Oxidation-Reduction (Redox) Reactions

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AP Chemistry › Oxidation-Reduction (Redox) Reactions

Questions 1 - 10
1

Aqueous hydrogen peroxide reacts with iodide ions in acidic solution to produce iodine and water, as shown:

$\mathrm{H_2O_2(aq) + 2,I^-(aq) + 2,H^+(aq) \rightarrow I_2(aq) + 2,H_2O(l)}$

Which statement correctly describes the redox changes?

I$_2$(aq) is oxidized and H$_2$O(l) is reduced

I$^-$(aq) is oxidized and H$_2$O$_2$(aq) is reduced

No species changes oxidation number because oxygen is present on both sides

H$^+$(aq) is reduced and I$^-$(aq) is oxidized

I$^-$(aq) is reduced and H$_2$O$_2$(aq) is oxidized

Explanation

This question assesses understanding of oxidation–reduction (redox) reactions. To describe the redox changes, assign oxidation numbers: O in H₂O₂(aq) is -1 each (H +1, total balanced), I in I⁻(aq) is -1, H in H⁺(aq) is +1, I in I₂(aq) is 0, O in H₂O(l) is -2. Iodine increases from -1 to 0, losing electrons and being oxidized, while oxygen in H₂O₂ decreases from -1 to -2, gaining electrons and being reduced; H remains +1. Thus, I⁻(aq) is oxidized and H₂O₂(aq) is reduced. A tempting distractor is 'I⁻(aq) is reduced and H₂O₂(aq) is oxidized,' but that's reversed—a common error is assigning O in peroxide as -2 instead of -1. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation numbers, especially for exceptions like peroxides.

2

Aluminum metal reacts with aqueous copper(II) chloride to produce aqueous aluminum chloride and copper metal, as shown:

$\mathrm{2,Al(s) + 3,CuCl_2(aq) \rightarrow 2,AlCl_3(aq) + 3,Cu(s)}$

How many electrons are transferred per aluminum atom that reacts?

1 electron

2 electrons

6 electrons

4 electrons

3 electrons

Explanation

This question assesses understanding of oxidation–reduction (redox) reactions. To determine electrons transferred per Al atom, assign oxidation numbers: Al(s) is 0, Cu in CuCl₂(aq) is +2 (Cl -1 each), Al in AlCl₃(aq) is +3, Cu(s) is 0. Each Al atom's oxidation number increases from 0 to +3, losing 3 electrons, while Cu decreases from +2 to 0, gaining 2 electrons; the balanced equation shows 2 Al and 3 Cu, so total 6 electrons transferred (3 per Al times 2). It's 3 electrons per aluminum atom. A tempting distractor is 2 electrons, but that's per Cu, not Al—a common error is confusing per atom with total transfer without balancing. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation number changes per atom and use coefficients for total electrons.

3

In acidic solution, iron(II) ions react with dichromate ions to form iron(III) ions and chromium(III) ions, as represented by the balanced equation: $\mathrm{Cr_2O_7^{2-}(aq) + 6,Fe^{2+}(aq) + 14,H^+(aq) \rightarrow 2,Cr^{3+}(aq) + 6,Fe^{3+}(aq) + 7,H_2O(l)}$ Which species acts as the oxidizing agent?

$H^{+}(aq)$

$Cr^{3+}(aq)$

$Fe^{2+}(aq)$

$H_2O(l)$

$Cr_2O_7^{2-}(aq)$

Explanation

This question assesses understanding of oxidation–reduction (redox) reactions. To find the oxidizing agent, assign oxidation numbers: iron in $Fe^{2+}(aq)$ is +2, chromium in $Cr_2O_7^{2-}(aq)$ is +6 (oxygen is -2, total -14 for seven oxygens, so two Cr are +12 total), and in products, $Fe^{3+}$ is +3, $Cr^{3+}$ is +3. Iron's oxidation number increases from +2 to +3, losing electrons and being oxidized, while chromium's decreases from +6 to +3, gaining electrons and being reduced. Thus, $Cr_2O_7^{2-}(aq)$ is the oxidizing agent as it causes oxidation by accepting electrons. A tempting distractor is $Fe^{2+}(aq)$, but it is oxidized, not the oxidizing agent—a common error is confusing the species that loses electrons with the one that accepts them. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation numbers to identify agents in redox reactions.

4

In a reaction used in some water-treatment processes, sulfur dioxide is oxidized by oxygen to form sulfur trioxide:

$2\text{SO}_2(g) + \text{O}_2(g) \rightarrow 2\text{SO}_3(g)$

Which species is oxidized?

O2(g)

SO3(g)

S(s)

SO2(g)

$O^2$− (in SO3)

Explanation

This question tests understanding of oxidation-reduction (redox) reactions. In 2SO₂(g) + O₂(g) → 2SO₃(g), we track oxidation numbers: S in SO₂ has +4 (since O is -2, and the molecule is neutral: S + 2(-2) = 0, so S = +4), and S in SO₃ has +6 (S + 3(-2) = 0, so S = +6). Oxygen in O₂ starts at 0 and becomes -2 in SO₃. Since sulfur increases from +4 to +6 (loses electrons), SO₂ is oxidized. A common mistake is thinking O₂ is oxidized because it "disappears," but O₂ actually gains electrons (0 → -2) and is reduced. Remember: oxidation involves loss of electrons and an increase in oxidation number.

5

In acidic solution, permanganate ions react with oxalate ions to form manganese(II) ions and carbon dioxide:

$2\text{MnO}_4^-(aq) + 5\text{C}_2\text{O}_4^{2-}(aq) + 16\text{H}^+(aq) \rightarrow 2\text{Mn}^{2+}(aq) + 10\text{CO}_2(g) + 8\text{H}_2\text{O}(l)$

Which species acts as the reducing agent?

$\text{C}_2\text{O}_4^{2-}(aq)$

$\text{MnO}_4^{-}(aq)$

$\text{CO}_2(g)$

$\text{H}^{+}(aq)$

$\text{H}_2\text{O}(l)$

Explanation

This question tests understanding of oxidation-reduction (redox) reactions. In the reaction, Mn in $MnO_4^{-}$ has oxidation number +7 ($(Mn + 4(-2) = -1$, so $Mn = +7$) and becomes $Mn^{2+}$ (+2), gaining electrons and being reduced. Carbon in $C_2O_4^{2-}$ has oxidation number +3 ($(2C + 4(-2) = -2$, so $C = +3$) and becomes +4 in $CO_2$, losing electrons and being oxidized. The reducing agent is the species that gets oxidized, which is $C_2O_4^{2-}$ (oxalate ion). A common mistake is thinking $MnO_4^{-}$ is the reducing agent because it's reduced, but the reducing agent causes reduction while itself being oxidized. Remember: the reducing agent loses electrons and increases in oxidation number.

6

A student mixes aqueous potassium iodide with aqueous iron(III) chloride, producing aqueous iron(II) chloride and iodine:

$2\text{FeCl}_3(aq) + 2\text{KI}(aq) \rightarrow 2\text{FeCl}_2(aq) + \text{I}_2(s) + 2\text{KCl}(aq)$

Which species is the reducing agent?

I2(s)

I−(aq)

Cl−(aq)

K+(aq)

$Fe^3$+(aq)

Explanation

This question tests understanding of oxidation-reduction (redox) reactions. In the reaction, Fe³⁺ in FeCl₃ becomes Fe²⁺ in FeCl₂ (gains electrons, is reduced), while I⁻ becomes I₂ (oxidation number -1 to 0, loses electrons, is oxidized). The reducing agent is the species that gets oxidized, which is I⁻ (iodide ion). K⁺ and Cl⁻ are spectator ions with unchanged oxidation numbers. A common error is thinking Fe³⁺ is the reducing agent because it appears to be "reduced," but the reducing agent causes reduction while itself being oxidized. Remember: the reducing agent loses electrons and gets oxidized in the process.

7

Hydrogen peroxide can react with iodide ions in acidic solution to produce iodine and water:

$\text{H}_2\text{O}_2(aq) + 2\text{I}^-(aq) + 2\text{H}^+(aq) \rightarrow \text{I}_2(aq) + 2\text{H}_2\text{O}(l)$

Which species is reduced?

H+(aq)

I2(aq)

H2O(l)

I−(aq)

H2O2(aq)

Explanation

This question tests understanding of oxidation-reduction (redox) reactions. In H₂O₂(aq) + 2I⁻(aq) + 2H⁺(aq) → I₂(aq) + 2H₂O(l), iodide (I⁻) goes from -1 to 0 in I₂ (loses electrons, is oxidized), while oxygen in H₂O₂ has oxidation number -1 (unusual for oxygen) and becomes -2 in H₂O (gains electrons, is reduced). To verify O in H₂O₂: 2(+1) + 2(O) = 0, so O = -1. The species being reduced is H₂O₂. A common error is thinking I⁻ is reduced because it forms I₂, but forming a diatomic molecule from ions involves electron loss. Remember: reduction is gain of electrons (decrease in oxidation number), and peroxides have oxygen at -1.

8

When hydrogen sulfide gas is bubbled into a solution containing chlorine gas dissolved in water, the reaction below occurs:

$\text{H}_2\text{S}(g) + \text{Cl}_2(aq) \rightarrow 2\text{HCl}(aq) + \text{S}(s)$

Which species acts as the oxidizing agent?

Cl2(aq)

H2S(g)

HCl(aq)

S(s)

H+(aq)

Explanation

This question tests understanding of oxidation-reduction (redox) reactions. In H₂S(g) + Cl₂(aq) → 2HCl(aq) + S(s), we assign oxidation numbers: S in H₂S has -2, S in elemental form has 0, Cl in Cl₂ has 0, and Cl in HCl has -1. Sulfur goes from -2 to 0 (loses electrons, is oxidized), while chlorine goes from 0 to -1 (gains electrons, is reduced). The oxidizing agent is the species that gets reduced, which is Cl₂. A common mistake is thinking H₂S is the oxidizing agent because it contains the element being oxidized, but the oxidizing agent causes oxidation while itself being reduced. Remember: the oxidizing agent gains electrons and gets reduced in the process.

9

A student adds aluminum metal to an aqueous solution of silver nitrate, producing silver metal:

$\text{Al}(s) + 3\text{AgNO}_3(aq) \rightarrow \text{Al(NO}_3)_3(aq) + 3\text{Ag}(s)$

How many electrons are transferred per aluminum atom in this reaction?

1

2

3

6

9

Explanation

This question tests understanding of oxidation–reduction (redox) reactions. Assign oxidation numbers: aluminum in Al(s) is 0, silver in AgNO₃ is +1, aluminum in Al(NO₃)₃ is +3, and silver in Ag(s) is 0. Aluminum's oxidation number increases from 0 to +3, indicating loss of 3 electrons per atom, while silver decreases from +1 to 0, showing gain of 1 electron per atom. Nitrate remains unchanged. A tempting distractor is 6, but that might come from doubling the electrons for the balanced equation; forgetting per-atom count is common. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation numbers.

10

A sample of magnesium metal burns in oxygen gas to form magnesium oxide:

$2\text{Mg}(s) + \text{O}_2(g) \rightarrow 2\text{MgO}(s)$

Which statement correctly describes the oxidation-number changes for Mg and O?

Mg: $+2 \rightarrow 0$ and O: $-2 \rightarrow 0$

Mg: $0 \rightarrow +1$ and O: $0 \rightarrow -1$

Mg: $0 \rightarrow -2$ and O: $0 \rightarrow +2$

Mg: $0 \rightarrow +2$ and O: $0 \rightarrow -2$

Mg: $+2 \rightarrow +4$ and O: $-2 \rightarrow -1$

Explanation

This question tests understanding of oxidation-reduction (redox) reactions. In 2Mg(s) + O₂(g) → 2MgO(s), we track oxidation numbers: Mg starts at 0 (elemental) and becomes +2 in MgO, while O starts at 0 (in O₂) and becomes -2 in MgO. Magnesium loses 2 electrons per atom (0 → +2, oxidation), and oxygen gains 2 electrons per atom (0 → -2, reduction). This is a classic combustion reaction where the metal is oxidized and oxygen is reduced. A common mistake is thinking Mg goes to -2 because it combines with oxygen, but metals typically form positive ions. Remember: in redox reactions, track oxidation numbers from reactants to products to identify electron transfer.

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