Types of Phase Changes - AP Chemistry

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Question

Liquid water at room temperature is cooled to -75O C

Which of the following descriptions applies to the process outlined above?

I: A physical change occurred

II: A chemical change occurred

III: There was a change in entropy

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Answer

A physical change is a process where the physical properties of a substance are changed. Here water undergoes a phase change from the more disordered liquid state to the more ordered solid state, which is indeed a physical change. A chemical change describes when a substance undergoes a change in the identity of its constituent molecules. Here although the water has gone from the liquid phase to the solid phase it is still composed only of water molecules so a chemical change has not occured. Entropy describes the degree to which a system is ordered. Here we do have a change in entropy becasue the liquid water was more disordered than the solid water.

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