AP Chemistry Flashcards: Calculating Equilibrium Concentrations

Study Calculating Equilibrium Concentrations in AP Chemistry with focused flashcards that help you recognize the idea, recall the key rule, and apply it in practice-style prompts.

AP Chemistry

Calculating Equilibrium Concentrations

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For the reaction CH4(g)+2O2(g)CO2(g)+2H2O(g)CH_4(g) + 2O_2(g) \rightleftharpoons CO_2(g) + 2H_2O(g), write the KcK_c expression.

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ANSWER

Kc=[CO2][H2O]2[CH4][O2]2K_c = \frac{[CO_2][H_2O]^2}{[CH_4][O_2]^2}. Products over reactants, each raised to their stoichiometric coefficients.

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Flashcard 1: For the reaction CH4(g)+2O2(g)CO2(g)+2H2O(g)CH_4(g) + 2O_2(g) \rightleftharpoons CO_2(g) + 2H_2O(g), write the KcK_c expression.

Answer: Kc=[CO2][H2O]2[CH4][O2]2K_c = \frac{[CO_2][H_2O]^2}{[CH_4][O_2]^2}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 2: Calculate KcK_c for H2+I22HIH_2 + I_2 \rightleftharpoons 2HI with [H2]=1M[H_2] = 1M, [I2]=1M[I_2] = 1M, [HI]=2M[HI] = 2M.

Answer: Kc=41K_c = \frac{4}{1}. Kc=[HI]2[H2][I2]=221×1=4K_c = \frac{[HI]^2}{[H_2][I_2]} = \frac{2^2}{1 \times 1} = 4.

Flashcard 3: State the effect of adding a reactant on the equilibrium position.

Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.

Flashcard 4: What is the effect of a catalyst on the equilibrium constant KK?

Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or KK.

Flashcard 5: Identify the equilibrium expression for the reaction N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g).

Answer: Kc=[NH3]2[N2][H2]3K_c = \frac{[NH_3]^2}{[N_2][H_2]^3}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 6: State the relationship between KpK_p and KcK_c for gaseous reactions.

Answer: Kp=Kc(RT)ΔnK_p = K_c(RT)^{\Delta n}. Where Δn\Delta n is moles of gaseous products minus gaseous reactants.

Flashcard 7: State the unit for KcK_c for the reaction aA+bBcC+dDaA + bB \rightleftharpoons cC + dD if c+d=a+bc+d = a+b.

Answer: Unitless. When total moles of products equals total moles of reactants.

Flashcard 8: What happens to KcK_c of an exothermic reaction when temperature increases?

Answer: KcK_c decreases. Higher temperature opposes exothermic reactions, decreasing KcK_c.

Flashcard 9: Find KcK_c for the reaction 2AB+C2A \rightleftharpoons B + C if [A]=0.5M[A] = 0.5M, [B]=1M[B] = 1M, [C]=1M[C] = 1M.

Answer: Kc=1×10.52K_c = \frac{1 \times 1}{0.5^2}. Kc=[B][C][A]2=1×10.52=4K_c = \frac{[B][C]}{[A]^2} = \frac{1 \times 1}{0.5^2} = 4.

Flashcard 10: For the reaction 2NO(g)+O2(g)2NO2(g)2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g), what is the KpK_p expression?

Answer: Kp=PNO22PNO2PO2K_p = \frac{P_{NO_2}^2}{P_{NO}^2 P_{O_2}}. Products over reactants using partial pressures, raised to coefficients.

Flashcard 11: What is the effect of adding an inert gas at constant volume on the equilibrium of a reaction?

Answer: No effect. Inert gas doesn't participate and doesn't change partial pressures.

Flashcard 12: For the endothermic reaction ABA \rightleftharpoons B, what is the effect of increasing temperature?

Answer: Shifts towards BB. Higher temperature favors endothermic reactions (heat-absorbing direction).

Flashcard 13: For the reaction C(s)+CO2(g)2CO(g)C(s) + CO_2(g) \rightleftharpoons 2CO(g), write the KcK_c expression.

Answer: Kc=[CO]2/[CO2]K_c = [CO]^2/[CO_2]. Solid carbon is excluded, only gaseous species are included.

Flashcard 14: Given Kc=10K_c = 10 for ABA \rightleftharpoons B, find KcK_c for 2A2B2A \rightleftharpoons 2B.

Answer: Kc=102K_c = 10^2. When reaction is doubled, equilibrium constant is squared.

Flashcard 15: What happens to the equilibrium position when pressure is increased for the reaction N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)?

Answer: Shifts towards NH3NH_3. Higher pressure favors the side with fewer gas molecules (2 vs 4).

Flashcard 16: What happens to the equilibrium position when pressure is increased for the reaction N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)?

Answer: Shifts towards NH3NH_3. Higher pressure favors the side with fewer gas molecules (2 vs 4).

Flashcard 17: Identify the equilibrium expression for CO(g)+Cl2(g)COCl2(g)CO(g) + Cl_2(g) \rightleftharpoons COCl_2(g).

Answer: Kc=[COCl2][CO][Cl2]K_c = \frac{[COCl_2]}{[CO][Cl_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 18: What is the equilibrium constant expression for 2H2O2(aq)2H2O(l)+O2(g)2H_2O_2(aq) \rightleftharpoons 2H_2O(l) + O_2(g)?

Answer: Kc=[O2]K_c = [O_2]. Liquids are excluded from equilibrium expressions, only gases included.

Flashcard 19: State the KcK_c expression for the reaction C2H4(g)+H2(g)C2H6(g)C_2H_4(g) + H_2(g) \rightleftharpoons C_2H_6(g).

Answer: Kc=[C2H6][C2H4][H2]K_c = \frac{[C_2H_6]}{[C_2H_4][H_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 20: What is the equilibrium expression for H2(g)+S(s)H2S(g)H_2(g) + S(s) \rightleftharpoons H_2S(g)?

Answer: Kc=[H2S]K_c = [H_2S]. Solids are excluded from equilibrium expressions, only gases included.

Flashcard 21: State the unit for KcK_c for the reaction aA+bBcC+dDaA + bB \rightleftharpoons cC + dD if c+d=a+bc+d = a+b.

Answer: Unitless. When total moles of products equals total moles of reactants.

Flashcard 22: For 2NO2(g)N2O4(g)2NO_2(g) \rightleftharpoons N_2O_4(g), what happens to KcK_c if temperature is increased?

Answer: KcK_c decreases. Higher temperature opposes exothermic reactions, decreasing KcK_c.

Flashcard 23: For the reaction H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g), find KcK_c if [HI]=2M[HI] = 2M, [H2]=1M[H_2] = 1M, [I2]=1M[I_2] = 1M.

Answer: Kc=4K_c = 4. Kc=[HI]2[H2][I2]=221×1=4K_c = \frac{[HI]^2}{[H_2][I_2]} = \frac{2^2}{1 \times 1} = 4.

Flashcard 24: For the reaction H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g), find KcK_c if [HI]=2M[HI] = 2M, [H2]=1M[H_2] = 1M, [I2]=1M[I_2] = 1M.

Answer: Kc=4K_c = 4. Kc=[HI]2[H2][I2]=221×1=4K_c = \frac{[HI]^2}{[H_2][I_2]} = \frac{2^2}{1 \times 1} = 4.

Flashcard 25: What is the effect of a catalyst on the equilibrium constant KK?

Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or KK.

Flashcard 26: What is the equilibrium expression for H2(g)+S(s)H2S(g)H_2(g) + S(s) \rightleftharpoons H_2S(g)?

Answer: Kc=[H2S]K_c = [H_2S]. Solids are excluded from equilibrium expressions, only gases included.

Flashcard 27: For the reaction CH4(g)+2O2(g)CO2(g)+2H2O(g)CH_4(g) + 2O_2(g) \rightleftharpoons CO_2(g) + 2H_2O(g), write the KcK_c expression.

Answer: Kc=[CO2][H2O]2[CH4][O2]2K_c = \frac{[CO_2][H_2O]^2}{[CH_4][O_2]^2}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 28: If Kc=1.5K_c = 1.5 for the reaction ABA \rightleftharpoons B, what is the value of KcK_c for BAB \rightleftharpoons A?

Answer: Kc=11.5K_c = \frac{1}{1.5}. For the reverse reaction, KcK_c becomes the reciprocal of the original.

Flashcard 29: If Kc=1.5K_c = 1.5 for the reaction ABA \rightleftharpoons B, what is the value of KcK_c for BAB \rightleftharpoons A?

Answer: Kc=11.5K_c = \frac{1}{1.5}. For the reverse reaction, KcK_c becomes the reciprocal of the original.

Flashcard 30: State the relationship between KpK_p and KcK_c for gaseous reactions.

Answer: Kp=Kc(RT)ΔnK_p = K_c(RT)^{\Delta n}. Where Δn\Delta n is moles of gaseous products minus gaseous reactants.

Flashcard 31: What is the effect of adding an inert gas at constant volume on the equilibrium of a reaction?

Answer: No effect. Inert gas doesn't participate and doesn't change partial pressures.

Flashcard 32: What is the expression for the equilibrium constant KcK_c for the reaction aA+bBcC+dDaA + bB \rightleftharpoons cC + dD?

Answer: Kc=[C]c[D]d[A]a[B]bK_c = \frac{[C]^c[D]^d}{[A]^a[B]^b}. Products in numerator raised to their coefficients, reactants in denominator.

Flashcard 33: For the reaction PCl5(g)PCl3(g)+Cl2(g)PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g), what is the effect of decreasing temperature?

Answer: Shifts towards PCl5PCl_5. Lower temperature favors the exothermic direction (heat-producing side).

Flashcard 34: For the reaction 2NO(g)+O2(g)2NO2(g)2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g), what is the KpK_p expression?

Answer: Kp=PNO22PNO2PO2K_p = \frac{P_{NO_2}^2}{P_{NO}^2 P_{O_2}}. Products over reactants using partial pressures, raised to coefficients.

Flashcard 35: For the reaction H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g), find KcK_c if [HI]=2M[HI] = 2M, [H2]=1M[H_2] = 1M, [I2]=1M[I_2] = 1M.

Answer: Kc=4K_c = 4. Kc=[HI]2[H2][I2]=221×1=4K_c = \frac{[HI]^2}{[H_2][I_2]} = \frac{2^2}{1 \times 1} = 4.

Flashcard 36: What is the effect of adding a product on the position of equilibrium?

Answer: Shifts left to form more reactants. Le Chatelier's principle: system responds by consuming the added product.

Flashcard 37: Calculate KcK_c for H2+I22HIH_2 + I_2 \rightleftharpoons 2HI with [H2]=1M[H_2] = 1M, [I2]=1M[I_2] = 1M, [HI]=2M[HI] = 2M.

Answer: Kc=41K_c = \frac{4}{1}. Kc=[HI]2[H2][I2]=221×1=4K_c = \frac{[HI]^2}{[H_2][I_2]} = \frac{2^2}{1 \times 1} = 4.

Flashcard 38: State the KcK_c expression for the reaction C2H4(g)+H2(g)C2H6(g)C_2H_4(g) + H_2(g) \rightleftharpoons C_2H_6(g).

Answer: Kc=[C2H6][C2H4][H2]K_c = \frac{[C_2H_6]}{[C_2H_4][H_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 39: Identify the equilibrium expression for CO(g)+Cl2(g)COCl2(g)CO(g) + Cl_2(g) \rightleftharpoons COCl_2(g).

Answer: Kc=[COCl2][CO][Cl2]K_c = \frac{[COCl_2]}{[CO][Cl_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 40: For AB+CA \rightleftharpoons B + C, if Kc=2K_c = 2, what is KcK_c for B+CAB + C \rightleftharpoons A?

Answer: Kc=12K_c = \frac{1}{2}. For the reverse reaction, KcK_c becomes the reciprocal of the original.

Flashcard 41: Find KcK_c for A2BA \rightleftharpoons 2B if [A]=1M[A] = 1M, [B]=0.5M[B] = 0.5M at equilibrium.

Answer: Kc=0.521K_c = \frac{0.5^2}{1}. Kc=[B]2[A]=0.521=0.25K_c = \frac{[B]^2}{[A]} = \frac{0.5^2}{1} = 0.25.

Flashcard 42: Given Kc=10K_c = 10 for ABA \rightleftharpoons B, find KcK_c for 2A2B2A \rightleftharpoons 2B.

Answer: Kc=102K_c = 10^2. When reaction is doubled, equilibrium constant is squared.

Flashcard 43: What is the effect of pressure decrease on equilibrium of N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)?

Answer: Shifts left. Lower pressure favors the side with more gas molecules (4 vs 2).

Flashcard 44: State the unit for KcK_c for the reaction aA+bBcC+dDaA + bB \rightleftharpoons cC + dD if c+d=a+bc+d = a+b.

Answer: Unitless. When total moles of products equals total moles of reactants.

Flashcard 45: For the reaction CH4(g)+2O2(g)CO2(g)+2H2O(g)CH_4(g) + 2O_2(g) \rightleftharpoons CO_2(g) + 2H_2O(g), write the KcK_c expression.

Answer: Kc=[CO2][H2O]2[CH4][O2]2K_c = \frac{[CO_2][H_2O]^2}{[CH_4][O_2]^2}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 46: For the reaction 2SO2(g)+O2(g)2SO3(g)2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g), what is the expression for KpK_p?

Answer: Kp=PSO32PSO22PO2K_p = \frac{P_{SO_3}^2}{P_{SO_2}^2 P_{O_2}}. Products over reactants using partial pressures, raised to coefficients.

Flashcard 47: State the effect of adding a reactant on the equilibrium position.

Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.

Flashcard 48: Identify the equilibrium expression for CO(g)+Cl2(g)COCl2(g)CO(g) + Cl_2(g) \rightleftharpoons COCl_2(g).

Answer: Kc=[COCl2][CO][Cl2]K_c = \frac{[COCl_2]}{[CO][Cl_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 49: State the KcK_c expression for the reaction C2H4(g)+H2(g)C2H6(g)C_2H_4(g) + H_2(g) \rightleftharpoons C_2H_6(g).

Answer: Kc=[C2H6][C2H4][H2]K_c = \frac{[C_2H_6]}{[C_2H_4][H_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 50: If Kc=1.5K_c = 1.5 for the reaction ABA \rightleftharpoons B, what is the value of KcK_c for BAB \rightleftharpoons A?

Answer: Kc=11.5K_c = \frac{1}{1.5}. For the reverse reaction, KcK_c becomes the reciprocal of the original.

Flashcard 51: For N2O4(g)2NO2(g)N_2O_4(g) \rightleftharpoons 2NO_2(g), how does increasing pressure affect equilibrium?

Answer: Shifts towards N2O4N_2O_4. Higher pressure favors the side with fewer gas molecules (1 vs 2).

Flashcard 52: What is the effect of adding an inert gas at constant volume on the equilibrium of a reaction?

Answer: No effect. Inert gas doesn't participate and doesn't change partial pressures.

Flashcard 53: State the relationship between KpK_p and KcK_c for gaseous reactions.

Answer: Kp=Kc(RT)ΔnK_p = K_c(RT)^{\Delta n}. Where Δn\Delta n is moles of gaseous products minus gaseous reactants.

Flashcard 54: For N2O4(g)2NO2(g)N_2O_4(g) \rightleftharpoons 2NO_2(g), how does increasing pressure affect equilibrium?

Answer: Shifts towards N2O4N_2O_4. Higher pressure favors the side with fewer gas molecules (1 vs 2).

Flashcard 55: For the reaction 2NO(g)+O2(g)2NO2(g)2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g), what is the KpK_p expression?

Answer: Kp=PNO22PNO2PO2K_p = \frac{P_{NO_2}^2}{P_{NO}^2 P_{O_2}}. Products over reactants using partial pressures, raised to coefficients.

Flashcard 56: If [N2]=2M[N_2] = 2M, [H2]=1M[H_2] = 1M, [NH3]=0.5M[NH_3] = 0.5M, find QcQ_c for N2+3H22NH3N_2 + 3H_2 \rightleftharpoons 2NH_3.

Answer: Qc=0.522×13Q_c = \frac{0.5^2}{2 \times 1^3}. Qc=[NH3]2[N2][H2]3=0.522×13=0.252Q_c = \frac{[NH_3]^2}{[N_2][H_2]^3} = \frac{0.5^2}{2 \times 1^3} = \frac{0.25}{2}.

Flashcard 57: For the reaction 2SO2(g)+O2(g)2SO3(g)2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g), what is the expression for KpK_p?

Answer: Kp=PSO32PSO22PO2K_p = \frac{P_{SO_3}^2}{P_{SO_2}^2 P_{O_2}}. Products over reactants using partial pressures, raised to coefficients.

Flashcard 58: What is the equilibrium expression for H2(g)+S(s)H2S(g)H_2(g) + S(s) \rightleftharpoons H_2S(g)?

Answer: Kc=[H2S]K_c = [H_2S]. Solids are excluded from equilibrium expressions, only gases included.

Flashcard 59: How does a decrease in the concentration of O2O_2 affect equilibrium in 2SO2+O22SO32SO_2 + O_2 \rightleftharpoons 2SO_3?

Answer: Shifts left. Removing reactant shifts equilibrium to replace it via reverse reaction.

Flashcard 60: Determine the equilibrium constant KcK_c for the reaction 2NO2(g)N2O4(g)2NO_2(g) \rightleftharpoons N_2O_4(g) given [NO2]=0.5M[NO_2] = 0.5M, [N2O4]=0.2M[N_2O_4] = 0.2M.

Answer: Kc=0.8K_c = 0.8. Kc=[N2O4][NO2]2=0.20.52=0.8K_c = \frac{[N_2O_4]}{[NO_2]^2} = \frac{0.2}{0.5^2} = 0.8.

Flashcard 61: What is the effect of increasing temperature on the equilibrium position of an exothermic reaction?

Answer: Shifts towards reactants. Higher temperature opposes exothermic reactions, favoring the reverse direction.

Flashcard 62: Calculate KcK_c for H2+I22HIH_2 + I_2 \rightleftharpoons 2HI with [H2]=1M[H_2] = 1M, [I2]=1M[I_2] = 1M, [HI]=2M[HI] = 2M.

Answer: Kc=41K_c = \frac{4}{1}. Kc=[HI]2[H2][I2]=221×1=4K_c = \frac{[HI]^2}{[H_2][I_2]} = \frac{2^2}{1 \times 1} = 4.

Flashcard 63: State the effect of a temperature decrease on an endothermic reaction's equilibrium position.

Answer: Shifts towards reactants. Lower temperature opposes endothermic reactions, favoring reactant formation.

Flashcard 64: Identify the expression for KcK_c for H2O(l)H+(aq)+OH(aq)H_2O(l) \rightleftharpoons H^+(aq) + OH^-(aq).

Answer: Kw=[H+][OH]K_w = [H^+][OH^-]. Auto-ionization of water uses KwK_w notation for the equilibrium constant.

Flashcard 65: What is the equilibrium constant expression for 2H2O2(aq)2H2O(l)+O2(g)2H_2O_2(aq) \rightleftharpoons 2H_2O(l) + O_2(g)?

Answer: Kc=[O2]K_c = [O_2]. Liquids are excluded from equilibrium expressions, only gases included.

Flashcard 66: If [N2]=2M[N_2] = 2M, [H2]=1M[H_2] = 1M, [NH3]=0.5M[NH_3] = 0.5M, find QcQ_c for N2+3H22NH3N_2 + 3H_2 \rightleftharpoons 2NH_3.

Answer: Qc=0.522×13Q_c = \frac{0.5^2}{2 \times 1^3}. Qc=[NH3]2[N2][H2]3=0.522×13=0.252Q_c = \frac{[NH_3]^2}{[N_2][H_2]^3} = \frac{0.5^2}{2 \times 1^3} = \frac{0.25}{2}.

Flashcard 67: For the endothermic reaction ABA \rightleftharpoons B, what is the effect of increasing temperature?

Answer: Shifts towards BB. Higher temperature favors endothermic reactions (heat-absorbing direction).

Flashcard 68: Find KcK_c for the reaction 2AB+C2A \rightleftharpoons B + C if [A]=0.5M[A] = 0.5M, [B]=1M[B] = 1M, [C]=1M[C] = 1M.

Answer: Kc=1×10.52K_c = \frac{1 \times 1}{0.5^2}. Kc=[B][C][A]2=1×10.52=4K_c = \frac{[B][C]}{[A]^2} = \frac{1 \times 1}{0.5^2} = 4.

Flashcard 69: What is the effect of adding a product on the position of equilibrium?

Answer: Shifts left to form more reactants. Le Chatelier's principle: system responds by consuming the added product.

Flashcard 70: Identify the expression for KcK_c for H2O(l)H+(aq)+OH(aq)H_2O(l) \rightleftharpoons H^+(aq) + OH^-(aq).

Answer: Kw=[H+][OH]K_w = [H^+][OH^-]. Auto-ionization of water uses KwK_w notation for the equilibrium constant.

Flashcard 71: Which factor does not affect the value of the equilibrium constant KK?

Answer: Concentration of reactants or products. KK depends only on temperature, not concentrations at equilibrium.

Flashcard 72: Which factor does not affect the value of the equilibrium constant KK?

Answer: Concentration of reactants or products. KK depends only on temperature, not concentrations at equilibrium.

Flashcard 73: For 2NO2(g)N2O4(g)2NO_2(g) \rightleftharpoons N_2O_4(g), what happens to KcK_c if temperature is increased?

Answer: KcK_c decreases. Higher temperature opposes exothermic reactions, decreasing KcK_c.

Flashcard 74: State the effect of adding a reactant on the equilibrium position.

Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.

Flashcard 75: For 2NO2(g)N2O4(g)2NO_2(g) \rightleftharpoons N_2O_4(g), what happens to KcK_c if temperature is increased?

Answer: KcK_c decreases. Higher temperature opposes exothermic reactions, decreasing KcK_c.

Flashcard 76: What is the effect of pressure decrease on equilibrium of N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)?

Answer: Shifts left. Lower pressure favors the side with more gas molecules (4 vs 2).

Flashcard 77: What is the effect of a catalyst on the equilibrium constant KK?

Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or KK.

Flashcard 78: State the effect of adding a reactant on the equilibrium position.

Answer: Shifts right to form more products. Le Chatelier's principle: system responds by consuming the added reactant.

Flashcard 79: For the reaction 2SO2(g)+O2(g)2SO3(g)2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g), what is the expression for KpK_p?

Answer: Kp=PSO32PSO22PO2K_p = \frac{P_{SO_3}^2}{P_{SO_2}^2 P_{O_2}}. Products over reactants using partial pressures, raised to coefficients.

Flashcard 80: For N2O4(g)2NO2(g)N_2O_4(g) \rightleftharpoons 2NO_2(g), how does increasing pressure affect equilibrium?

Answer: Shifts towards N2O4N_2O_4. Higher pressure favors the side with fewer gas molecules (1 vs 2).

Flashcard 81: For the reaction C(s)+CO2(g)2CO(g)C(s) + CO_2(g) \rightleftharpoons 2CO(g), write the KcK_c expression.

Answer: Kc=[CO]2/[CO2]K_c = [CO]^2/[CO_2]. Solid carbon is excluded, only gaseous species are included.

Flashcard 82: For N2O4(g)2NO2(g)N_2O_4(g) \rightleftharpoons 2NO_2(g), how does increasing pressure affect equilibrium?

Answer: Shifts towards N2O4N_2O_4. Higher pressure favors the side with fewer gas molecules (1 vs 2).

Flashcard 83: Identify the expression for KcK_c for H2O(l)H+(aq)+OH(aq)H_2O(l) \rightleftharpoons H^+(aq) + OH^-(aq).

Answer: Kw=[H+][OH]K_w = [H^+][OH^-]. Auto-ionization of water uses KwK_w notation for the equilibrium constant.

Flashcard 84: What is the equilibrium constant expression for 2H2O2(aq)2H2O(l)+O2(g)2H_2O_2(aq) \rightleftharpoons 2H_2O(l) + O_2(g)?

Answer: Kc=[O2]K_c = [O_2]. Liquids are excluded from equilibrium expressions, only gases included.

Flashcard 85: What is the equilibrium expression for H2(g)+S(s)H2S(g)H_2(g) + S(s) \rightleftharpoons H_2S(g)?

Answer: Kc=[H2S]K_c = [H_2S]. Solids are excluded from equilibrium expressions, only gases included.

Flashcard 86: What is the effect of increasing temperature on the equilibrium position of an exothermic reaction?

Answer: Shifts towards reactants. Higher temperature opposes exothermic reactions, favoring the reverse direction.

Flashcard 87: Identify the equilibrium expression for the reaction N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g).

Answer: Kc=[NH3]2[N2][H2]3K_c = \frac{[NH_3]^2}{[N_2][H_2]^3}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 88: Which factor does not affect the value of the equilibrium constant KK?

Answer: Concentration of reactants or products. KK depends only on temperature, not concentrations at equilibrium.

Flashcard 89: What happens to the equilibrium position when pressure is increased for the reaction N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)?

Answer: Shifts towards NH3NH_3. Higher pressure favors the side with fewer gas molecules (2 vs 4).

Flashcard 90: Find KcK_c for the reaction 2AB+C2A \rightleftharpoons B + C if [A]=0.5M[A] = 0.5M, [B]=1M[B] = 1M, [C]=1M[C] = 1M.

Answer: Kc=1×10.52K_c = \frac{1 \times 1}{0.5^2}. Kc=[B][C][A]2=1×10.52=4K_c = \frac{[B][C]}{[A]^2} = \frac{1 \times 1}{0.5^2} = 4.

Flashcard 91: If [N2]=2M[N_2] = 2M, [H2]=1M[H_2] = 1M, [NH3]=0.5M[NH_3] = 0.5M, find QcQ_c for N2+3H22NH3N_2 + 3H_2 \rightleftharpoons 2NH_3.

Answer: Qc=0.522×13Q_c = \frac{0.5^2}{2 \times 1^3}. Qc=[NH3]2[N2][H2]3=0.522×13=0.252Q_c = \frac{[NH_3]^2}{[N_2][H_2]^3} = \frac{0.5^2}{2 \times 1^3} = \frac{0.25}{2}.

Flashcard 92: Identify the equilibrium expression for the reaction N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g).

Answer: Kc=[NH3]2[N2][H2]3K_c = \frac{[NH_3]^2}{[N_2][H_2]^3}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 93: What is the effect of a catalyst on the equilibrium constant KK?

Answer: No effect. Catalysts only affect reaction rate, not equilibrium position or KK.

Flashcard 94: Determine the equilibrium constant KcK_c for the reaction 2NO2(g)N2O4(g)2NO_2(g) \rightleftharpoons N_2O_4(g) given [NO2]=0.5M[NO_2] = 0.5M, [N2O4]=0.2M[N_2O_4] = 0.2M.

Answer: Kc=0.8K_c = 0.8. Kc=[N2O4][NO2]2=0.20.52=0.8K_c = \frac{[N_2O_4]}{[NO_2]^2} = \frac{0.2}{0.5^2} = 0.8.

Flashcard 95: What is the equilibrium constant expression for 2H2O2(aq)2H2O(l)+O2(g)2H_2O_2(aq) \rightleftharpoons 2H_2O(l) + O_2(g)?

Answer: Kc=[O2]K_c = [O_2]. Liquids are excluded from equilibrium expressions, only gases included.

Flashcard 96: State the KcK_c expression for the reaction C2H4(g)+H2(g)C2H6(g)C_2H_4(g) + H_2(g) \rightleftharpoons C_2H_6(g).

Answer: Kc=[C2H6][C2H4][H2]K_c = \frac{[C_2H_6]}{[C_2H_4][H_2]}. Products over reactants, each raised to their stoichiometric coefficients.

Flashcard 97: Find KcK_c for A2BA \rightleftharpoons 2B if [A]=1M[A] = 1M, [B]=0.5M[B] = 0.5M at equilibrium.

Answer: Kc=0.521K_c = \frac{0.5^2}{1}. Kc=[B]2[A]=0.521=0.25K_c = \frac{[B]^2}{[A]} = \frac{0.5^2}{1} = 0.25.

Flashcard 98: Determine the equilibrium constant KcK_c for the reaction 2NO2(g)N2O4(g)2NO_2(g) \rightleftharpoons N_2O_4(g) given [NO2]=0.5M[NO_2] = 0.5M, [N2O4]=0.2M[N_2O_4] = 0.2M.

Answer: Kc=0.8K_c = 0.8. Kc=[N2O4][NO2]2=0.20.52=0.8K_c = \frac{[N_2O_4]}{[NO_2]^2} = \frac{0.2}{0.5^2} = 0.8.

Flashcard 99: What is the effect of pressure decrease on equilibrium of N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)?

Answer: Shifts left. Lower pressure favors the side with more gas molecules (4 vs 2).

Flashcard 100: If Kc=1.5K_c = 1.5 for the reaction ABA \rightleftharpoons B, what is the value of KcK_c for BAB \rightleftharpoons A?

Answer: Kc=11.5K_c = \frac{1}{1.5}. For the reverse reaction, KcK_c becomes the reciprocal of the original.