

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Question

Which of the following periodic table groups typically undergo reduction reactions?

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Answer

Reduction reactions are characterized by a gain of electrons whereas oxidation reactions are characterized by a loss of electrons. Recall that elements on the right side of the periodic table have the tendency to gain electrons to complete the octet. Groups such as chalcogens (group VI) and halogens (group VII) have six and seven valence electrons, respectively; therefore, they only need a few electrons to have eight valence electrons and complete the octet. Since halogens tend to gain electrons, they typically undergo reduction.

Alkaline earth metals (group II) and transition metals have few valence electrons; therefore, they tend to lose electrons and undergo oxidation. Noble gases are nonreactive elements and do not undergo reduction or oxidation.

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