Molecules vs Crystal Structures
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Middle School Physical Science › Molecules vs Crystal Structures
A model of quartz (SiO$_2$) shows silicon and oxygen atoms connected in a repeating pattern that continues in all directions, with no clear “one molecule” unit you can circle and count. What is the best conclusion?
Quartz is a molecular substance made of separate SiO$_2$ molecules floating apart.
Quartz must be a gas because it does not have separate molecules.
Quartz is made of separate NaCl units arranged in a pattern.
Quartz is an extended (crystal) structure; SiO$_2$ tells the ratio of atoms in the network, not a single molecule.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. For quartz: Quartz (SiO₂) is an extended structure where silicon and oxygen atoms form a continuous 3D network—there's no such thing as 'one SiO₂ molecule' because each silicon is bonded to oxygens and each oxygen to silicons in a pattern extending throughout the crystal, so the formula SiO₂ just tells us the 1:2 ratio; this contrasts with molecular substances like CO₂ where each molecule is a discrete O=C=O unit separate from others. Choice B is correct because it correctly categorizes the substance based on its structure type. Choice A incorrectly reverses the structure types, calling the molecular substance an extended structure or vice versa. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
Which list contains only molecular substances (made of discrete molecules), not extended crystal structures?
NaCl, Cu (metal), SiO$_2$ (quartz)
NaCl, H$_2$O, O$_2$
Diamond (C), CO$_2$, NaCl
H$_2$O, CO$_2$, O$_2$
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. For water vs salt: Water exists as individual H₂O molecules—you can see separate molecules in the liquid or gas, and each molecule has exactly 2 H atoms bonded to 1 O atom, forming discrete units that can move independently; Salt (NaCl), however, is an extended structure where sodium ions (Na⁺) and chloride ions (Cl⁻) alternate in a continuous 3D pattern—there's no such thing as 'one NaCl molecule' because every sodium is surrounded by chlorides and every chloride by sodiums in a network extending throughout the crystal, so the formula NaCl just tells us the 1:1 ratio; similarly, diamond (C) is an extended carbon network, while CO₂ and O₂ are molecular. Choice A is correct because it lists only molecular substances: H₂O, CO₂, O₂, all with discrete molecules. Choice D incorrectly includes extended structures like NaCl, Cu (metal lattice), and SiO₂ (quartz network) as if they were molecular. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
A model of solid table salt shows Na$^+$ and Cl$^-$ ions arranged in a repeating pattern. There are no separate “NaCl molecules” drawn—just the pattern continuing.
Why can you not count “one NaCl molecule” inside the salt crystal the way you can count one H$_2$O molecule in water vapor?
Because water vapor is a crystal lattice, but salt is made of separate molecules.
Because the salt crystal is a continuous repeating network of ions, not separate NaCl molecules.
Because NaCl contains no atoms, only energy.
Because H$_2$O has no fixed formula, but NaCl does.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. Choice A is correct because it properly explains the key difference: you cannot count individual NaCl molecules in salt because it is a continuous network, unlike discrete H₂O molecules in vapor. Choice B is incorrect because it reverses the structure types, calling water vapor a crystal lattice and salt separate molecules. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
Two students describe a substance:
Student 1: “It is made of identical groups of atoms, and each group stays together as a unit. There is space between the groups.”
Student 2: “It is made of atoms/ions bonded in a repeating pattern that continues throughout the solid, so there are no separate units.”
Which student is describing a molecular substance, and which is describing an extended crystal structure?
Student 1: extended crystal; Student 2: molecular substance.
Student 1: molecular substance; Student 2: extended crystal structure.
Both students are describing extended crystal structures.
Both students are describing molecular substances.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. Choice B is correct because it accurately identifies that molecules are discrete countable units while extended structures are continuous networks, correctly categorizing Student 1 as describing molecular (separate groups with space) and Student 2 as extended (continuous pattern with no separate units). Choice D is incorrect because it claims both students are describing extended crystal structures, when Student 1 clearly describes separate units typical of molecular substances. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
A student says: “NaCl is one molecule made of 1 sodium atom and 1 chlorine atom, just like H$_2$O is one molecule.”
Which statement best corrects the student using the idea of molecules vs. extended crystal structures?
H$_2$O is an extended lattice, but NaCl is made of small molecules.
Both NaCl and H$_2$O are always extended networks, so neither has individual molecules.
NaCl usually forms an extended crystal lattice of Na$^+$ and Cl$^-$ ions; NaCl shows a ratio, not a single molecule like H$_2$O.
NaCl is made of separate NaCl molecules floating around with space between them, like water vapor.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. Choice A is correct because it properly explains the key difference: separated molecules vs bonded-throughout crystal, correctly categorizing NaCl as an extended ionic lattice with a ratio and H₂O as discrete molecules. Choice B is incorrect because it claims you can count individual molecules in salt when actually salt is a continuous network with no discrete molecules. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
Which substance is best described as an extended crystal structure (a continuous repeating pattern with no separate molecules)?
Table salt, NaCl
Water vapor, H$_2$O
Carbon dioxide, CO$_2$
Oxygen gas, O$_2$
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. For water vs salt: Water exists as individual H₂O molecules—you can see separate molecules in the liquid or gas, and each molecule has exactly 2 H atoms bonded to 1 O atom, forming discrete units that can move independently; Salt (NaCl), however, is an extended structure where sodium ions (Na⁺) and chloride ions (Cl⁻) alternate in a continuous 3D pattern—there's no such thing as 'one NaCl molecule' because every sodium is surrounded by chlorides and every chloride by sodiums in a network extending throughout the crystal, so the formula NaCl just tells us the 1:1 ratio. Choice C is correct because it correctly categorizes table salt (NaCl) as an extended crystal structure based on its continuous ionic lattice. Choice A incorrectly claims oxygen gas (O₂), which is made of discrete O₂ molecules, is an extended structure. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
Two particle models are shown.
Model 1: Several separate groups shaped like a “V”, each group has 3 atoms labeled H–O–H, and the groups are not connected to each other.
Model 2: A repeating checkerboard pattern of circles labeled Na$^+$ and Cl$^-$ that continues in all directions, with each Na$^+$ touching several Cl$^-$.
Which statement correctly identifies the structure types shown in Model 1 and Model 2?
Model 1 is made of separate molecules; Model 2 is an extended crystal structure (lattice).
Model 1 is an extended crystal network; Model 2 is made of separate molecules.
Both models show continuous networks with no discrete units.
Both models show separate molecules that can be counted.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. For water vs salt: Water exists as individual H₂O molecules—you can see separate molecules in the liquid or gas, and each molecule has exactly 2 H atoms bonded to 1 O atom, forming discrete units that can move independently, as shown in Model 1 with separate H–O–H groups; Salt (NaCl), however, is an extended structure where sodium ions (Na⁺) and chloride ions (Cl⁻) alternate in a continuous 3D pattern—there's no such thing as 'one NaCl molecule' because every sodium is surrounded by chlorides and every chloride by sodiums in a network extending throughout the crystal, so the formula NaCl just tells us the 1:1 ratio, as in Model 2 with the repeating checkerboard. Choice B is correct because it accurately identifies that Model 1 (water) is made of separate molecules while Model 2 (salt) is an extended crystal structure (lattice). Choice A incorrectly reverses the structure types, calling the molecular substance (Model 1) an extended crystal network and the extended structure (Model 2) made of separate molecules. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
Two models are shown.
Model A: Several separate ring-shaped groups labeled C, H, and O (each group represents one sugar molecule), and the groups do not connect to each other.
Model B: A solid made of identical circles packed in a repeating pattern, each circle is labeled Cu, and the pattern continues across the whole piece.
Which statement correctly matches each model to “molecular substance” or “extended structure”?
Model A and Model B are both molecular substances because they contain atoms.
Model A is a molecular substance (separate molecules); Model B is an extended structure (metal lattice).
Model A is an extended structure; Model B is a molecular substance.
Model A is an ionic lattice; Model B is separate Cu molecules.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. For water vs salt: Water exists as individual H₂O molecules—you can see separate molecules in the liquid or gas, and each molecule has exactly 2 H atoms bonded to 1 O atom, forming discrete units that can move independently, similar to Model A with separate sugar molecules; Salt (NaCl), however, is an extended structure where sodium ions (Na⁺) and chloride ions (Cl⁻) alternate in a continuous 3D pattern—there's no such thing as 'one NaCl molecule' because every sodium is surrounded by chlorides and every chloride by sodiums in a network extending throughout the crystal, so the formula NaCl just tells us the 1:1 ratio, while for metals like Cu in Model B, it's a lattice of copper atoms in a repeating pattern. Choice C is correct because it correctly categorizes Model A (sugar) as a molecular substance with separate molecules and Model B (Cu metal) as an extended structure (metal lattice). Choice D incorrectly describes Model A as an ionic lattice and Model B as separate Cu molecules, when Cu is a continuous metallic network and sugar is molecular. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
A student says, “NaCl is one molecule made of 1 sodium atom bonded to 1 chlorine atom.”
Which statement best corrects the student using the idea of molecular vs crystal structures?
NaCl is a continuous network of H$_2$O molecules with sodium and chlorine mixed in.
NaCl cannot form a repeating pattern because crystals only form from molecules.
NaCl is an extended ionic lattice; the formula NaCl shows a 1:1 ratio of Na$^+$ to Cl$^-$, not one discrete molecule.
NaCl is made of separate NaCl molecules, and each molecule is easy to count in the solid.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like H₂O with 2 hydrogen and 1 oxygen), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like NaCl for table salt) gives the ratio of atoms or ions, not the composition of one separate molecule. For water vs salt: Water exists as individual H₂O molecules—you can see separate molecules in the liquid or gas, and each molecule has exactly 2 H atoms bonded to 1 O atom, forming discrete units that can move independently; Salt (NaCl), however, is an extended structure where sodium ions (Na⁺) and chloride ions (Cl⁻) alternate in a continuous 3D pattern—there's no such thing as 'one NaCl molecule' because every sodium is surrounded by chlorides and every chloride by sodiums in a network extending throughout the crystal, so the formula NaCl just tells us the 1:1 ratio. Choice B is correct because it properly explains the key difference: NaCl is an extended ionic lattice with the formula representing a ratio, not a discrete molecule. Choice A incorrectly claims NaCl is made of separate NaCl molecules that can be counted, when actually it's a continuous network. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.
A sample of oxygen gas is made of O$_2$ units moving around with space between them. A sample of diamond is made of carbon atoms bonded in a repeating network that extends throughout the solid.
What is the main structural difference between oxygen gas and diamond?
Diamond is made of O$_2$ molecules packed tightly, while oxygen gas is made of single carbon atoms.
Both oxygen gas and diamond are made of separate molecules that can be counted easily.
Oxygen gas is a continuous network, but diamond is made of separate molecules.
Oxygen gas is made of discrete molecules (O$_2$); diamond is a continuous network with no individual molecules to count.
Explanation
This question tests understanding of the important distinction between molecular substances (made of discrete individual molecules) and extended structures like crystals (continuous networks of atoms or ions). Molecular substances are composed of separate individual molecules, where each molecule is a specific group of atoms bonded together (like O₂ with 2 oxygen atoms), and these molecules are separated from each other by space—you can identify and count individual molecules (one molecule, two molecules, three molecules) because they exist as discrete units. Extended structures like crystals, on the other hand, are continuous networks where atoms or ions are bonded to their neighbors in a repeating pattern that extends throughout the entire substance with no discrete molecules to count—the formula (like C for diamond) gives the ratio of atoms, not the composition of one separate molecule. Choice B is correct because it accurately identifies that molecules are discrete countable units while extended structures are continuous networks, correctly categorizing oxygen gas as discrete O₂ molecules and diamond as a continuous carbon network. Choice A is incorrect because it reverses the structure types, calling the molecular substance (oxygen gas) a continuous network and the extended structure (diamond) separate molecules. To distinguish molecular from extended structures, ask these questions: (1) Can you identify and count individual molecules? (yes → molecular, no → extended), (2) Are there distinct separate groups of bonded atoms? (yes → molecular, no → extended), (3) Does the formula represent one molecule's composition or just a ratio? (composition → molecular, ratio → extended). Examples to remember: molecular substances include most gases (O₂, CO₂, N₂), many liquids (water H₂O, gasoline), and some solids (sugar, ice - though ice is crystalline arrangement of molecules); extended structures include table salt (NaCl network), diamond and graphite (carbon networks), most metals (metal atom networks), and sand/quartz (SiO₂ network)—the structure type affects properties like melting point (crystals often higher due to continuous bonding), state at room temperature, and how the substance dissolves or breaks apart.