Identify Limiting Reactants
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Chemistry › Identify Limiting Reactants
Magnesium oxide forms according to $$2\text{Mg} + \text{O}_2 \rightarrow 2\text{MgO}$$. If $6.0 \text{ mol}$ of Mg and $2.0 \text{ mol}$ of $\text{O}_2$ react, which reactant is in excess (left over after the reaction stops)?
Neither is in excess; both are completely consumed.
Both are in excess because products form before reactants are used up.
$\text{O}_2$ is in excess.
Mg is in excess.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). To identify limiting reactant, you must compare what you HAVE (given moles) to what you NEED (calculated from mole ratios) for each reactant: for each reactant, use the mole ratio from the balanced equation to calculate how much of it would be needed if another reactant reacted completely. Whichever reactant you don't have enough of (need more than available) is the limiting reactant! For example, in $$2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}$$ with $3$ moles $\text{H}_2$ and $1$ mole $\text{O}_2$: if all the $\text{O}_2$ reacts ($1$ mole), you'd need $2$ moles $\text{H}_2$ (from $2:1$ ratio), and you have $3$ moles $\text{H}_2$—enough! But if all the $\text{H}_2$ reacts ($3$ moles), you'd need $1.5$ moles $\text{O}_2$ (from $2:1$ ratio), and you only have $1$ mole $\text{O}_2$—NOT enough! So $\text{O}_2$ is limiting. For $$2\text{Mg} + \text{O}_2 \rightarrow 2\text{MgO}$$ with $6.0$ mol Mg and $2.0$ mol $\text{O}_2$, dividing gives Mg:$6/2=3$ and $\text{O}_2$: $2/1=2$, so $\text{O}_2$ is limiting (smaller), meaning Mg is in excess. Choice A correctly identifies Mg as in excess by properly comparing the ratios showing $\text{O}_2$ runs out first. Choice C fails by assuming perfect consumption without checking the mole ratios, which reveal $\text{O}_2$ limits the reaction. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is LESS than available, that reactant is excess. If needed is MORE than available, that reactant is limiting. (5) Whichever reactant you run short on (need more than you have) is the limiting reactant! Alternative quick method: divide each available amount by its coefficient; the SMALLEST result identifies limiting reactant. Both methods work—pick whichever makes more sense to you. After identifying limiting reactant, ALWAYS use IT for product calculations, not the excess reactant! The limiting reactant determines the maximum product—keep up the great work!
Ammonia forms according to $$\text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3.$$ If $2.0\ \text{mol}$ of $\text{N}_2$ and $4.0\ \text{mol}$ of $\text{H}_2$ are available, which reactant is limiting?
$\text{H}_2$ is limiting because there is not enough to match the $1:3$ ratio.
$\text{N}_2$ is limiting because it has fewer moles than $\text{H}_2$.
Both reactants are limiting and run out at the same time.
$\text{N}_2$ is limiting because its coefficient is 1.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). To identify limiting reactant, you must compare what you HAVE (given moles) to what you NEED (calculated from mole ratios) for each reactant: for each reactant, use the mole ratio from the balanced equation to calculate how much of it would be needed if another reactant reacted completely. Whichever reactant you don't have enough of (need more than available) is the limiting reactant! For example, in $2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}$ with 3 moles of $\text{H}_2$ and 1 mole of $\text{O}_2$: if all the $\text{O}_2$ reacts (1 mole), you'd need 2 moles $\text{H}_2$ (from 2:1 ratio), and you have 3 moles $\text{H}_2$—enough! But if all the $\text{H}_2$ reacts (3 moles), you'd need 1.5 moles $\text{O}_2$ (from 2:1 ratio), and you only have 1 mole $\text{O}_2$—NOT enough! So $\text{O}_2$ is limiting. In this case, for $$\text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3$$ with 2.0 mol of $\text{N}_2$ and 4.0 mol of $\text{H}_2$, assuming all $\text{N}_2$ reacts requires 6.0 mol $\text{H}_2$, but only 4.0 mol is available (not enough), while assuming all $\text{H}_2$ reacts requires about 1.33 mol $\text{N}_2$, and 2.0 mol is available (enough), so $\text{H}_2$ is limiting. Choice B correctly identifies $\text{H}_2$ as the limiting reactant by properly comparing needed vs available amounts using mole ratios from the balanced equation. Choice C fails by assuming fewer moles alone determine the limiting reactant, ignoring the 1:3 ratio which shows $\text{H}_2$ is insufficient. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is LESS than available, that reactant is excess. If needed is MORE than available, that reactant is limiting. (5) Whichever reactant you run short on (need more than you have) is the limiting reactant! Example: $$\text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3$$ with 2 moles $\text{N}_2$, 5 moles $\text{H}_2$. If 2 moles $\text{N}_2$ reacts (reference), needs 6 moles $\text{H}_2$ (from 1:3 ratio). Have only 5 moles $\text{H}_2$ (not enough!). $\text{H}_2$ is limiting. Alternative quick method: divide each available amount by its coefficient. Example: 2 moles $\text{N}_2$ ÷ 1 = 2. 5 moles $\text{H}_2$ ÷ 3 = 1.67. The SMALLEST result identifies limiting reactant ($\text{H}_2$, with 1.67 < 2). This works because you're finding 'how many times can I run the reaction with each reactant?' Whichever gives the fewest runs is limiting! Both methods work—pick whichever makes more sense to you. After identifying limiting reactant, ALWAYS use IT for product calculations, not the excess reactant! The limiting reactant determines the maximum product—great job tackling this!
Aluminum chloride can form as: $$2\text{Al} + 3\text{Cl}_2 \rightarrow 2\text{AlCl}_3$$ If you have $4.0,\text{mol}$ of Al and $3.0,\text{mol}$ of $\text{Cl}_2$, which reactant will be completely consumed first?
$\text{Cl}_2$ will be completely consumed first
The reaction cannot proceed because there are two reactants
Al will be completely consumed first
They will be consumed at the same time
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). To identify limiting reactant, you must compare what you HAVE (given moles) to what you NEED (calculated from mole ratios) for each reactant: for each reactant, use the mole ratio from the balanced equation to calculate how much of it would be needed if another reactant reacted completely. Whichever reactant you don't have enough of (need more than available) is the limiting reactant! For example, in 2H2 + O2 → 2H2O with 3 moles H2 and 1 mole O2: if all the O2 reacts (1 mole), you'd need 2 moles H2 (from 2:1 ratio), and you have 3 moles H2—enough! But if all the H2 reacts (3 moles), you'd need 1.5 moles O2 (from 2:1 ratio), and you only have 1 mole O2—NOT enough! So O2 is limiting. With 4.0 mol Al and 3.0 mol Cl2, Cl2 is consumed first because assuming all Al reacts requires 6.0 mol Cl2 but only 3.0 mol is available, while assuming all Cl2 reacts requires 2.0 mol Al and 4.0 mol is available (ratios 2:3). Choice B correctly states Cl2 will be completely consumed first by using proper mole ratio comparisons. Choice A fails by wrongly assuming Al is consumed first, perhaps from miscounting the coefficients. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is LESS than available, that reactant is excess. If needed is MORE than available, that reactant is limiting. (5) Whichever reactant you run short on (need more than you have) is the limiting reactant! Example: N2 + 3H2 → 2NH3 with 2 moles N2, 5 moles H2. If 2 moles N2 reacts (reference), needs 6 moles H2 (from 1:3 ratio). Have only 5 moles H2 (not enough!). H2 is limiting. Alternative quick method: divide each available amount by its coefficient. Example: 2 moles N2 ÷ 1 = 2. 5 moles H2 ÷ 3 = 1.67. The SMALLEST result identifies limiting reactant (H2, with 1.67 < 2). This works because you're finding "how many times can I run the reaction with each reactant?" Whichever gives the fewest runs is limiting! Both methods work—pick whichever makes more sense to you. After identifying limiting reactant, ALWAYS use IT for product calculations, not the excess reactant! The limiting reactant determines the maximum product.
Aluminum oxide forms as $$4\text{Al} + 3\text{O}_2 \rightarrow 2\text{Al}_2\text{O}_3.$$ If you start with $12.0\ \text{mol}$ of Al and $6.0\ \text{mol}$ of $\text{O}_2$, which reactant is the limiting reactant?
Neither; both are limiting because there are two reactants.
Al, because $12/4 = 3$ and $6/3 = 2$, so Al is smaller.
$\text{O}_2$, because $12/4 = 3$ and $6/3 = 2$, so $\text{O}_2$ is smaller.
Al, because it has fewer moles than $\text{O}_2$ after dividing by 2.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). To identify limiting reactant, you must compare what you HAVE (given moles) to what you NEED (calculated from mole ratios) for each reactant: for each reactant, use the mole ratio from the balanced equation to calculate how much of it would be needed if another reactant reacted completely. Whichever reactant you don't have enough of (need more than available) is the limiting reactant! For example, in $2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}$ with 3 moles H2 and 1 mole O2: if all the O2 reacts (1 mole), you'd need 2 moles H2 (from 2:1 ratio), and you have 3 moles H2—enough! But if all the H2 reacts (3 moles), you'd need 1.5 moles O2 (from 2:1 ratio), and you only have 1 mole O2—NOT enough! So O2 is limiting. For $4\text{Al} + 3\text{O}_2 \rightarrow 2\text{Al}_2\text{O}_3$ with 12.0 mol Al and 6.0 mol O2, dividing gives Al: $12/4=3$ and O2: $6/3=2$ (smaller for O2), so O2 is limiting. Choice B correctly identifies O2 as the limiting reactant by properly comparing $12/4=3$ and $6/3=2$, with the smaller value indicating O2 limits. Choice A fails by reversing the conclusion despite the same calculations showing O2 is smaller. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is LESS than available, that reactant is excess. If needed is MORE than available, that reactant is limiting. (5) Whichever reactant you run short on (need more than you have) is the limiting reactant! Alternative quick method: divide each available amount by its coefficient; the SMALLEST result identifies limiting reactant. Both methods work—pick whichever makes more sense to you. After identifying limiting reactant, ALWAYS use IT for product calculations, not the excess reactant! The limiting reactant determines the maximum product—way to go!
Hydrogen chloride forms by $$\text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl}.$$ If $5.0\ \text{mol}$ of $\text{H}_2$ and $2.0\ \text{mol}$ of $\text{Cl}_2$ are mixed, which reactant will be completely consumed first?
$\text{Cl}_2$
$\text{H}_2$
Neither; both reactants are consumed at the same time.
$\text{HCl}$
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). To identify limiting reactant, you must compare what you HAVE (given moles) to what you NEED (calculated from mole ratios) for each reactant: for each reactant, use the mole ratio from the balanced equation to calculate how much of it would be needed if another reactant reacted completely. Whichever reactant you don't have enough of (need more than available) is the limiting reactant! For example, in $$2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}$$ with 3 moles of $\text{H}_2$ and 1 mole of $\text{O}_2$: if all the $\text{O}_2$ reacts (1 mole), you'd need 2 moles of $\text{H}_2$ (from 2:1 ratio), and you have 3 moles of $\text{H}_2$—enough! But if all the $\text{H}_2$ reacts (3 moles), you'd need 1.5 moles of $\text{O}_2$ (from 2:1 ratio), and you only have 1 mole of $\text{O}_2$—NOT enough! So $\text{O}_2$ is limiting. For $$\text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl}$$ with 5.0 mol of $\text{H}_2$ and 2.0 mol of $\text{Cl}_2$, dividing gives $\text{H}_2$:5/1=5 and $\text{Cl}_2$:2/1=2 (smaller), so $\text{Cl}_2$ is completely consumed first. Choice B correctly identifies $\text{Cl}_2$ as the limiting reactant by properly comparing the ratios. Choice A fails by ignoring the equal coefficients, where fewer moles of $\text{Cl}_2$ make it limit. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is LESS than available, that reactant is excess. If needed is MORE than available, that reactant is limiting. (5) Whichever reactant you run short on (need more than you have) is the limiting reactant! Alternative quick method: divide each available amount by its coefficient; the SMALLEST result identifies limiting reactant. Both methods work—pick whichever makes more sense to you. After identifying limiting reactant, ALWAYS use IT for product calculations, not the excess reactant! The limiting reactant determines the maximum product—excellent effort!
Carbon dioxide forms by combustion: $$\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}.$$ If you have $4.0\ \text{mol}$ of $\text{CH}_4$ and $6.0\ \text{mol}$ of $\text{O}_2$, what is the maximum amount of $\text{CO}_2$ that can form (in moles)?
$6.0\ \text{mol}$
$3.0\ \text{mol}$
$2.0\ \text{mol}$
$4.0\ \text{mol}$
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). To identify limiting reactant, you must compare what you HAVE (given moles) to what you NEED (calculated from mole ratios) for each reactant: for each reactant, use the mole ratio from the balanced equation to calculate how much of it would be needed if another reactant reacted completely. Whichever reactant you don't have enough of (need more than available) is the limiting reactant! For example, in $$2\text{H}_2 + \text{O}_2 \rightarrow 2\text{H}_2\text{O}$$ with 3 moles $\text{H}_2$ and 1 mole $\text{O}_2$: if all the $\text{O}_2$ reacts (1 mole), you'd need 2 moles $\text{H}_2$ (from 2:1 ratio), and you have 3 moles $\text{H}_2$—enough! But if all the $\text{H}_2$ reacts (3 moles), you'd need 1.5 moles $\text{O}_2$ (from 2:1 ratio), and you only have 1 mole $\text{O}_2$—NOT enough! So $\text{O}_2$ is limiting. Here, for $$\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}$$ with 4.0 mol $\text{CH}_4$ and 6.0 mol $\text{O}_2$, dividing gives CH4:4/1=4 and O2:6/2=3, so O2 is limiting (smaller value); maximum CO2 is 3.0 mol based on O2 (since 6 mol O2 produces 3 mol CO2 using the 2:1 O2:CO2 ratio). Choice B correctly identifies the maximum CO2 as 3.0 mol by properly determining O2 as limiting and calculating product from it. Choice C fails by likely using the excess reactant CH4 for calculation, which overestimates since O2 runs out first. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is LESS than available, that reactant is excess. If needed is MORE than available, that reactant is limiting. (5) Whichever reactant you run short on (need more than you have) is the limiting reactant! Alternative quick method: divide each available amount by its coefficient; the SMALLEST result identifies limiting reactant. Both methods work—pick whichever makes more sense to you. After identifying limiting reactant, ALWAYS use IT for product calculations, not the excess reactant! The limiting reactant determines the maximum product—you're doing awesome!
Hydrogen chloride forms by $,\text{H}_2 + \text{Cl}_2 \rightarrow 2\text{HCl},$. If you have $3.0\ \text{mol H}_2$ and $5.0\ \text{mol Cl}_2$, which reactant will be completely consumed first?
$\text{H}_2$ (it is limiting).
$\text{Cl}_2$ (it is limiting).
Both are consumed at the same time because the coefficients are 1 and 1.
Neither is consumed completely because the reaction can keep going.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). For the reaction H₂ + Cl₂ → 2HCl with 3.0 mol H₂ and 5.0 mol Cl₂: if all 3.0 mol H₂ reacts, it needs 3.0 mol Cl₂ (from the 1:1 ratio), and we have 5.0 mol Cl₂—plenty! If all 5.0 mol Cl₂ reacts, it needs 5.0 mol H₂ (from the 1:1 ratio), but we only have 3.0 mol H₂—not enough! So H₂ is limiting and will be consumed first. Choice A correctly identifies H₂ as the limiting reactant that will be completely consumed first. Choice C incorrectly assumes equal coefficients mean both are consumed simultaneously, but this only happens if the initial amounts match the stoichiometric ratio—here we have unequal amounts (3.0 vs 5.0). The limiting reactant identification method works even with 1:1 ratios—whichever reactant you have less of is limiting when coefficients are equal. Quick check: 3.0 mol H₂ ÷ 1 = 3.0, and 5.0 mol Cl₂ ÷ 1 = 5.0, so H₂ is limiting (smaller value). After H₂ is consumed, 2.0 mol Cl₂ will remain as excess.
Ammonia forms by $,\text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3,$. If you have $2.0\ \text{mol N}_2$ and $4.0\ \text{mol H}_2$, which reactant is limiting?
$\text{N}_2$ is limiting because the coefficient of $\text{N}_2$ is 1.
$\text{H}_2$ is limiting because $2.0\ \text{mol N}_2$ would require $6.0\ \text{mol H}_2$, but only $4.0\ \text{mol H}_2$ is available.
$\text{N}_2$ is limiting because it has fewer moles than $\text{H}_2$.
Neither is limiting because $\text{H}_2$ is in excess.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). For the reaction N₂ + 3H₂ → 2NH₃ with 2.0 mol N₂ and 4.0 mol H₂: if all 2.0 mol N₂ reacts, it needs 6.0 mol H₂ (from the 1:3 ratio), but we only have 4.0 mol H₂—not enough! So H₂ is limiting. If all 4.0 mol H₂ reacts, it needs 1.33 mol N₂ (from the 3:1 ratio), and we have 2.0 mol N₂—plenty! Choice B correctly identifies H₂ as limiting by calculating that 2.0 mol N₂ would require 6.0 mol H₂, but only 4.0 mol H₂ is available. Choice A incorrectly assumes the reactant with fewer moles is always limiting without considering the stoichiometric coefficients—H₂ needs three times as many moles as N₂. Alternative quick method: divide each available amount by its coefficient. 2.0 mol N₂ ÷ 1 = 2.0. 4.0 mol H₂ ÷ 3 = 1.33. The SMALLEST result identifies limiting reactant (H₂, with 1.33 < 2.0). This works because you're finding "how many times can I run the reaction with each reactant?" Whichever gives the fewest runs is limiting!
Carbon monoxide forms by $,2\text{C} + \text{O}_2 \rightarrow 2\text{CO},$. If you start with $3.0\ \text{mol C}$ and $2.0\ \text{mol O}_2$, which reactant is the limiting reactant?
$\text{C}$ is limiting because $2.0\ \text{mol O}_2$ would require $4.0\ \text{mol C$, but only $3.0\ \text{mol C}$ is available.}
$\text{O}_2$ is limiting because it has fewer moles than $\text{C}$.
$\text{C}$ is limiting because $3.0\ \text{mol C}$ would require $1.5\ \text{mol O}_2$ and there is enough $\text{O}_2$.
$\text{C}$ is limiting because it has fewer moles than $\text{O}_2$.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). For the reaction 2C + O₂ → 2CO with 3.0 mol C and 2.0 mol O₂: if all 3.0 mol C reacts, it needs 1.5 mol O₂ (from the 2:1 ratio), and we have 2.0 mol O₂—plenty! If all 2.0 mol O₂ reacts, it needs 4.0 mol C (from the 1:2 ratio), but we only have 3.0 mol C—not enough! So C is limiting. Choice D correctly identifies C as limiting by calculating that 2.0 mol O₂ would require 4.0 mol C, but only 3.0 mol C is available. Choice C makes an error by stating C is limiting but gives the wrong reasoning—it incorrectly says there's enough O₂ when actually C runs out because O₂ needs more C than available. The limiting reactant identification method: compare what you HAVE to what you NEED. Quick verification: 3.0 mol C ÷ 2 = 1.5, and 2.0 mol O₂ ÷ 1 = 2.0, so C is limiting (smaller value). With C limiting, only 1.5 mol O₂ will react, leaving 0.5 mol O₂ in excess.
Iron(III) oxide forms by $,4\text{Fe} + 3\text{O}_2 \rightarrow 2\text{Fe}_2\text{O}_3,$. If you have $8.0\ \text{mol Fe}$ and $4.0\ \text{mol O}_2$, which reactant is limiting?
$\text{O}_2$ is limiting because $8.0\ \text{mol Fe}$ would require $6.0\ \text{mol O}_2$, but only $4.0\ \text{mol O}_2$ is available.
$\text{Fe}$ is limiting because the coefficient 4 is larger than 3.
$\text{Fe}$ is limiting because it has more moles.
Both are limiting because they are not in a 1:1 ratio.
Explanation
This question tests your understanding of limiting reactants—the reactant that is completely consumed first in a reaction, thereby limiting the maximum amount of product that can form. When a reaction has multiple reactants with given amounts, usually one runs out before the others—this is the limiting reactant, and it determines how much product can possibly form because once it's gone, the reaction must stop even if other reactants remain (the excess reactants). For the reaction 4Fe + 3O₂ → 2Fe₂O₃ with 8.0 mol Fe and 4.0 mol O₂: if all 8.0 mol Fe reacts, it needs 6.0 mol O₂ (from the 4:3 ratio), but we only have 4.0 mol O₂—not enough! So O₂ is limiting. If all 4.0 mol O₂ reacts, it needs 5.33 mol Fe (from the 3:4 ratio), and we have 8.0 mol Fe—plenty! Choice B correctly identifies O₂ as limiting by calculating that 8.0 mol Fe would require 6.0 mol O₂, but only 4.0 mol O₂ is available. Choice C incorrectly focuses on coefficient size rather than the actual mole ratio calculation—the larger coefficient doesn't make that reactant limiting. The limiting reactant identification method: (1) Write the balanced equation and identify given amounts for each reactant. (2) Pick one reactant as reference—assume all of it reacts. (3) Calculate how much of each OTHER reactant would be needed for the reference reactant to completely react (use mole ratios). (4) Compare needed vs available for each: if needed is MORE than available, that reactant is limiting. Quick verification: 8.0 mol Fe ÷ 4 = 2.0, and 4.0 mol O₂ ÷ 3 = 1.33, so O₂ is limiting (smaller value).