Gibbs Free Energy - Physical Chemistry

Card 1 of 16

0
Didn't Know
Knew It
0
1 of 1615 left
Question

For Constant Temperature, Gibbs Free Energy is defined as:

Where , is the change in Gibbs Free Energy, is the change in enthalpy, is temperature, and is the change in entropy.

Which of the following scenarios is not possible?

Tap to reveal answer

Answer

The following condition is not possible:

This is because if enthalpy is positive, and entropy is negative, the negative sign in front of the temperature term in the formula becomes positive. Addition of 2 positive numbers can not be negative. Plugging in arbitrary numbers into the other conditions can show they are all possible.

Take the following condition:

Then Gibbs free energy can either be positive or negative, depending on the magnitude of enthalpy, entropy, and temperature. (If enthalpy is much larger than entropy and temperature, then the difference will be positive, but if entropy * is greater than the enthalpy, then the difference will be negative).

← Didn't Know|Knew It →