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A buffer using acetic acid (pKa=4.76) is titrated with NaOH. What is the pH at half the equivalence point?
2.38
4.76
7.00
9.52
12.36
Explanation
The pH at half the equivalence point is equal to the pKa of the acid.
Which of the following will increase the pH of an buffer solution?
I. Removing carbonic acid
II. Adding sodium bicarbonate
Both I and II
I only
II only
Neither of these options
Explanation
To answer this question we need to look at the reaction below:
An increase in the pH will result in a decrease in the concentration of hydrogen ions (). Using Le Chatelier’s principle we can find out which answer choices will decrease
.
Removing carbonic acid will decrease the concentration of . To maintain equilibrium, the reaction will shift to the left and make more reactants from products; therefore, there will be a decrease in the
and an increase in pH.
Recall that salts like sodium bicarbonate, or , will dissociate in water and form ions. Sodium bicarbonate will form sodium (
) and bicarbonate (
) ions. This side reaction will result in an increase in the bicarbonate ion concentration. Le Chatelier’s principle will shift the equilibrium of the given reaction to the left and, therefore, decrease the
. Adding sodium bicarbonate will increase the pH.
The following ReDox reaction takes place in acidic solution:
Fe2+ + Cr2O72– → Fe3+ + Cr3+
What is the sum of coefficients in this redox reaction?
36
35
34
33
37
Explanation
When you balance the redox reaction in acidic conditons, there are 6Fe2+, 1 Cr2O72–, 14 H+, 6 Fe3+, 2 Cr3+, and 7 H2O. Don't forget to add the 1 in front of the Cr2O72–
Where does the flattest region of a titration curve of the titration of a weak acid with a strong base occur?
At the pKa of the acid
At the pKb of the base
At a pH greater than 7
At a pH of 7
Explanation
In this question, titration curve would graph the pH of acid solution versus the amount of base added. Since the base is strong and the acid is weak, we can conclude that the pH will be slightly greater than 7 at the equivalence point. The equivalence point is found in the steepest region of the curve.
The half-equivalence point is the flattest region of the titration curve and is most resistant to changes in pH. This corresponds to the pKa of the acid. Within this region, adding base (changing the x-value) results in very little deviation in the pH (the y-value). This region is also the buffer region for the given acid.
Which of the following will increase the pH of an buffer solution?
I. Removing carbonic acid
II. Adding sodium bicarbonate
Both I and II
I only
II only
Neither of these options
Explanation
To answer this question we need to look at the reaction below:
An increase in the pH will result in a decrease in the concentration of hydrogen ions (). Using Le Chatelier’s principle we can find out which answer choices will decrease
.
Removing carbonic acid will decrease the concentration of . To maintain equilibrium, the reaction will shift to the left and make more reactants from products; therefore, there will be a decrease in the
and an increase in pH.
Recall that salts like sodium bicarbonate, or , will dissociate in water and form ions. Sodium bicarbonate will form sodium (
) and bicarbonate (
) ions. This side reaction will result in an increase in the bicarbonate ion concentration. Le Chatelier’s principle will shift the equilibrium of the given reaction to the left and, therefore, decrease the
. Adding sodium bicarbonate will increase the pH.
When is the oxidation number of H (-1)?
Never
When it is bonded to a more electronegative element
When it is bonded to a less electronegative element
Only when it is bonded to Flourine
Only when it is bonded to Chlorine
Explanation
We typically think of Hydrogen as having an oxidation number of +1. However when it is bonded to a less electronegative element such as Na it is actually assigned an oxidation number of -1.
For the redox reaction shown, which of the following half reactions occurs in the anode?
Explanation
Recall that oxidation always occurs at the anode (in both the electrochemical and galvanic cells). loses two electrons in this case to become
. The presence of
is hinted by the ionic compound
.
A buffer using acetic acid (pKa=4.76) is titrated with NaOH. What is the pH at half the equivalence point?
2.38
4.76
7.00
9.52
12.36
Explanation
The pH at half the equivalence point is equal to the pKa of the acid.
How many electrons are involved in the following reaction?
1 e-
2 e-
4 e-
5 e-
10 e-
Explanation
The common factor between 2 e- and 5 e- is 10. Therefore the number of electrons involved is 10 e-.
In the following reaction, which compound is being oxidized?
Copper
Sulfur
Hydrogen
Nitrate
No oxidation takes place
Explanation
Hydrogen doesn't change. Cu2+ doesn't change (partnered with S2- then with SO42-). Sulfur goes from S2- and S6+(paired with 6 O2- with a 2– charge), showing an oxidation. Nitrogen goes from N5+ to N2+ meaning it was reduced.