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AP Chemistry › Molecules

Questions 1 - 10
1

How many lone pairs of electrons exist on the following molecule?

BF3

1

0

9

10

11

Explanation

.. ..

:F — B — F: Boron can have a violated octet (6 e-) and each F has 3 lone pairs

.. | .. for a total of 9 pairs of unpaired electrons

:F:

..

2

How many lone pairs of electrons exist on the following molecule?

BF3

1

0

9

10

11

Explanation

.. ..

:F — B — F: Boron can have a violated octet (6 e-) and each F has 3 lone pairs

.. | .. for a total of 9 pairs of unpaired electrons

:F:

..

3

What is the Lewis dot structure for ?

1-1

2-1

3-1

4-1

5-1

Explanation

When drawing a Lewis dot structure, we are always trying to reach an electron count where all atoms involved are stable and (usually) have full octets. We are also trying to estabilsh a structure in which we have the smallest formal charge possible. The general rule is first to draw out all of the elements involved and their valence electrons, then start piecing them together trying to reduce the formal charge and get all elements involved to an octet. There are a couple exceptions to the octet rule.

In this case, boron actually has an incomplete octet. Though there are resonance forms in which boron has a full octet, when you calculate the formal charge of these configurations it will not be zero.

4

What is the Lewis dot structure for ?

1-1

2-1

3-1

4-1

5-1

Explanation

When drawing a Lewis dot structure, we are always trying to reach an electron count where all atoms involved are stable and (usually) have full octets. We are also trying to estabilsh a structure in which we have the smallest formal charge possible. The general rule is first to draw out all of the elements involved and their valence electrons, then start piecing them together trying to reduce the formal charge and get all elements involved to an octet. There are a couple exceptions to the octet rule.

In this case, boron actually has an incomplete octet. Though there are resonance forms in which boron has a full octet, when you calculate the formal charge of these configurations it will not be zero.

5

A compound is comprised of sodium and element X. The compound has a molar mass of and is sodium by mass. The compound consists of a 1:1 ratio between sodium and element X. Find the molecular and empirical formulas of the compound, including the identity of element X.

Molecular:

Empirical:

Molecular:

Empirical:

Molecular:

Empirical:

Molecular:

Empirical:

None of these are correct

Explanation

Use the molar mass and percent by mass of sodium to find the moles of sodium in the compound.

Since the compound consists of only sodium and element X, we can subtract to find the percent by mass of element X.

Use the percent by mass to find the mass per mole of compound of element X.

Because there is a 1:1 ratio, between sodium and element X, they must have an equal number of moles in the compound. Since there are 2 moles of sodium, there must also be 2 moles of element X. Divide the mass of element X by the moles of element X to find its atomic mass and its identity.

By consulting a periodic table, we can find that element X is oxygen.

Therefore element X is Oxygen.

Therefore, the molecular formula is and the empirical formula is .

6

Which of the following compounds contains an atom that does NOT satisfy the octet rule?

I.

II.

III.

IV.

I and IV

I, II, and IV

II and III

I and II

IV only

Explanation

BCl3 only has six electrons around boron, while NO2 (with an odd number of electrons) would have only 7 electrons around the central nitrogen.

7

Which of the following compounds contains an atom that does NOT satisfy the octet rule?

I.

II.

III.

IV.

I and IV

I, II, and IV

II and III

I and II

IV only

Explanation

BCl3 only has six electrons around boron, while NO2 (with an odd number of electrons) would have only 7 electrons around the central nitrogen.

8

A compound is comprised of sodium and element X. The compound has a molar mass of and is sodium by mass. The compound consists of a 1:1 ratio between sodium and element X. Find the molecular and empirical formulas of the compound, including the identity of element X.

Molecular:

Empirical:

Molecular:

Empirical:

Molecular:

Empirical:

Molecular:

Empirical:

None of these are correct

Explanation

Use the molar mass and percent by mass of sodium to find the moles of sodium in the compound.

Since the compound consists of only sodium and element X, we can subtract to find the percent by mass of element X.

Use the percent by mass to find the mass per mole of compound of element X.

Because there is a 1:1 ratio, between sodium and element X, they must have an equal number of moles in the compound. Since there are 2 moles of sodium, there must also be 2 moles of element X. Divide the mass of element X by the moles of element X to find its atomic mass and its identity.

By consulting a periodic table, we can find that element X is oxygen.

Therefore element X is Oxygen.

Therefore, the molecular formula is and the empirical formula is .

9

Which answer option correctly depicts the Lewis dot structure of sodium chloride?

1

2

3

4

5

Explanation

When drawing a Lewis dot structure, we are always trying to reach an electron count where all atoms involved are stable and (usually) have full octets. We are also trying to estabilsh a structure in which we have the smallest formal charge possible. The general rule is first to draw out all of the elements involved and their valence electrons, then start piecing them together trying to reduce the formal charge and get all elements involved to an octet. There are a couple exceptions to the octet rule.

Sodium and chlorine form an ionic bond, meaning that one atom will donate an electron and the other will receive it. This gives each atom a charge. Chlorine has seven valence electrons, while sodium has one valence electron. For each atom to arrive at an octet, sodium will need to lose one electron and chlorine will need to gain one electron. This would give chlorine a negative charge, and sodium a positive charge.

Thus, the answer is a sodium with a positive charge (due to one lost electron) and a chlorine with eight electrons and a negative charge (due to one electron gained).

10

Which answer option correctly depicts the Lewis dot structure of sodium chloride?

1

2

3

4

5

Explanation

When drawing a Lewis dot structure, we are always trying to reach an electron count where all atoms involved are stable and (usually) have full octets. We are also trying to estabilsh a structure in which we have the smallest formal charge possible. The general rule is first to draw out all of the elements involved and their valence electrons, then start piecing them together trying to reduce the formal charge and get all elements involved to an octet. There are a couple exceptions to the octet rule.

Sodium and chlorine form an ionic bond, meaning that one atom will donate an electron and the other will receive it. This gives each atom a charge. Chlorine has seven valence electrons, while sodium has one valence electron. For each atom to arrive at an octet, sodium will need to lose one electron and chlorine will need to gain one electron. This would give chlorine a negative charge, and sodium a positive charge.

Thus, the answer is a sodium with a positive charge (due to one lost electron) and a chlorine with eight electrons and a negative charge (due to one electron gained).

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