Molecules and Compounds

Help Questions

AP Chemistry › Molecules and Compounds

Questions 1 - 10
1

What is the molecular geometry of ?

Bent

Trigonal planar

Linear

T-shaped

Explanation

Start by drawing the Lewis structure of .

1

Notice that the central oxygen atom has other oxygen atoms bonded to it, as well as a lone pair. This means it has a steric number of . A molecule with a steric number of and lone pair has a bent molecular geometry.

2

What is the molecular geometry of the molecule ?

T-shaped

Trigonal bipyramidal

Square pyramidal

Trigonal pyramidal

Trigonal planar

Explanation

is t-shaped. By drawing the Lewis diagram for , we see that there are 5 electron groups and 2 lone pairs on the central atom, . Electron group geometry states that molecules with 5 electron groups have a trigonal bipyramidal geometry. The molecular geometries of trigonal bipyramidal molecules can be trigonal bipyramidal (no lone pairs), seesaw (1 lone pair), t-shaped (2 lone pairs). and linear (3 lone pairs).

consists of 5 electron groups and 2 lone pairs and therefore fits the molecular geometry of a t-shaped molecule.

3

Which of the following is true of Valence Bond theory and Molecular Orbital theory?

The Valence Bond theory states that covalent bonds are formed from atomic orbital overlap while the Molecular Orbital theory is the mathematical combination of atomic orbitals to produce anti bonding and bonding orbitals.

The Valence Bond Theory states that covalent bonds are the result of electron repulsion while the Molecular Orbital theory states that covalent bonds form as a result of atomic overlap.

The Valence Bond theory is the mathematical combination of atomic orbitals to produce anti bonding and bonding orbitals while the Molecular Orbital theory states that covalent bonds are formed from atomic orbital overlap.

Both Valence Bond theory and Molecular Orbital theory produce hybridized geometries through anti bonding and bonding orbitals.

Neither Valence Bond theory nor Molecular Orbital theory produces hybridized geometries.

Explanation

The Valence Bond theory states that covalent bonds are formed from atomic orbital overlap while the Molecular Orbital theory is the mathematical combination of atomic orbitals to produce anti bonding and bonding orbitals.

Hybridization occurs through combining atomic orbitals, a concept consistent with Valence Bond theory. Common bonds found in Valence Bond hybridization are sigma and pi bonds which overlap end-to-end or side-to-side respectively. Orbitals are combined in Molecular Orbital theory, producing either bonding or anti bonding orbitals. Molecular Orbital theory shows the destructive or constructive interference of sigma and pi bonds (displayed through bonding and anti bonding orbitals).

4

What is the molecular geometry of ?

Bent

Trigonal planar

Linear

T-shaped

Explanation

Start by drawing the Lewis structure of .

1

Notice that the central oxygen atom has other oxygen atoms bonded to it, as well as a lone pair. This means it has a steric number of . A molecule with a steric number of and lone pair has a bent molecular geometry.

5

Which of the following is true of Valence Bond theory and Molecular Orbital theory?

The Valence Bond theory states that covalent bonds are formed from atomic orbital overlap while the Molecular Orbital theory is the mathematical combination of atomic orbitals to produce anti bonding and bonding orbitals.

The Valence Bond Theory states that covalent bonds are the result of electron repulsion while the Molecular Orbital theory states that covalent bonds form as a result of atomic overlap.

The Valence Bond theory is the mathematical combination of atomic orbitals to produce anti bonding and bonding orbitals while the Molecular Orbital theory states that covalent bonds are formed from atomic orbital overlap.

Both Valence Bond theory and Molecular Orbital theory produce hybridized geometries through anti bonding and bonding orbitals.

Neither Valence Bond theory nor Molecular Orbital theory produces hybridized geometries.

Explanation

The Valence Bond theory states that covalent bonds are formed from atomic orbital overlap while the Molecular Orbital theory is the mathematical combination of atomic orbitals to produce anti bonding and bonding orbitals.

Hybridization occurs through combining atomic orbitals, a concept consistent with Valence Bond theory. Common bonds found in Valence Bond hybridization are sigma and pi bonds which overlap end-to-end or side-to-side respectively. Orbitals are combined in Molecular Orbital theory, producing either bonding or anti bonding orbitals. Molecular Orbital theory shows the destructive or constructive interference of sigma and pi bonds (displayed through bonding and anti bonding orbitals).

6

What is the molecular geometry of the molecule ?

T-shaped

Trigonal bipyramidal

Square pyramidal

Trigonal pyramidal

Trigonal planar

Explanation

is t-shaped. By drawing the Lewis diagram for , we see that there are 5 electron groups and 2 lone pairs on the central atom, . Electron group geometry states that molecules with 5 electron groups have a trigonal bipyramidal geometry. The molecular geometries of trigonal bipyramidal molecules can be trigonal bipyramidal (no lone pairs), seesaw (1 lone pair), t-shaped (2 lone pairs). and linear (3 lone pairs).

consists of 5 electron groups and 2 lone pairs and therefore fits the molecular geometry of a t-shaped molecule.

7

Which of the following is a characteristic of covalent bonds?

A covalent bond is one between two nonmetals.

A covalent bond is one between a metal and a nonmetal.

Covalent compounds dissolve in water to form cations and anions.

Covalent compounds are good conductors of electricity.

Explanation

A covalent bond is one between two nonmetals, while an ionic bond is formed between a metal and a nonmetal. Covalent bonds also do not dissociate in aqueous solution to form cations and anions; this is a characteristic of ionic bonds. For example, represents a bond between a metal () and a nonmetal (), and it dissociates in aqueous solution to form a cation () and an anion (). In contrast, represents a bond between two nonmetals, and it does not dissociate in aqueous solution. Ionic compounds are also good conductors of electricity, while covalent compounds are not. This is because moving electrons are required in order to conduct electricity. When dissolved in aqueous solution, ions are free to move and thus conduct electricity. Covalent bonds have localized electrons, which cannot move and thus cannot conduct electricity well.

8

Which of the following C-N bonds is the shortest?

The C-N bond in .

The C-N bond in .

The C-N bond in .

The C-N bond in .

Explanation

Drawing the Lewis Diagrams for these molecules reveals that the C-N bond in is a triple covalent bond, whereas the C-N bonds in and are double covalent bonds and the C-N bond in is a single covalent bond. Triple covalent bonds between two given atoms are always stronger than double bonds between these same two atoms, and similarly double bonds are even stronger than single bonds. Bond length is inversely related to bond strength; therefore a shorter bond is a stronger bond, and triple covalent bonds are shorter than either double or single covalent bonds. Thus, the C-N bond in is the shortest in length.

9

Which of the following is a characteristic of covalent bonds?

A covalent bond is one between two nonmetals.

A covalent bond is one between a metal and a nonmetal.

Covalent compounds dissolve in water to form cations and anions.

Covalent compounds are good conductors of electricity.

Explanation

A covalent bond is one between two nonmetals, while an ionic bond is formed between a metal and a nonmetal. Covalent bonds also do not dissociate in aqueous solution to form cations and anions; this is a characteristic of ionic bonds. For example, represents a bond between a metal () and a nonmetal (), and it dissociates in aqueous solution to form a cation () and an anion (). In contrast, represents a bond between two nonmetals, and it does not dissociate in aqueous solution. Ionic compounds are also good conductors of electricity, while covalent compounds are not. This is because moving electrons are required in order to conduct electricity. When dissolved in aqueous solution, ions are free to move and thus conduct electricity. Covalent bonds have localized electrons, which cannot move and thus cannot conduct electricity well.

10

Which of the following C-N bonds is the shortest?

The C-N bond in .

The C-N bond in .

The C-N bond in .

The C-N bond in .

Explanation

Drawing the Lewis Diagrams for these molecules reveals that the C-N bond in is a triple covalent bond, whereas the C-N bonds in and are double covalent bonds and the C-N bond in is a single covalent bond. Triple covalent bonds between two given atoms are always stronger than double bonds between these same two atoms, and similarly double bonds are even stronger than single bonds. Bond length is inversely related to bond strength; therefore a shorter bond is a stronger bond, and triple covalent bonds are shorter than either double or single covalent bonds. Thus, the C-N bond in is the shortest in length.

Page 1 of 13