All flashcards
Flashcard 1: What does a high pKa indicate about the strength of an acid?
Answer: Weak acid. High pKa means low ionization tendency.
Flashcard 2: What is the pH of a neutral solution at 25°C?
Answer: pH = 7. Equal concentrations of H+ and OH− ions.
Flashcard 3: If Ka is small, is the acid strong or weak?
Answer: Weak acid. Small Ka means limited ionization.
Flashcard 4: Find the pOH of a solution with pH = 2.
Answer: pOH = 12. Using the relationship pH + pOH = 14.
Flashcard 5: Calculate the pH of a 0.1 M HCl solution.
Answer: pH = 1. HCl completely ionizes; [H+] = 0.1 M.
Flashcard 6: What does a high pKa indicate about the strength of an acid?
Answer: Weak acid. High pKa means low ionization tendency.
Flashcard 7: What is the pKb of a strong base?
Answer: Low pKb. Strong bases have very negative pKb values.
Flashcard 8: What is the pH of a 0.1 M acetic acid solution with Ka=1.8×10−5?
Answer: pH ≈ 2.88. Using the weak acid approximation formula.
Flashcard 9: Identify the term for the negative logarithm of the base dissociation constant.
Answer: pKb. Standard notation for base dissociation constant.
Flashcard 10: Calculate the pKb for a base with Kb=4.5×10−8.
Answer: pKb ≈ 7.35. Using pKb=−log(4.5×10−8).
Flashcard 11: What is the formula for calculating pOH?
Answer: pOH=−log10[OH−]. Negative log base 10 of hydroxide ion concentration.
Flashcard 12: What is the formula for the ion product of water (Kw) at 25°C?
Answer: Kw=1.0×10−14. Ion product constant for water at standard temperature.
Flashcard 13: What does a low pKb indicate about the strength of a base?
Answer: Strong base. Low pKb means high ionization tendency.
Flashcard 14: Calculate the [OH−] for a solution with pOH = 8.
Answer: [OH−] = 1.0×10−8 M. Using [OH−] = 10−pOH relationship.
Flashcard 15: What is the relationship between Ka and pKa?
Answer: pKa=−log10(Ka). Takes the negative logarithm of the acid constant.
Flashcard 16: Define the term 'acid dissociation constant' (Ka).
Answer: Ka is the equilibrium constant for the dissociation of an acid. Measures the extent of acid ionization in solution.
Flashcard 17: What is the formula for the base dissociation constant (Kb)?
Answer: Kb is the equilibrium constant for the dissociation of a base. Measures the extent of base ionization in solution.
Flashcard 18: Calculate the [H+] for a solution with pH = 6.
Answer: [H+] = 1.0×10−6 M. Using [H+] = 10−pH relationship.
Flashcard 19: Identify the pH range of a basic solution.
Answer: pH > 7. Higher OH− concentration than neutral solution.
Flashcard 20: Determine the pOH of a solution with [OH−] = 1.0×10−4 M.
Answer: pOH = 4. Using pOH=−log(1.0×10−4)=4.
Flashcard 21: What is the pH of a 0.01 M NH3 solution (Kb=1.8×10−5)?
Answer: pH ≈ 11.13. Using weak base approximation with given Kb.
Flashcard 22: Calculate the pKa for an acid with Ka=3.2×10−4.
Answer: pKa ≈ 3.5. Using pKa=−log(3.2×10−4).
Flashcard 23: If Ka is large, is the acid strong or weak?
Answer: Strong acid. Large Ka means extensive ionization.
Flashcard 24: Determine the pH of a 0.01 M NaOH solution.
Answer: pH = 12. NaOH gives [OH−] = 0.01 M, so pOH = 2.
Flashcard 25: Which has a higher pH: 0.1 M HCl or 0.1 M CH3COOH?
Answer: 0.1 M CH3COOH. Acetic acid is weak, HCl is strong acid.
Flashcard 26: Calculate Kb if Ka=1.0×10−5 for a conjugate acid-base pair.
Answer: Kb=1.0×10−9. Using Ka×Kb=1.0×10−14.
Flashcard 27: What is the pH of pure water at 25°C?
Answer: pH = 7. Autoionization gives equal H+ and OH−.
Flashcard 28: Calculate the pH of a solution with [H+] = 1.0×10−3 M.
Answer: pH = 3. Using pH=−log(1.0×10−3)=3.
Flashcard 29: State the relationship between pH and pOH in water at 25°C.
Answer: pH+pOH=14. Based on the ion product of water at 25°C.
Flashcard 30: If pKa is 4, what is the strength of the acid?
Answer: Weak acid. pKa = 4 indicates moderate acid strength.