Mass Spectroscopy of the Elements

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AP Chemistry › Mass Spectroscopy of the Elements

Questions 1 - 10
1

Which of the following isotopes has the greatest number of neutrons?

Carbon-14

Nitrogen-13

Oxygen-15

Fluorine-16

Boron-10

Explanation

Carbon-14 has 8 neutrons

Nitrogen-13 has 6 neutrons

Oxygen-15 has 7 neutrons

Fluorine-16 has 7 neutrons

Boron-10 has 5 neutrons

2

Which of the following statements is true?

Electrons are smaller in size than nucleons, but have equal charge

The nucleus of an atom is electrically neutral

Electrons are smaller than protons, which means they have less charge than protons

Electrons are close in proximity to the atomic nucleus

Electrons are larger than protons, which means they must have less charge than protons

Explanation

Electrons are notably smaller than nucleons (protons and neutrons), however, they have an equal amount of charge to protons. This is why an atom with the same amount of protons as electrons is considered electrically neutral.

The nucleus itself is positively charged, as the electrons are located relatively far away from the atomic center.

3

Which of the following describes an isotope to ?

A carbon atom with 7 protons, 6 neutrons

A carbon with 6 protons, 6 neutrons

A carbon with 8 protons, 5 neutrons

A carbon with 6 protons, 7 neutrons

A carbon with 4 protons, 9 neutrons

Explanation

An element is defined by the number of protons it contains. An isotope is the same element with a different number of neutrons; only two choices have six protons, which carbon has. One of them is 13C, which is the same as the question; the other is 12C.

Note that the question asks for an isotope to 13C. By definition, our answer choice cannot be 13C, but must be a variation (an isotope). We are looking for a second answer with 6 protons, in order to maintain the elemental identity of carbon, but a different number of neutrons (not 7). This makes our final answer a carbon atom with 7 protons, 6 neutrons, or 12C, because it is an isotope to 13C.

4

Anionic atoms are __________ than their respective neutral atoms because they have __________ electron(s) than their neutral atoms.

larger . . . more

larger . . . less

smaller . . . more

smaller . . . less

Explanation

Anions have at least one more electron than their neutral atoms. Adding an electron creates a shielding effect on other electrons in the same shell, decreasing the nuclear charge felt by each valence electron. As a result, the electrons will lie slightly further from the nucleus, corresponding to an increase in atomic radius. If there are no other electrons than the newly added electron in the valence shell, then the added electron was added to the now highest shell, which would significantly increase the size of the atom.

5

An element has two main isotopes. The first isotope has a molar mass of 125 grams, and the second isotope has a molar mass of 128 grams. A naturally occurring sample of the element has a molar mass of 126.8 grams.

What is the lighter isotope's percentage in the natural sample?

Explanation

In order to find the percentage of the lighter isotope in the natural sample, we need to use an equation that compares the percentage of each isotope and the natural molar mass. Since both of the isotopes together will account for 100% of the natural sample, we can say that the lighter isotope's percentage is , while the remaining percentage is .

Use this equation to solve for .

In other words, we can conclude that the lighter isotope makes up 40% of the natural sample.

6

Chemical has only two isotopes: and . The atomic weight of chemical X, listed on the periodic table, is . What is the relative abundance of each isotope?

The abundance of is 96.25%, and the abundance of is 3.75%

The abundance of is 3.75%, and the abundance of is 96.25%

The abundance of is 50%, and the abundance of is 50%

The abundance of is 91.25%, and the abundance of is 8.75%

There is not enough information to answer this question

Explanation

The abundance of will be referred to as "n," and the abundance of is "1-n." Together, we know that these values account for the full abundance of chemical X in existence.

The abundance of is 96.25%, and the abundance of is 3.75%.

7

What is the sum of the number of neutrons of the following atoms: (a) N15
(b) Ag109 (c) Si30

86

84

82

88

90

Explanation

In an atomic representation, the number of neutrons and protons is the upper number
and the number of protons is the lower number. If only one number is given, we can assume
that the number of protons is its atomic number. Therefore (a) 7 protons and 8 neutrons
(b) 47 protons and 62 neutrons (c) 14 protons and 16 neutrons. The total number is 86.

8

A certain element X is comprised of isotopes A, B, and C. Isotope A has a mass of 50 amu and is 70% of naturally occurring X. Isotope B is 35 amu and is 25% of X. Isotope C has a mass of 70 amu and is 5% of X. What is the atomic weight of element X?

40 g/mol

47 g/mol

55 g/mol

70 g/mol

87 g/mol

Explanation

0.70 (50 amu) + 0.25 (35 amu) + 0.05 (70 amu) = 47 amu = 47 g/mol

9

How many of each subatomic particle exist in ?

52 protons, 78 neutrons, 54 electrons

130 protons, 52 neutrons, 130 electrons

52 protons, 130 neutrons, 54 electrons

130 protons, 130 neutrons, 132 electrons

78 protons, 52 neutrons, 80 electrons

Explanation

Using the standard isotope notation of , where Z equals the number of protons, and a is the mass number, or the number of protons plus neutrons. Therefore, this isotopic ion has 52 protons and 78 neutrons. Because this anion has a charge of 2-, we know that it contains 54 electrons.

10

Which of the following contains the most neutrons?

Carbon-12

Oxygen-15

Boron-12

Carbon-14

Nitrogen-14

Explanation

The number following the compound is the isotope number, giving the number of protons and neutrons the element contains per atom. To get the number of neutrons you take the isotope number and subtract the atomic number of that element.

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