Biochemistry › Hydrogen Bonds
Which molecule will not form hydrogen bonds?
Only nitrogen, oxygen, and fluorine can form hydrogen bonds since these three elements are very electronegative. Thus, their partial negative charge (and the presence of a lone pair of electrons) attracts a partially positive hydrogen atom. Carbon, on the other hand, is not very electronegative and thus cannot form hydrogen bonds.
Classically, covalent bonds are considered __________ bonds and hydrogen bonds are __________.
intramolecular . . . intermolecular
intramolecular . . . intramolecular
intermolecular . . . intermolecular
intermolecular . . . intramolecular
Covalent bonds occur between atoms within (or intra) molecules. This means that covalent bonds are intramolecular bonds. Hydrogen bonds, on the other hand, occur between hydrogen atoms of one molecule and either a nitrogen, an oxygen, or a fluorine atom in another molecule. Since hydrogen bonds occur between molecules, they are classified as intermolecular bonds. There are some situations in which hydrogen bonds may be formed intramolecularly, but these are special cases.
What is not true about hydrogen bonds?
Hydrogen bonds can be found between metals
Hydrogen bonds are found between water molecules
Hydrogen bonds are found in protein structure
Hydrogen bonds are found in DNA structure
Hydrogen bonds increase the boiling point of water
Hydrogen bonds are found in primary structure of protein, as well as between the bases in DNA structure. Hydrogen bonds are only found between hydrogens attached to oxygen, nitrogen, or fluorine. They increase the attraction between water molecules, therefore are harder to break in large numbers, causing an increase in boiling point.
Why is water conducive to hydrogen bond formation?
All other answers are correct.
Water is an electric dipole.
Oxygen is electronegative.
The two hydrogen atoms are covalently bonded.
Water is a polar solvent.
Oxygen is more electronegative than hydrogen. This results in the electrons to spend more time with the oxygen atom making it negatively chared and the hydrogen atoms to be positively charged. The charged water molecule is then able to form hydrogen bonds with polar molecules.
What is the maximum number of hydrogen bonds that one water molecule can form?
Four
Two
One
Three
Hydrogen can form hydrogen bonds with nitrogen, oxygen, and fluorine. A water molecule consists of an oxygen atom bonded to two hydrogen atoms. Each hydrogen atom can form a hydrogen bond with a nitrogen, fluorine, or oxygen atom. Also, the oxygen, which has two lone pairs of electrons, can form two hydrogen bonds with hydrogen atoms. This sums to four hydrogen bonds per water molecule.
In a solution of water, which of the following amino acids do you expect to be on the outside of a protein in its native state?
Glutamic acid
Phenylalanine
Isoleucine
Valine
In a solution of water, the outside of a folded protein is going to be in direct contact with water. Therefore, polar or ionic attractions are most favored on the outside of a protein in a solution of water since these can form attractions. The only amino acid listed that can form either polar or ionic attractions is glutamic acid.
How does the strength of hydrogen bonds compare with the strength of ionic bonds?
Hydrogen bonds are weaker than ionic bonds.
Hydrogen bonds are stronger than ionic bonds.
Hydrogen bonds are just as strong as ionic bonds.
It depends on the temperature.
Bond strengths are measured in kilojoules/mole. Hydrogen bonds can have a strength of . Ionic bonds can have a strength of
. This makes hydrogen bonds much weaker than ionic bonds.
A: adenine
U: uracil
C: cytosine
G: guanine
T: thymine
Which of the following pairs of DNA bases would require the most energy to break?
G-C
G-A
T-A
A-U
C-T
Uracil is not a base in DNA, so A-U can be ruled out as an answer. Moreover, C-G and A-T are the correct base pairs, so the other combinations can be ruled out as well. C-G requires more energy to break because there are three hydrogen bonds between these bases, while A-T has only two hydrogen bonds holding them together.
A researcher adds three molecules together and notices no reactions. Upon further analysis, he notices that molecule A and molecule B form strong intermolecular bonds whereas molecule C doesn’t form any bonds between A and B. Which of the following might be true regarding these three molecules?
I. Molecule A might have nitrogen
II. Molecule B might have fluorine
III. Molecule C might have nitrogen
I and II
I and III
II and III
I, II and III
An example of strong intermolecular bond is a hydrogen bond. A hydrogen bond occurs between a hydrogen atom on a molecule and an either nitrogen, oxygen, or fluorine atom on an adjacent molecule. The question states that there are bonds between molecule A and molecule B. We can assume that these are hydrogen bonds. This means that molecule A can have hydrogen atom and/or nitrogen, oxygen, or fluorine atoms. Similarly, molecule B can also have hydrogen atom and/or nitrogen, oxygen, or fluorine atoms.
Molecule C doesn’t form hydrogen bonds with either of the other two molecules. This means it cannot have hydrogen and/or nitrogen, oxygen, or fluorine atoms. This is because if molecule C had any of these atoms then it would interact with at least one of the other molecules and form hydrogen bonds (because molecule A and molecule B have these other atoms).
Hydrogen bonds mostly occur between hydrogen and which other atoms?
Oxygen, nitrogen, and fluorine
Sodium, magnesium and aluminum
Silicon and Germanium
Scandium and vanadium
Neon, argon, and xenon
For a hydrogen bond to occur, the atom to which the hydrogen is bonded has to have a high relative Pauling electronegativity. Only oxygen, nitrogen, and fluorine, in the upper right corner of the periodic table, have these electronegativities. Neon, argon, and xenon are, of course, inert noble gases, although xenon is sometimes assigned a high electronegativity. This is due, however, to rare bonding events -- certainly not regular hydrogen bonding. Sodium, magnesium and aluminum often form positively charged ions, so they would not tend to attract a hydrogen nucleus.