Equilibrium Constant and Reaction Quotient

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AP Chemistry › Equilibrium Constant and Reaction Quotient

Questions 1 - 10
1

Consider the following balanced reaction.

Write the equilibrium constant expression for this reaction.

Explanation

When writing an equilibrium constant expression, remember that products are on the top, and reactants are on the bottom of the expression. The coefficients for the compounds in the balanced reaction become the exponents for the compounds seen in the expression.

2

Which of the following is true when the reaction quotient (Q) equals the equilibrium constant (K)?

Change in free energy = 0.

The change in free energy is greater than zero.

The change in free energy is less than zero.

The reaction stops completely.

Explanation

When Q = K, the reaction has reached equilibrium and is in a state of dynamic equilibrium, where the forward and reverse reactions are occurring at the same rate. Since there is no net change in concentration, the free energy is zero.

3

Which of the following factors will change the equilibrium constant, Keq?

Change in temperature

Change in solvent volume

Introducing additional reactants

Introducing additional products

Adding a chemical that will cause side reactions

Explanation

The only factor that changes the equilibrium constant is temperature. Changes in concentration of reactants or products by any means (whether addition, taking away solvent, or adding a chemical that will cause side reactions) will remove the system from equilibrium, but will not change the equilibrium constant.

4

For the following reaction, what would be the correct equilibrium expression?

Explanation

For any equilibrium expression, solids and liquids are excluded because their concentrations are presumed to be constant during the reaction. The equilibrium expression is defined as the ratio of the concentration of products divided by the concentration of the reactants. Each reactant or product is raised to the power corresponding to its coefficient in the balanced chemical equation.

Using an arbitrary example:

Compare this to our question. Remember to exclude the solid magnesium!

5

What is the equilbrium constant for a reaction written in reverse if the forward reaction has constant K?

1/K

2K

K/2

4K

Explanation

This is one of the properties of the law of mass action. The equilbrium constant for a reaction written in reverse is 1/K.

6

If the equilibrium constant lies farther to the right, this indicates that the reaction __________.

is more complete

is less complete

does not have a bearing on the reaction

includes a catalyst

Explanation

The equilibrium constant is given by the concentraton of products over the concentration of reactants. If it lies to the right, it means that it favors the forward reaction, and thus the reaction is "more complete" or closer to completion.

7

Why do the concentrations of pure liquids and solids not appear in the equilibrium constant expression?

Their concentrations don't change over the course of the reaction.

They are not present in the mixture at equilibrium.

Their concentrations change too quickly to be accounted for.

They are completely consumed before the reaction reaches equilibrium.

Explanation

This is one of the properties of the law of mass action—the concentrations of pure solids and liquids don't change over the course of the reaction.

8

What is the correct equilibrium expression for this reaction?

Explanation

Solids are not included in any equilibrium expression. The equilibrium expression will contain only aqueous solutions and gases. In addition, the coefficients of a balanced chemical equation correspond to exponents, not coefficients, in the equilibrium expression.

For this reaction, the only relevant product is oxygen gas and the only relevant reactant is fluorine gas.

9

Which of the following is not a property of the law of mass action?

A system shifts to reduce applied "stress."

The concentrations of pure solids and liquids don't appear in the equilbrium expression.

The equlibrium constant is characteristic of a particular reaction at a certain temperature.

The larger the equilibrium constant (K), the farther to the right equilibrium lies.

Explanation

All of the statements are properties of the law of mass action, except for the answer, which is a statement of Le Chatelier's Principle.

10

If delta G for a certain reaction is found to be -4955 J/mol, what is the equilibrium constant (Keq) for this reaction?

5.9

7.4

55.6

80.9

100

Explanation

Given the equation delta G = -RTln(Keq), plugging in the correct values for the variables will lead us to the correct answer. Using e = 2.7, R = 8.314 J/molK, T= 298 K, and G = -4955 J, we can calculate that K = 7.4.

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