Heat Capacity and Calorimetry
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AP Chemistry › Heat Capacity and Calorimetry
A coffee-cup calorimeter has a calorimeter constant of $C = 95\ \text{J},\text{^\circC}^{-1}$. During an experiment, the calorimeter’s temperature increases from $24.0^\circ\text{C}$ to $29.0^\circ\text{C}$. What is the heat absorbed by the calorimeter, $q_{\text{cal}}$?
−475\ $\text{J}$
+1900\ $\text{J}$
+95\ $\text{J}$
+475\ $\text{J}$
+19\ $\text{J}$
Explanation
This problem tests the skill of heat capacity and calorimetry. For a calorimeter with a known heat capacity C, we use q = CΔT instead of q = mcΔT. The temperature increases from 24.0°C to 29.0°C, so ΔT = 5.0°C and the calorimeter absorbs heat (positive q). Calculating: q = (95 J·°C⁻¹)(5.0°C) = 475 J, which is positive because heat is absorbed. A common mistake would be to choose -475 J (choice A), incorrectly assigning a negative sign even though the temperature increased. When working with calorimeter constants, remember that q = CΔT directly gives the heat absorbed or released by the calorimeter itself.
A $50.0\ \text{g}$ sample of an unknown metal is warmed from $20.0^\circ\text{C}$ to $80.0^\circ\text{C}$. The metal’s specific heat capacity is $0.450\ \text{J},\text{g}^{-1},\text{^\circC}^{-1}$. What is the heat absorbed by the metal, $q$?
+2.70\ $\text{kJ}$
+1.35\ $\text{kJ}$
−1.35\ $\text{kJ}$
+13.5\ $\text{kJ}$
+0.675\ $\text{kJ}$
Explanation
This problem tests the skill of heat capacity and calorimetry. The metal is warmed from 20.0°C to 80.0°C, so it absorbs heat and q will be positive. Using q = mcΔT, we calculate q = (50.0 g)(0.450 J·g⁻¹·°C⁻¹)(80.0°C - 20.0°C) = (50.0)(0.450)(60.0) = 1350 J = 1.35 kJ. The positive value correctly indicates heat absorption as the temperature increased. A tempting error would be to select +13.5 kJ (choice B), which results from a decimal place error when converting from J to kJ. To avoid calculation errors, write out all units during the calculation and carefully track decimal places when converting between J and kJ.
A coffee-cup calorimeter has a calorimeter constant of $C_{\text{cal}}=120,\text{J},/,^\circ\text{C}$. During a process occurring inside the calorimeter, the temperature of the calorimeter increases from $20.0^\circ\text{C}$ to $25.0^\circ\text{C}$. What is the heat absorbed by the calorimeter, $q_{\text{cal}}$?
+600 J
+300 J
−600 J
+720 J
+24.0 J
Explanation
This problem tests the skill of heat capacity and calorimetry. For a calorimeter with constant C_cal = 120 J/°C, we use q = C_cal × ΔT instead of q = mcΔT. With ΔT = 25.0°C - 20.0°C = 5.0°C, we calculate: q = (120 J/°C)(5.0°C) = 600 J. Since the calorimeter temperature increases, it absorbs heat, making q positive: +600 J. A common error is confusing the calorimeter constant (J/°C) with specific heat capacity (J/(g·°C)) and trying to use mass in the calculation. Remember that calorimeter constants already incorporate the total heat capacity of the system, so use q = C_cal × ΔT directly.
A $200\ \text{g}$ piece of aluminum is cooled. The specific heat capacity of aluminum is $0.90\ \text{J},\text{g}^{-1},^{\circ}\text{C}^{-1}$. If the temperature decreases from $75^{\circ}\text{C}$ to $25^{\circ}\text{C}$, what is the heat transferred for the aluminum sample, $q$, in joules? (Use the sign convention that heat released by the sample is negative.)
$−1.11×10^4$ J
$+9.00×10^3$ J
$−1.80×10^2$ J
$−4.50×10^3$ J
$−9.00×10^3$ J
Explanation
This problem involves heat capacity and calorimetry for a cooling process. When aluminum releases heat during cooling, we apply q = mcΔT with m = 200 g, c = 0.90 J·g⁻¹·°C⁻¹, and ΔT = 25°C - 75°C = -50°C. Calculating: q = (200 g)(0.90 J·g⁻¹·°C⁻¹)(-50°C) = -9,000 J = -9.00×10³ J. The negative sign indicates heat is released by the aluminum as it cools. A common mistake is forgetting the negative sign for cooling processes, which would give +9.00×10³ J (answer B). When solving heat transfer problems, always determine the sign of ΔT first (negative for cooling, positive for heating) to ensure the correct sign for q.
A $40.0,\text{g}$ sample of aluminum is heated, and its temperature increases from $25.0^\circ\text{C}$ to $50.0^\circ\text{C}$. The specific heat capacity of aluminum is $0.900,\text{J},(\text{g}\cdot{}^\circ\text{C})^{-1}$. What is the heat absorbed by the aluminum sample, $q$?
+90.0 J
−900 J
+360 J
$+1.80×10^3$ J
+900 J
Explanation
This problem tests the skill of heat capacity and calorimetry. For aluminum heating from 25.0°C to 50.0°C, we use q = mcΔT with m = 40.0 g, c = 0.900 J/(g·°C), and ΔT = 50.0°C - 25.0°C = 25.0°C. Calculating: q = (40.0 g)(0.900 J/(g·°C))(25.0°C) = 900 J. Since temperature increases, the aluminum absorbs heat, so q = +900 J. A common error is using only one temperature value (like 25.0°C) instead of calculating the temperature difference, which would give +360 J. Always calculate ΔT as the difference between final and initial temperatures before substituting into q = mcΔT.
A $75.0,\text{g}$ sample of water cools from $40.0^\circ\text{C}$ to $30.0^\circ\text{C}$ in an insulated container. The specific heat capacity of water is $4.18,\text{J},(\text{g}\cdot{}^\circ\text{C})^{-1}$. What is the heat transferred for the water, $q$?
$−6.27×10^3$ J
$−3.14×10^3$ J
−314 J
+314 J
$+3.14×10^3$ J
Explanation
This problem tests the skill of heat capacity and calorimetry. When water cools from 40.0°C to 30.0°C, we calculate q = mcΔT with m = 75.0 g, c = 4.18 J/(g·°C), and ΔT = 30.0°C - 40.0°C = -10.0°C. Substituting: q = (75.0 g)(4.18 J/(g·°C))(-10.0°C) = -3135 J ≈ -3.14×10³ J. The negative sign indicates heat is released as the water cools. A common mistake is calculating ΔT as +10.0°C (using 40-30 instead of 30-40), which would incorrectly give +3.14×10³ J. For cooling processes, always calculate ΔT = T_final - T_initial to get the correct negative value.
A reaction occurs in a coffee-cup calorimeter and causes the temperature of the solution to decrease from $26.0^\circ\text{C}$ to $23.0^\circ\text{C}$. The total heat capacity of the solution is $C_{\text{soln}}=500,\text{J},/,^\circ\text{C}$. What is the heat transferred for the solution, $q_{\text{soln}}$?
$−5.00×10^2$ J
$−1.67×10^2$ J
$+1.00×10^3$ J
$−1.50×10^3$ J
$+1.50×10^3$ J
Explanation
This problem tests the skill of heat capacity and calorimetry. For a solution with total heat capacity C_soln = 500 J/°C cooling from 26.0°C to 23.0°C, we use q = C × ΔT. With ΔT = 23.0°C - 26.0°C = -3.0°C, we get: q = (500 J/°C)(-3.0°C) = -1500 J = -1.50×10³ J. The negative sign indicates the solution releases heat as it cools. A common error is using the absolute value of ΔT (3.0°C), which would incorrectly give +1.50×10³ J, missing the direction of heat flow. When using total heat capacity, apply q = C × ΔT directly and preserve the sign of ΔT.
A student heats a 100.0 g sample of liquid water in a beaker. The temperature of the water increases from 22.0°C to 28.0°C. Assume the specific heat capacity of water is $4.18\ \text{J},\text{g}^{-1},^{\circ}\text{C}^{-1}$. What is the heat transferred to the water, $q$?
+418 J
+251 J
-2,510 J
+10,000 J
+2,510 J
Explanation
This question tests the skill of heat capacity and calorimetry. The heat transferred to the water is calculated using the formula q = m c ΔT, where m is the mass, c is the specific heat capacity, and ΔT is the change in temperature. Here, the system is the water sample, which absorbs heat to increase its temperature from 22.0°C to 28.0°C, resulting in a positive ΔT of 6.0°C. Plugging in the values, q = 100.0 g × 4.18 J g⁻¹ °C⁻¹ × 6.0°C = +2,510 J, correctly modeling the energy absorbed by the water. A tempting distractor is choice C, -2,510 J, which arises from the misconception of assigning a negative sign to q when the system gains heat, confusing the sign convention. Always calculate ΔT as T_final - T_initial and assign the sign of q based on whether the system absorbs (positive) or releases (negative) heat.
A student adds heat to a 120 g sample of aluminum, causing its temperature to increase from 20.0°C to 45.0°C. The specific heat capacity of aluminum is $0.90\ \text{J},\text{g}^{-1},^{\circ}\text{C}^{-1}$. What is the heat absorbed by the aluminum sample?
+3,240 J
+2,700 J
+270 J
+1,080 J
-2,700 J
Explanation
This question tests the skill of heat capacity and calorimetry. The heat absorbed by the aluminum is q = m c ΔT, with positive ΔT since temperature increases from 20.0°C to 45.0°C. The system is the aluminum sample, gaining heat, and the equation models this endothermic process. Thus, q = 120 g × 0.90 J g⁻¹ °C⁻¹ × 25°C = +2,700 J, correctly quantifying the energy transfer. A tempting distractor is choice C, -2,700 J, arising from the misconception of using a negative sign for q when the system absorbs heat. Start by noting if the temperature increases (positive q) or decreases (negative q), then apply q = m c ΔT accordingly.
A 200. g sample of a solution in a coffee-cup calorimeter absorbs $+3,600\ \text{J}$ of heat. The specific heat capacity of the solution is $4.0\ \text{J},\text{g}^{-1},^{\circ}\text{C}^{-1}$. What is the temperature change, $\Delta T$, of the solution?
+4.5 °C
-4.5 °C
+9.0 °C
+18.0 °C
+0.45 °C
Explanation
This question tests the skill of heat capacity and calorimetry. The temperature change is determined by rearranging q = m c ΔT to ΔT = q / (m c), where q is positive since the solution absorbs heat. The system is the solution, and this equation models the temperature rise due to energy input. With q = +3,600 J, ΔT = 3,600 J / (200 g × 4.0 J g⁻¹ °C⁻¹) = +4.5°C, correctly calculating the change. A tempting distractor is choice A, +18.0°C, which occurs from the misconception of forgetting to include the mass in the denominator. Always rearrange the heat capacity formula carefully and double-check units for consistency.