Molecular Structure of Acids and Bases

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AP Chemistry › Molecular Structure of Acids and Bases

Questions 1 - 5
1

Put the following acids in order of their INCREASING acid strength: HI, HCl, HBr, HF.

HI, HCl, HBr, HF

HF, HCl, HBr, HI

HI, HBr, HCl, HF

HF, HBR, HI, HCl

HCl, HBr, HI, HF

Explanation

Larger halogen size leads to greater acidity because of weaker H-X interactions.

2

Put the following in order of INCREASING acid strength: H2Se, KH, AsH3, HBr.

KH, AsH3, H2Se, HBr

HBr, H2Se, AsH3, KH

AsH3, H2Se, HBr, KH

AsH3, H2Se, KH, HBr

KH, H2Se, AsH3, HBr

Explanation

Acid strength increases going across a period.

3

Put the following acids in order of their INCREASING acid strength: HCl, HS, HBr, H2Se.

HCl, HS, HBr, H2Se

H2Se, HBr, HS, HCl

HBr, H2Se, HCl, H2S

H2S, HCl, HBr, H2Se

H2S, H2Se, HCl, HBr

Explanation

Acid strength increases from left to right across a period and increases going down a group.

4

Put the following acids in order of their DECREASING acid strength: HOCl, HOBr, HOI, H2O.

HOCl, HOBr, HOI, H2O

H2O, HOI, HOBr, HOCl

HOI, HOBr, HOCl, H2O

H2O, HOCl, HOBr, HOI

HOCl, H2O, HOBr, HOI

Explanation

Acid strength of an oxy acid increases with increasing electronegativity on the halogen.

5

Put the following acids in order of their DECREASING acid strength: HOCl, HO2Cl, HO3Cl, HO4Cl.

HOCL, HO2Cl, HO3Cl, HO4Cl

HOCl, HO4Cl, HO2Cl, HO3Cl

HO4Cl, HO3Cl, HO2Cl, HOCl

HO4Cl, HOCl, HO2Cl, HO3Cl

HO2Cl, HOCl, HO3Cl, HO4Cl

Explanation

For an oxyacid, the acid strength increases as the number of oxygens increase.

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