Introduction for Reactions

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AP Chemistry › Introduction for Reactions

Questions 1 - 10
1

What is the chemical formula of the salt formed when a chemist mixes solvated Potassium and Arsenic ions in solution?

K_3As

K_2As

KAs

KAs_3

KAs_2

Explanation

Potassium is a Group I element, so to get to a filled valence shell, it will lost one electron, yielding K^+.

Arsenic is a Group 5 element, so it needs to gain three electrons to obtain a filled valence shell, yielding As^{-3}.

In order to balance out the charges, the resultant salt will be K_3As.

2

What is the balanced chemical equation for the combustion of butane ?

Explanation

Combustion is the chemical reaction of a hydrocarbon with molecular oxygen, and it always produces carbon dioxide and water. Knowing the reactants and products, the unbalanced equation must be:

We start by balancing the hydrogens. Since there are 10 on the left and only 2 on the right, we put a coefficient of 5 on water.

Similarly, we balance carbons by putting a 4 on the carbon dioxide.

To find the number of oxygens on the right, we multiply the 4 coefficient by the 2 subscript on O (which gets us 8 oxygens) and then add the 5 oxygens from the 5 water molecules to get a total of 13. The needed coefficient for on the left would then have to be 13/2.

Because fractional coefficients are not allowed, we mutiply every coefficient by 2 to find our final reaction:

3

For single replacement reactions, which of the following sets of guidelines are most helpful?

Activity series

Solubility rules

Oxidation-reduction

Octet rule

Boyle's law

Explanation

When writing/balancing a single replacement reaction, make sure to consult the activity series, because that will tell us if a reaction will actually take place. Remember to look at the cations (metals and hydrogen) and where they are in relation to each other on the activity series. The higher one on the activity series is the most reactive; so if the cation by itself is the most reactive, it will replace the other cation and a reaction will occur. Boyle's law explains the inverse relationship between volume and pressure with respect to certain amount of an ideal gas at constant temperature.

4

What is the coefficient for , reduced to the lowest whole number, when the given reaction is balanced?

Explanation

The best way to solve this problem is to try all the possible answers. When we try 8, means that there must be . means that there must be just , which means that there is . When is reduced to , there are 5 remaining electrons. So 8 is correct. Alternatively, this question may be answered by the classical "trial and error" method of balancing equations.

5

What is the net ionic equation for the ion exchange reaction between ferrous sulfate and calcium iodide? Assume all compounds are soluble.

None of the available answers

Explanation

First, we must know what ferrous sulfate is. Ferrous refers to , and sulfate has the formula . When we combine the two together we get .

Calcium is a divatent cation and iodide is a monovalent anion, so their salt is . The ion exchange reaction is then:

6

Given that lithium is higher on the activity series than hydrogen, what should be seen when solid lithium and hydrochloric acid are mixed?

Bubbles

Increase in test tube's temperature

No change

Change in color

None of these

Explanation

Given that lithium is more reactive than hydrogen, expect a single replacement reaction to take place, so lithium will replace hydrogen.

All ionic compounds are solids at room temperature, which is why lithium chloride has the solid phase label. Remember that hydrogen is a diatomic element which is a gas a room temperature. When observing reactions in which gasses are produced from a solution, bubbles are seen. There is no indication whether this reaction is endothermic or exothermic, nor is there any information that suggests the reaction should change color.

7

Determine whether or not solid aluminum reacts with aqueous zinc chloride. If it does, determine the balanced equation for the reaction.

No reaction occurs

Explanation

When we check the activity series, it is fairly easy to see that aluminum metal is more reactive than zinc metal. So, in this case, the two metals undergo a redox reaction, where the aqueous is reduced to solid , and the solid is oxidized to aqueous . These charges are the common oxidation states for zinc and aluminum and should be memorized.

Because is the new species, it bonds with 3 ions. The unbalanced equation is:

We note that there are 2 chlorine atoms on the left and 3 chlorine atoms on the right. To balance, we use a 3 coefficient on the left and a 2 coefficient on the right. This gives a total of 6 chlorine atoms on eahc side.

However, now we have also increased the amounts of zinc and aluminum. We copy the necessary coefficients to balance those—2 for aluminum on the left, 3 for zinc on the right—and we are done:

8

What is used as guidelines to determine the phase labels for double displacement/double replacement reactions?

Solubility rules

Activity series

Oxidation-reduction

Octet rule

Huckel number

Explanation

For double displacement, the solubility rules determine the phase labels. Make sure the correct set of rules/guidelines for the type of reaction that is being written/balanced are used. The octet rule refers to the stability atoms achieve by filling their outer shell of electrons. Huckel number is 4n+2 where n is any integer, and is involved in assigning aromaticity.

9

Which of the following represents a combustion reaction?

Explanation

Combustion reactions always produce and excess heat. Depending on the molecule that is oxidized by oxygen, which in this case was methane , the ratios between and can vary.

10

What type of reaction is shown above?

Double replacement

Single replacement

Combustion

Decomposition

Explanation

The typical double replacement reaction is as follows:

The anions are the chemical species being exchanged (both sulfur and chloride). Hence, the name double replacement is given to this particular reaction.

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