Calculating Equilibrium Concentrations
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AP Chemistry › Calculating Equilibrium Concentrations
In a 1.00 L container at constant temperature, the equilibrium $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ is established. Initially, $\mathrm{H_2} = 0.80\ \mathrm{M}$, $\mathrm{I_2} = 0.80\ \mathrm{M}$, and $\mathrm{HI} = 8.00\ \mathrm{M}$. The value of $K_c$ is 64.0. Using an ICE table (assume only $\mathrm{HI}$ changes appreciably), what is the equilibrium concentration of $\mathrm{HI}$?
9.00 M
7.50 M
8.00 M
8.50 M
7.00 M
Explanation
This problem requires calculating equilibrium concentrations for the reaction H₂(g) + I₂(g) ⇌ 2HI(g). With initial concentrations [H₂] = 0.80 M, [I₂] = 0.80 M, and [HI] = 8.00 M, we calculate Q = [HI]²/([H₂][I₂]) = (8.00)²/(0.80)(0.80) = 100. Since Q > Kc (100 > 64), the reaction shifts left. Using an ICE table where [HI] changes by -2x: [H₂] = 0.80 + x, [I₂] = 0.80 + x, and [HI] = 8.00 - 2x at equilibrium. Substituting into Kc = 64: (8.00 - 2x)²/((0.80 + x)²) = 64, taking the square root gives (8.00 - 2x)/(0.80 + x) = 8. Solving: 8.00 - 2x = 6.40 + 8x, which yields x = 0.25, so [HI]eq = 8.00 - 2(0.25) = 7.50 M. The distractor 8.00 M (choice D) incorrectly assumes the system is already at equilibrium. The strategy involves calculating Q, determining shift direction, and solving the equilibrium expression with proper stoichiometry.
In a 1.00 L flask at a constant temperature, the reversible reaction $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ is established. Initially, $\mathrm{H_2} = 1.00\ \mathrm{M}$, $\mathrm{I_2} = 1.00\ \mathrm{M}$, and $\mathrm{HI} = 10.0\ \mathrm{M}$. The equilibrium constant is $K_c = 100$. Using an ICE table (assume only $\mathrm{HI}$ changes appreciably), what is the equilibrium concentration of $\mathrm{HI}$?
9.00 M
11.0 M
10.5 M
9.50 M
10.0 M
Explanation
This problem requires calculating equilibrium concentrations using an ICE table. For the reaction H₂(g) + I₂(g) ⇌ 2HI(g), we set up the ICE table with initial concentrations [H₂] = 1.00 M, [I₂] = 1.00 M, and [HI] = 10.0 M. Since we're told only [HI] changes appreciably, we let the change in [HI] be -2x (negative because Q > K, so the reaction shifts left), making changes in [H₂] and [I₂] each +x. At equilibrium: [H₂] = 1.00 + x, [I₂] = 1.00 + x, and [HI] = 10.0 - 2x. Substituting into Kc = [HI]²/([H₂][I₂]) = 100 gives (10.0 - 2x)²/((1.00 + x)(1.00 + x)) = 100, which simplifies to (10.0 - 2x)² = 100(1.00 + x)². Taking the square root: 10.0 - 2x = 10(1.00 + x), solving gives x = 0.25, so [HI]eq = 10.0 - 2(0.25) = 9.50 M. A common error (choice B, 10.0 M) assumes no change occurs because the initial [HI] seems large. The key strategy is to properly set up the ICE table with correct stoichiometric coefficients and solve the resulting equation systematically.
In a 1.00 L flask at constant temperature, the reaction $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ comes to equilibrium. Initially, $\mathrm{H_2} = 0.70\ \mathrm{M}$, $\mathrm{I_2} = 0.70\ \mathrm{M}$, and $\mathrm{HI} = 7.00\ \mathrm{M}$. Given $K_c = 49.0$, use an ICE table (assume only $\mathrm{HI}$ changes appreciably) to find the equilibrium concentration of $\mathrm{HI}$.
7.20 M
7.00 M
6.00 M
6.80 M
6.50 M
Explanation
This problem requires calculating equilibrium concentrations for H₂(g) + I₂(g) ⇌ 2HI(g). With initial concentrations [H₂] = 0.70 M, [I₂] = 0.70 M, and [HI] = 7.00 M, we calculate Q = [HI]²/([H₂][I₂]) = (7.00)²/(0.70)(0.70) = 100. Since Q > Kc (100 > 49), the reaction shifts left to reach equilibrium. Setting up the ICE table with [HI] decreasing by 2x: [H₂] = 0.70 + x, [I₂] = 0.70 + x, and [HI] = 7.00 - 2x at equilibrium. Substituting into Kc = 49: (7.00 - 2x)²/((0.70 + x)²) = 49, taking the square root gives (7.00 - 2x)/(0.70 + x) = 7. Solving: 7.00 - 2x = 4.90 + 7x, which gives x = 0.10, so [HI]eq = 7.00 - 2(0.10) = 6.80 M. The distractor 7.00 M (choice B) incorrectly assumes the system is already at equilibrium. The key strategy is to always check Q versus K and solve systematically using the equilibrium expression.
In a 1.00 L flask at a constant temperature, the reaction $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ reaches equilibrium. Initially, $\mathrm{H_2} = 0.50\ \mathrm{M}$, $\mathrm{I_2} = 0.50\ \mathrm{M}$, and $\mathrm{HI} = 5.00\ \mathrm{M}$. The equilibrium constant is $K_c = 25.0$. Using an ICE table (assume only $\mathrm{HI}$ changes appreciably), what is the equilibrium concentration of $\mathrm{HI}$?
4.00 M
6.00 M
5.50 M
4.50 M
5.00 M
Explanation
This problem involves calculating equilibrium concentrations for H₂(g) + I₂(g) ⇌ 2HI(g). Setting up the ICE table with initial values [H₂] = 0.50 M, [I₂] = 0.50 M, and [HI] = 5.00 M, we need to determine which direction the reaction shifts. Calculating Q = [HI]²/([H₂][I₂]) = (5.00)²/(0.50)(0.50) = 100, and since Q > Kc (100 > 25), the reaction shifts left. With [HI] changing by -2x, we have [H₂] = 0.50 + x, [I₂] = 0.50 + x, and [HI] = 5.00 - 2x at equilibrium. Substituting into Kc = 25: (5.00 - 2x)²/((0.50 + x)²) = 25, taking the square root gives (5.00 - 2x)/(0.50 + x) = 5. Solving: 5.00 - 2x = 2.50 + 5x, which gives x = 0.25, so [HI]eq = 5.00 - 2(0.25) = 4.50 M. A tempting distractor (choice D, 5.00 M) incorrectly assumes the system is already at equilibrium. The strategy is to always calculate Q first, compare to K to determine shift direction, then solve the equilibrium expression.
A 1.00 L flask contains a mixture for the reaction $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ at constant temperature. Initially, $\mathrm{H_2} = 0.30\ \mathrm{M}$, $\mathrm{I_2} = 0.30\ \mathrm{M}$, and $\mathrm{HI} = 6.00\ \mathrm{M}$. If $K_c = 36.0$, and an ICE table is used with the assumption that only $\mathrm{HI}$ changes appreciably, what is the equilibrium concentration of $\mathrm{HI}$?
5.00 M
5.70 M
6.50 M
6.00 M
5.50 M
Explanation
This question involves calculating equilibrium concentrations for H₂(g) + I₂(g) ⇌ 2HI(g). Starting with [H₂] = 0.30 M, [I₂] = 0.30 M, and [HI] = 6.00 M, we calculate Q = [HI]²/([H₂][I₂]) = (6.00)²/(0.30)(0.30) = 400. Since Q > Kc (400 > 36), the reaction must shift left to reach equilibrium. Setting up the ICE table with [HI] decreasing by 2x: [H₂] = 0.30 + x, [I₂] = 0.30 + x, and [HI] = 6.00 - 2x at equilibrium. Substituting into Kc = 36: (6.00 - 2x)²/((0.30 + x)²) = 36, taking the square root gives (6.00 - 2x)/(0.30 + x) = 6. Solving: 6.00 - 2x = 1.80 + 6x, which gives x = 0.25, so [HI]eq = 6.00 - 2(0.25) = 5.50 M. A common error (choice C, 6.00 M) assumes no shift occurs. The key is to always check Q versus K and set up the ICE table with correct stoichiometric relationships.
In a 1.00 L flask at constant temperature, the equilibrium $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ is established. Initially, $\mathrm{H_2} = 0.25\ \mathrm{M}$, $\mathrm{I_2} = 0.25\ \mathrm{M}$, and $\mathrm{HI} = 5.00\ \mathrm{M}$. If $K_c = 100$, and an ICE table is used with the assumption that only $\mathrm{HI}$ changes appreciably, what is the equilibrium concentration of $\mathrm{HI}$?
4.75 M
5.25 M
4.50 M
4.90 M
5.00 M
Explanation
This problem involves calculating equilibrium concentrations for H₂(g) + I₂(g) ⇌ 2HI(g). Starting with [H₂] = 0.25 M, [I₂] = 0.25 M, and [HI] = 5.00 M, we calculate Q = [HI]²/([H₂][I₂]) = (5.00)²/(0.25)(0.25) = 400. Since Q > Kc (400 > 100), the reaction must shift left. Setting up the ICE table with [HI] changing by -2x: [H₂] = 0.25 + x, [I₂] = 0.25 + x, and [HI] = 5.00 - 2x at equilibrium. Substituting into Kc = 100: (5.00 - 2x)²/((0.25 + x)²) = 100, taking the square root gives (5.00 - 2x)/(0.25 + x) = 10. Solving: 5.00 - 2x = 2.50 + 10x, which gives x = 0.125, so [HI]eq = 5.00 - 2(0.125) = 4.75 M. A common mistake (choice D, 5.00 M) assumes the initial concentration doesn't change. The key is recognizing that Q > K requires a leftward shift, even with seemingly balanced initial concentrations.
A student prepares a 1.00 L mixture for the reversible reaction $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$ at constant temperature. Initially, $\mathrm{H_2} = 0.20\ \mathrm{M}$, $\mathrm{I_2} = 0.20\ \mathrm{M}$, and $\mathrm{HI} = 4.00\ \mathrm{M}$. Given $K_c = 100$, and using an ICE table with the assumption that only $\mathrm{HI}$ changes appreciably, what is $\mathrm{HI}$ at equilibrium?
3.60 M
3.80 M
4.00 M
4.40 M
4.20 M
Explanation
This question asks for equilibrium concentration calculations using an ICE table approach. For H₂(g) + I₂(g) ⇌ 2HI(g) with initial concentrations [H₂] = 0.20 M, [I₂] = 0.20 M, and [HI] = 4.00 M, we first calculate Q = [HI]²/([H₂][I₂]) = (4.00)²/(0.20)(0.20) = 400. Since Q > Kc (400 > 100), the reaction shifts left to reach equilibrium. Setting up the ICE table with [HI] decreasing by 2x gives: [H₂] = 0.20 + x, [I₂] = 0.20 + x, and [HI] = 4.00 - 2x at equilibrium. Substituting into Kc = 100: (4.00 - 2x)²/((0.20 + x)²) = 100, taking the square root yields (4.00 - 2x)/(0.20 + x) = 10. Solving: 4.00 - 2x = 2.00 + 10x, which gives x = 0.10, so [HI]eq = 4.00 - 2(0.10) = 3.80 M. The distractor 4.00 M (choice C) incorrectly assumes no change from initial conditions. The key is recognizing that even small initial reactant concentrations require the system to shift when Q ≠ K.
A 1.00 L container is set up at constant temperature for the reaction $\mathrm{H_2(g) + I_2(g) \rightleftharpoons 2HI(g)}$. Initially, $\mathrm{H_2} = 0.40\ \mathrm{M}$, $\mathrm{I_2} = 0.40\ \mathrm{M}$, and $\mathrm{HI} = 2.00\ \mathrm{M}$. The equilibrium constant is $K_c = 4.00$. Using an ICE table (assume only $\mathrm{HI}$ changes appreciably), what is $\mathrm{HI}$ at equilibrium?
2.20 M
1.60 M
2.40 M
1.80 M
2.00 M
Explanation
This question requires calculating equilibrium concentrations for H₂(g) + I₂(g) ⇌ 2HI(g). With initial concentrations [H₂] = 0.40 M, [I₂] = 0.40 M, and [HI] = 2.00 M, we calculate Q = [HI]²/([H₂][I₂]) = (2.00)²/(0.40)(0.40) = 25. Since Q > Kc (25 > 4), the reaction shifts left to reach equilibrium. Using an ICE table where [HI] decreases by 2x: [H₂] = 0.40 + x, [I₂] = 0.40 + x, and [HI] = 2.00 - 2x at equilibrium. Substituting into Kc = 4: (2.00 - 2x)²/((0.40 + x)²) = 4, taking the square root gives (2.00 - 2x)/(0.40 + x) = 2. Solving: 2.00 - 2x = 0.80 + 2x, which yields x = 0.10, so [HI]eq = 2.00 - 2(0.10) = 1.80 M. The distractor 2.00 M (choice C) incorrectly assumes no change occurs. The strategy is to compare Q to K, determine shift direction, and solve using proper stoichiometry.
The following equilibrium occurs in aqueous solution:
$\text{C(aq)} \rightleftharpoons \text{D(aq)}$
Initially, $\text{C}_0 = 1.20,\text{M}$ and $\text{D}_0 = 0.010,\text{M}$. The equilibrium constant is $K_c = 0.030$.
Using an ICE table with a single variable, what is the equilibrium concentration of $\text{D(aq)}$?
0.010 M
0.026 M
0.036 M
0.020 M
0.030 M
Explanation
This problem involves calculating equilibrium concentrations for C(aq) ⇌ D(aq). Setting up the ICE table with [C]₀ = 1.20 M and [D]₀ = 0.010 M, the changes are -x and +x, giving [C] = 1.20 - x and [D] = 0.010 + x at equilibrium. Using Kc = [D]/[C] = 0.030: (0.010 + x)/(1.20 - x) = 0.030. Solving: 0.010 + x = 0.030(1.20 - x) = 0.036 - 0.030x, which gives 1.030x = 0.026, so x = 0.0252. Therefore, [D]eq = 0.010 + 0.0252 = 0.0352 M ≈ 0.036 M. A tempting distractor might be 0.030 M, which incorrectly uses the equilibrium constant as the concentration. The transferable strategy is to always solve for x algebraically and add it to the initial concentration, never confusing Kc with actual concentrations.
The equilibrium $\mathrm{H_2(g) + Cl_2(g) \rightleftharpoons 2HCl(g)}$ is established in a 1.0 L flask. Initially, $\mathrm{H_2}=0.010,\mathrm{M}$, $\mathrm{Cl_2}=1.00,\mathrm{M}$, and $\mathrm{HCl}=0,\mathrm{M}$. At this temperature, $K_c=9.0\times 10^{-4}$. Using an ICE table and treating $\mathrm{Cl_2}$ as effectively constant, what is the equilibrium concentration of $\mathrm{HCl}$?
3.0×10⁻³ M
6.0×10⁻³ M
1.0×10⁻² M
9.0×10⁻⁴ M
3.0×10⁻² M
Explanation
This problem requires calculating equilibrium concentrations for H₂(g) + Cl₂(g) ⇌ 2HCl(g). Setting up an ICE table with initial values [H₂]=0.010 M, [Cl₂]=1.00 M, and [HCl]=0 M, we can treat [Cl₂] as constant due to its large initial concentration. The equilibrium expression is Kc = [HCl]²/([H₂][Cl₂]) = 9.0×10⁻⁴. If x mol/L of H₂ reacts, then [HCl]=2x at equilibrium and [H₂]=0.010-x. For small x, the expression becomes (2x)²/(0.010×1.00) = 9.0×10⁻⁴, which gives 4x²/0.010 = 9.0×10⁻⁴, so x² = 2.25×10⁻⁶, and x = 1.5×10⁻³ M. Therefore, [HCl] = 2x = 3.0×10⁻³ M. A common error would be to use [HCl]=x instead of [HCl]=2x in the ICE table, leading to an incorrect answer of 1.5×10⁻³ M. The key strategy is to carefully track stoichiometric coefficients when setting up the ICE table and ensure the equilibrium expression reflects the balanced equation.