Using Other Organic Reducing Agents

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Organic Chemistry › Using Other Organic Reducing Agents

Questions 1 - 5
1

Which of the following is not a reducing agent?

Explanation

is not a reducing agent; peroxides (compounds with the formula R-O-O-R) are oxidizing agents. A very common peroxide is sodium peroxide .

All of the other listed compounds are reducing agents.

2

Which reagents reduce alkynes to trans alkenes?

Meta-Chloroperoxybenzoic acid

Explanation

produces a trans-alkene from an alkyne whereas produces a cis-alkene. reduces an alkyne all the way down to an alkane. is a strong oxidizing agent.

3

Img 0688

Identify the major product of the pictured reaction. Assume workup.

1. Img 0691

2. Img 0692

3. Img 0689

4. Img 0690

Explanation

This is a standard organolithium reaction.

The organolithium product can be thought of as a strong nucleophile. The carbon steals an electron from the lithium to create . From there, the highly reactive carbo-anion is free to attack the ketone at the site of its carbon to form a tertiary alcohol on the cyclohexane.

Img 0693

4

Which of the following compounds is not an oxidizing agent?

Explanation

is the only answer choice that is not an oxidizing agent. In fact, it is a reducing agent because of the lack of oxygen atoms present. This compound adds hydrogen atoms to a compound, thereby reducing it.

5

Screen shot 2015 12 29 at 7.06.21 pm

Which of the following would be the product of the reaction given?

Screen shot 2015 12 29 at 7.06.40 pm

Screen shot 2015 12 29 at 7.06.36 pm

Screen shot 2015 12 29 at 7.06.25 pm

Screen shot 2015 12 29 at 7.06.29 pm

Explanation

Alkenes can be reduced in the presence of and a metal catalyst like platinum to hydrogenate the alkene to give a saturated alkane. The reaction occurs in a heterogeneous solution rather than a homogenous solution. It occurs on the presence of a solid surface of the metal catalyst.

Note that the three carbon-carbon double bonds in the aromatic ring in the presence of the reducing agent does not get reduced because they are extremely stable due to resonance.

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