Endothermic and Exothermic Processes - AP Chemistry
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State Hess's Law.
State Hess's Law.
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The total enthalpy change is the same no matter how the reaction is carried out. Enthalpy is path-independent, only depends on states.
The total enthalpy change is the same no matter how the reaction is carried out. Enthalpy is path-independent, only depends on states.
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What is a non-spontaneous process?
What is a non-spontaneous process?
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A process that requires continuous external energy input. Thermodynamically unfavorable without energy input.
A process that requires continuous external energy input. Thermodynamically unfavorable without energy input.
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What is the standard state condition for enthalpy changes?
What is the standard state condition for enthalpy changes?
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1 atm pressure and 298 K temperature. Reference conditions for thermodynamic measurements.
1 atm pressure and 298 K temperature. Reference conditions for thermodynamic measurements.
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Which type of reaction is combustion?
Which type of reaction is combustion?
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Combustion is an exothermic reaction. Burning reactions always release energy.
Combustion is an exothermic reaction. Burning reactions always release energy.
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State the First Law of Thermodynamics.
State the First Law of Thermodynamics.
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Energy cannot be created or destroyed, only transformed. Conservation of energy principle in thermodynamics.
Energy cannot be created or destroyed, only transformed. Conservation of energy principle in thermodynamics.
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Identify whether the rusting of iron is endothermic or exothermic.
Identify whether the rusting of iron is endothermic or exothermic.
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Rusting of iron is exothermic. Oxidation reactions release energy.
Rusting of iron is exothermic. Oxidation reactions release energy.
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What is meant by a spontaneous process?
What is meant by a spontaneous process?
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A process that occurs without external energy input. Thermodynamically favorable under given conditions.
A process that occurs without external energy input. Thermodynamically favorable under given conditions.
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State the enthalpy change for an exothermic reaction.
State the enthalpy change for an exothermic reaction.
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$\triangle H$ is negative. Energy is released during the reaction.
$\triangle H$ is negative. Energy is released during the reaction.
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State the enthalpy change for an endothermic reaction.
State the enthalpy change for an endothermic reaction.
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$\triangle H$ is positive. Energy is absorbed during the reaction.
$\triangle H$ is positive. Energy is absorbed during the reaction.
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What is the sign of $\triangle H$ for a reaction that releases heat?
What is the sign of $\triangle H$ for a reaction that releases heat?
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The sign of $\triangle H$ is negative. Heat release means negative enthalpy change.
The sign of $\triangle H$ is negative. Heat release means negative enthalpy change.
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Identify an endothermic process in everyday life.
Identify an endothermic process in everyday life.
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Photosynthesis is an endothermic process. Light energy is absorbed to drive the reaction.
Photosynthesis is an endothermic process. Light energy is absorbed to drive the reaction.
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Define enthalpy ($H$) in thermodynamics.
Define enthalpy ($H$) in thermodynamics.
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Enthalpy is the total heat content of a system. It's a state function measuring internal energy.
Enthalpy is the total heat content of a system. It's a state function measuring internal energy.
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Is dissolving ammonium nitrate in water endothermic or exothermic?
Is dissolving ammonium nitrate in water endothermic or exothermic?
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It is an endothermic process. Dissolution breaks ionic bonds, absorbing energy.
It is an endothermic process. Dissolution breaks ionic bonds, absorbing energy.
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Calculate $\triangle H$: Reactants = 200 kJ, Products = 150 kJ.
Calculate $\triangle H$: Reactants = 200 kJ, Products = 150 kJ.
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$\triangle H = 150 - 200 = -50$ kJ. Products have lower energy than reactants.
$\triangle H = 150 - 200 = -50$ kJ. Products have lower energy than reactants.
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Which phase change is endothermic: melting or freezing?
Which phase change is endothermic: melting or freezing?
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Melting is endothermic. Energy is needed to break intermolecular forces.
Melting is endothermic. Energy is needed to break intermolecular forces.
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What is the sign of $\triangle H$ for a reaction that absorbs heat?
What is the sign of $\triangle H$ for a reaction that absorbs heat?
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The sign of $\triangle H$ is positive. Heat absorption means positive enthalpy change.
The sign of $\triangle H$ is positive. Heat absorption means positive enthalpy change.
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What is meant by activation energy?
What is meant by activation energy?
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The minimum energy required to initiate a reaction. Energy barrier that must be overcome.
The minimum energy required to initiate a reaction. Energy barrier that must be overcome.
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What does a calorimeter measure?
What does a calorimeter measure?
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A calorimeter measures the heat of chemical reactions. Device that quantifies energy changes in reactions.
A calorimeter measures the heat of chemical reactions. Device that quantifies energy changes in reactions.
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What is the heat of reaction?
What is the heat of reaction?
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The heat absorbed or released during a chemical reaction. Energy change when reactants become products.
The heat absorbed or released during a chemical reaction. Energy change when reactants become products.
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What does a positive $\triangle H$ indicate about heat flow?
What does a positive $\triangle H$ indicate about heat flow?
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Heat is absorbed by the system. System gains energy from surroundings.
Heat is absorbed by the system. System gains energy from surroundings.
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Identify whether the evaporation of alcohol is endothermic or exothermic.
Identify whether the evaporation of alcohol is endothermic or exothermic.
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Evaporation of alcohol is endothermic. Phase change requires energy input.
Evaporation of alcohol is endothermic. Phase change requires energy input.
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Identify whether lighting a match is endothermic or exothermic.
Identify whether lighting a match is endothermic or exothermic.
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Lighting a match is exothermic. Combustion of match head releases energy.
Lighting a match is exothermic. Combustion of match head releases energy.
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Identify whether boiling water is endothermic or exothermic.
Identify whether boiling water is endothermic or exothermic.
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Boiling water is an endothermic process. Energy is required to overcome intermolecular forces.
Boiling water is an endothermic process. Energy is required to overcome intermolecular forces.
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What is the standard state condition for enthalpy changes?
What is the standard state condition for enthalpy changes?
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1 atm pressure and 298 K temperature. Reference conditions for thermodynamic measurements.
1 atm pressure and 298 K temperature. Reference conditions for thermodynamic measurements.
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Which type of reaction is combustion?
Which type of reaction is combustion?
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Combustion is an exothermic reaction. Burning reactions always release energy.
Combustion is an exothermic reaction. Burning reactions always release energy.
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Differentiate between system and surroundings in thermodynamics.
Differentiate between system and surroundings in thermodynamics.
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The system is the part of the universe being studied; surroundings are everything else. Defines boundaries for energy transfer analysis.
The system is the part of the universe being studied; surroundings are everything else. Defines boundaries for energy transfer analysis.
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What is meant by activation energy?
What is meant by activation energy?
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The minimum energy required to initiate a reaction. Energy barrier that must be overcome.
The minimum energy required to initiate a reaction. Energy barrier that must be overcome.
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Identify whether freezing water is endothermic or exothermic.
Identify whether freezing water is endothermic or exothermic.
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Freezing water is an exothermic process. Energy is released as molecules form ordered structure.
Freezing water is an exothermic process. Energy is released as molecules form ordered structure.
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State the enthalpy change for an endothermic reaction.
State the enthalpy change for an endothermic reaction.
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$\triangle H$ is positive. Energy is absorbed during the reaction.
$\triangle H$ is positive. Energy is absorbed during the reaction.
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What is the sign of $\triangle H$ for a reaction that releases heat?
What is the sign of $\triangle H$ for a reaction that releases heat?
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The sign of $\triangle H$ is negative. Heat release means negative enthalpy change.
The sign of $\triangle H$ is negative. Heat release means negative enthalpy change.
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