All flashcards
Flashcard 1: State Hess's Law.
Answer: The total enthalpy change is the same no matter how the reaction is carried out. Enthalpy is path-independent, only depends on states.
Flashcard 2: What is a non-spontaneous process?
Answer: A process that requires continuous external energy input. Thermodynamically unfavorable without energy input.
Flashcard 3: What is the standard state condition for enthalpy changes?
Answer: 1 atm pressure and 298 K temperature. Reference conditions for thermodynamic measurements.
Flashcard 4: Which type of reaction is combustion?
Answer: Combustion is an exothermic reaction. Burning reactions always release energy.
Flashcard 5: State the First Law of Thermodynamics.
Answer: Energy cannot be created or destroyed, only transformed. Conservation of energy principle in thermodynamics.
Flashcard 6: Identify whether the rusting of iron is endothermic or exothermic.
Answer: Rusting of iron is exothermic. Oxidation reactions release energy.
Flashcard 7: What is meant by a spontaneous process?
Answer: A process that occurs without external energy input. Thermodynamically favorable under given conditions.
Flashcard 8: State the enthalpy change for an exothermic reaction.
Answer: △H is negative. Energy is released during the reaction.
Flashcard 9: State the enthalpy change for an endothermic reaction.
Answer: △H is positive. Energy is absorbed during the reaction.
Flashcard 10: What is the sign of △H for a reaction that releases heat?
Answer: The sign of △H is negative. Heat release means negative enthalpy change.
Flashcard 11: Identify an endothermic process in everyday life.
Answer: Photosynthesis is an endothermic process. Light energy is absorbed to drive the reaction.
Flashcard 12: Define enthalpy (H) in thermodynamics.
Answer: Enthalpy is the total heat content of a system. It's a state function measuring internal energy.
Flashcard 13: Is dissolving ammonium nitrate in water endothermic or exothermic?
Answer: It is an endothermic process. Dissolution breaks ionic bonds, absorbing energy.
Flashcard 14: Calculate △H: Reactants = 200 kJ, Products = 150 kJ.
Answer: △H=150−200=−50 kJ. Products have lower energy than reactants.
Flashcard 15: Which phase change is endothermic: melting or freezing?
Answer: Melting is endothermic. Energy is needed to break intermolecular forces.
Flashcard 16: What is the sign of △H for a reaction that absorbs heat?
Answer: The sign of △H is positive. Heat absorption means positive enthalpy change.
Flashcard 17: What is meant by activation energy?
Answer: The minimum energy required to initiate a reaction. Energy barrier that must be overcome.
Flashcard 18: What does a calorimeter measure?
Answer: A calorimeter measures the heat of chemical reactions. Device that quantifies energy changes in reactions.
Flashcard 19: What is the heat of reaction?
Answer: The heat absorbed or released during a chemical reaction. Energy change when reactants become products.
Flashcard 20: What does a positive △H indicate about heat flow?
Answer: Heat is absorbed by the system. System gains energy from surroundings.
Flashcard 21: Identify whether the evaporation of alcohol is endothermic or exothermic.
Answer: Evaporation of alcohol is endothermic. Phase change requires energy input.
Flashcard 22: Identify whether lighting a match is endothermic or exothermic.
Answer: Lighting a match is exothermic. Combustion of match head releases energy.
Flashcard 23: Identify whether boiling water is endothermic or exothermic.
Answer: Boiling water is an endothermic process. Energy is required to overcome intermolecular forces.
Flashcard 24: What is the standard state condition for enthalpy changes?
Answer: 1 atm pressure and 298 K temperature. Reference conditions for thermodynamic measurements.
Flashcard 25: Which type of reaction is combustion?
Answer: Combustion is an exothermic reaction. Burning reactions always release energy.
Flashcard 26: Differentiate between system and surroundings in thermodynamics.
Answer: The system is the part of the universe being studied; surroundings are everything else. Defines boundaries for energy transfer analysis.
Flashcard 27: What is meant by activation energy?
Answer: The minimum energy required to initiate a reaction. Energy barrier that must be overcome.
Flashcard 28: Identify whether freezing water is endothermic or exothermic.
Answer: Freezing water is an exothermic process. Energy is released as molecules form ordered structure.
Flashcard 29: State the enthalpy change for an endothermic reaction.
Answer: △H is positive. Energy is absorbed during the reaction.
Flashcard 30: What is the sign of △H for a reaction that releases heat?
Answer: The sign of △H is negative. Heat release means negative enthalpy change.