Solutions and Mixtures
Help Questions
AP Chemistry › Solutions and Mixtures
A student bubbles carbon dioxide gas (CO2) into water and caps the container. After shaking, no bubbles are visible and the liquid is clear. Which statement is correct?
A homogeneous solution forms, and water is the solvent.
A homogeneous solution forms, and CO2 is the solvent.
A heterogeneous mixture forms because CO2 is nonpolar.
A heterogeneous mixture forms because gases cannot dissolve in liquids.
A homogeneous solution forms, and water is the solute.
Explanation
This question tests the skill of recognizing gas solubility in liquids and identifying the solvent in gaseous solute systems. Carbon dioxide gas dissolves in water to form a clear, homogeneous solution, as CO2 molecules interact with water via dipole-induced dipole forces, and no bubbles are visible after shaking. In this solution, water is the solvent as it is the liquid medium containing the dissolved gas. The capped container and shaking enhance dissolution by increasing pressure and contact. A tempting distractor is choice B, which identifies CO2 as the solvent, arising from the misconception that the gaseous component acts as the solvent. To determine solution types with gases, consider the liquid as the solvent and check for uniformity and absence of phases to confirm homogeneity.
A student adds a small amount of iodine (I2, nonpolar molecular solid) to a beaker containing hexane (C6H14, nonpolar) and swirls. The mixture turns uniformly purple. Which statement is correct?
A heterogeneous mixture forms because nonpolar solutes only dissolve in polar solvents.
A homogeneous solution forms, and iodine is the solvent because it provides the color.
A homogeneous solution forms, and hexane is the solvent.
A heterogeneous mixture forms because solids cannot dissolve in liquids.
A homogeneous solution forms, and iodine is the solvent.
Explanation
This question tests the skill of applying the 'like dissolves like' rule to predict solubility and identify solvents in nonpolar systems. Iodine, a nonpolar molecular solid, dissolves in hexane, a nonpolar solvent, forming a uniformly purple mixture because their similar nonpolar natures allow for dispersion forces to facilitate dissolution. In this homogeneous solution, hexane is the solvent as it is the liquid medium in larger amount. The uniform color without visible solids confirms complete dissolution. A tempting distractor is choice B, which identifies iodine as the solvent, based on the misconception that the colored or solid component dictates the solvent role. When dealing with nonpolar solutes and solvents, use the 'like dissolves like' principle and identify the solvent as the predominant liquid component to classify the mixture accurately.
A student adds $2.0,\text{g}$ of sodium chloride (NaCl) to $50,\text{mL}$ of liquid water at room temperature and stirs for 2 minutes. Which statement best describes the mixture?
No homogeneous solution forms because ionic compounds cannot dissolve in polar solvents.
A homogeneous solution forms; water is the solvent and NaCl is the solute.
No homogeneous solution forms because water and NaCl are both polar substances.
A homogeneous solution forms; NaCl is the solvent and water is the solute.
A homogeneous solution forms; both NaCl and water are solvents because both are present.
Explanation
This question tests the understanding of solubility principles, specifically how ionic compounds interact with polar solvents and the identification of solvent versus solute. When 2.0 g of NaCl, an ionic compound, is added to 50 mL of water, a polar solvent, it dissolves completely due to the 'like dissolves like' rule, where the polar water molecules can effectively solvate the Na+ and Cl- ions, forming a homogeneous solution. Water is identified as the solvent because it is present in a much larger quantity compared to NaCl, which is the solute as the dissolved substance. The stirring helps in dispersing the ions evenly throughout the solution. A tempting distractor is choice B, which incorrectly identifies NaCl as the solvent and water as the solute, stemming from the misconception that the solid must be the solvent due to its state of matter rather than considering the relative amounts. A transferable strategy is to always evaluate the polarity of substances and the relative quantities to determine solubility and roles in a solution.
A student adds $1.0,\text{mL}$ of ethanol ($\text{C}_2\text{H}_5\text{OH}$) to $99,\text{mL}$ of water and stirs until the mixture appears uniform. Which statement correctly identifies the solvent and solute?
No homogeneous solution forms because two liquids cannot form a solution.
A homogeneous solution forms; ethanol is the solvent and water is the solute.
A homogeneous solution forms; both ethanol and water are solutes in each other.
A homogeneous solution forms; water is the solvent and ethanol is the solute.
No homogeneous solution forms because ethanol is polar and water is polar.
Explanation
This question tests the identification of solvent and solute in miscible liquid mixtures and the principles of solubility for polar substances. Adding 1.0 mL of ethanol, a polar molecule capable of hydrogen bonding, to 99 mL of polar water results in a homogeneous solution because both substances have similar intermolecular forces, allowing them to mix uniformly according to 'like dissolves like'. Water is the solvent as it constitutes the vast majority of the mixture by volume, while ethanol is the solute being dissolved in it. The stirring ensures even distribution, leading to a uniform appearance. A tempting distractor is choice A, which reverses the solvent and solute, based on the misconception that the added substance is always the solvent regardless of quantity. A transferable strategy is to designate the component in the greatest amount as the solvent in mixtures of similar polarity.
A student mixes $10,\text{mL}$ of hexane ($\text{C}6\text{H}{14}$, nonpolar) with $10,\text{mL}$ of water (polar) in a test tube and shakes the mixture. After standing, two distinct layers are observed. Which statement is correct?
No homogeneous solution forms because equal volumes cannot make a solution.
A homogeneous solution forms; both liquids act as solvents since both are liquids.
A homogeneous solution forms; hexane is the solvent and water is the solute.
No homogeneous solution forms because a polar liquid and a nonpolar liquid are immiscible.
A homogeneous solution forms; water is the solvent and hexane is the solute.
Explanation
This question tests the concept of miscibility between liquids of different polarities and the formation of homogeneous solutions. Mixing 10 mL of nonpolar hexane with 10 mL of polar water results in two distinct layers because nonpolar and polar substances are immiscible, following the 'like dissolves like' principle where similar intermolecular forces are required for mixing. The shaking temporarily disperses the liquids, but upon standing, they separate due to the inability of water's hydrogen bonding to interact effectively with hexane's London dispersion forces. No homogeneous solution forms as the substances do not mix at a molecular level. A tempting distractor is choice A, which suggests a homogeneous solution with water as solvent, but this is incorrect due to the misconception that equal volumes guarantee miscibility regardless of polarity differences. A transferable strategy is to assess the polarity of components to predict whether they will form a single phase or separate layers.
A student mixes $5.0,\text{g}$ of sucrose ($\text{C}{12}\text{H}{22}\text{O}_{11}$) with $20,\text{mL}$ of water and stirs until the mixture is clear. Which statement is correct?
A homogeneous solution forms; water is the solvent and sucrose is the solute.
No homogeneous solution forms because sugar molecules are too large to dissolve.
A homogeneous solution forms; both substances are solvents because both are present in large amounts.
No homogeneous solution forms because covalent compounds cannot dissolve in water.
A homogeneous solution forms; sucrose is the solvent and water is the solute.
Explanation
This question tests the solubility of polar covalent compounds in polar solvents and correct identification of solution components. Mixing 5.0 g of sucrose, a polar molecular solid with multiple OH groups, into 20 mL of polar water forms a homogeneous solution because the similar polar natures allow hydrogen bonding interactions, adhering to 'like dissolves like', resulting in a clear mixture after stirring. Water serves as the solvent due to its larger quantity, while sucrose is the solute being dissolved. The process is facilitated by the breakdown of sucrose crystals into molecules dispersed in water. A tempting distractor is choice B, which incorrectly labels sucrose as solvent, arising from the misconception that the solid component is always the solvent based on physical state rather than amount. A transferable strategy is to consider molecular polarity and hydrogen bonding capability when predicting dissolution of organic compounds in water.
A student adds 1.0 g of sucrose (C12H22O11, polar) to 20 mL of water and stirs until the liquid is clear and uniform. Which statement is correct?
A homogeneous solution forms, and water is the solute.
A homogeneous solution forms, and sucrose is the solvent.
A homogeneous solution forms, and water is the solvent.
A heterogeneous mixture forms because sucrose molecules are too large.
A heterogeneous mixture forms because covalent compounds do not dissolve in water.
Explanation
This question tests the skill of recognizing solubility of polar covalent compounds in water and distinguishing solvent from solute. Sucrose, a polar covalent solid, dissolves completely in water, a polar solvent, forming a clear, uniform solution due to hydrogen bonding interactions between sucrose molecules and water. With 1.0 g of sucrose in 20 mL of water, water is the solvent as it is the abundant liquid component. The clarity and uniformity indicate a homogeneous solution. A tempting distractor is choice A, which names sucrose as the solvent, stemming from the misconception that the solid is always the solvent irrespective of quantity. To evaluate dissolution, consider molecular polarity and intermolecular forces, and designate the solvent as the component in greater amount for proper classification.
A student adds $1.0,\text{g}$ of calcium carbonate ($\text{CaCO}_3$) to $100,\text{mL}$ of water at room temperature and stirs. A solid remains at the bottom after several minutes. Which statement is most accurate?
A homogeneous solution forms; $\text{CaCO}_3$ is the solvent because it is a solid.
No homogeneous solution forms because stirring cannot produce solutions.
A homogeneous solution forms; the solvent is the substance with the higher molar mass.
A homogeneous solution forms; water is the solute and $\text{CaCO}_3$ is the solvent.
No homogeneous solution forms because $\text{CaCO}_3$ is only sparingly soluble in water.
Explanation
This question tests knowledge of solubility limits for ionic compounds and recognition of sparingly soluble substances. Adding 1.0 g of CaCO3 to 100 mL of water results in undissolved solid remaining because CaCO3 has very low solubility in water (about 0.0013 g/100 mL at room temperature), preventing a homogeneous solution from forming despite stirring. This is due to the strong lattice energy in CaCO3 not being sufficiently overcome by hydration energy in water. The mixture remains heterogeneous with precipitate at the bottom. A tempting distractor is choice A, suggesting a homogeneous solution with reversed roles, but this stems from the misconception that all ionic solids are highly soluble in water without checking specific solubility data. A transferable strategy is to consult solubility rules or tables for ionic compounds to predict if a given amount will fully dissolve.
A student bubbles carbon dioxide gas (CO2) into water to make carbonated water. Which statement correctly identifies the solvent and solute in the resulting mixture (ignoring any chemical reaction)?
CO2 and water form a heterogeneous mixture because gases cannot dissolve in liquids.
CO2 is the solute and water is the solvent in a homogeneous solution.
Water is the solute because it is the liquid phase.
CO2 is the solvent because it is added using a gas tank.
CO2 is the solvent and water is the solute in a homogeneous solution.
Explanation
This question tests identification of solute and solvent when a gas dissolves in a liquid. When CO2 gas bubbles through water, some CO2 molecules dissolve in the water to form a homogeneous solution (carbonated water). In this solution, water is the solvent because it's the liquid medium doing the dissolving, while CO2 is the solute because it's the substance being dissolved. Choice D incorrectly claims gases cannot dissolve in liquids, when in fact many gases have measurable solubility in liquids (think of oxygen dissolved in water for fish to breathe). Remember that the physical state doesn't determine solvent/solute roles - the solvent is the dissolving medium (usually in greater amount) and the solute is what gets dissolved.
A student adds $3.0,\text{g}$ of potassium nitrate ($\text{KNO}_3$) to $100,\text{mL}$ of water at $60^\circ\text{C}$ and stirs until the mixture is clear. Which statement is correct?
A homogeneous solution forms; the solvent is the component present in fewer moles.
A homogeneous solution forms; water is the solvent and $\text{KNO}_3$ is the solute.
No homogeneous solution forms because ionic compounds cannot dissolve at elevated temperature.
A homogeneous solution forms; $\text{KNO}_3$ is the solvent and water is the solute.
No homogeneous solution forms because heating prevents dissolution by increasing particle motion.
Explanation
This question tests the effect of temperature on solubility of ionic compounds and identification of solution components. Adding 3.0 g of KNO3 to 100 mL of water at 60°C forms a homogeneous solution because KNO3 has high solubility in water, which increases with temperature (about 100 g/100 mL at 60°C), allowing full dissolution with stirring. Water is the solvent as the abundant liquid, and KNO3 is the solute, following standard definitions where the dissolved solid is the solute. The elevated temperature provides more kinetic energy to break ionic bonds and enhance solvation. A tempting distractor is choice B, claiming no solution due to temperature effects, but this reflects the misconception that heat always reduces solubility, whereas for most solids like KNO3, it increases it. A transferable strategy is to reference solubility curves for temperature-dependent dissolution predictions.