Electrochemistry

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AP Chemistry › Electrochemistry

Questions 1 - 10
1

Consider the following electrolytic cell:

What happens at the anode in the electrolytic cell?

Nickel is oxidized

Nickel is reduced

Iron is oxidized

Iron is reduced

Explanation

It does not matter if the cell is galvanic or electrolytic; oxidation will always take place at the anode. This means that the nickel loses two electrons and is oxidized at the anode to generate nickel ions.

Nickel ions and iron are products, and are neither oxidized nor reduced during the reaction. Iron ions are reduced at the cathode to generate the iron product.

2

Consider the following electrolytic cell:

What happens at the anode in the electrolytic cell?

Nickel is oxidized

Nickel is reduced

Iron is oxidized

Iron is reduced

Explanation

It does not matter if the cell is galvanic or electrolytic; oxidation will always take place at the anode. This means that the nickel loses two electrons and is oxidized at the anode to generate nickel ions.

Nickel ions and iron are products, and are neither oxidized nor reduced during the reaction. Iron ions are reduced at the cathode to generate the iron product.

3

Toward which pole do the electrons travel in an electrolytic cell?

Towards the cathode

Towards the anode

Towards the positive pole

More information is needed

The electrons do not travel; only the protons travel

Explanation

Reduction always occurs at the cathode, and oxidation always occurs at the anode. Since reduction is the addition of electrons, electrons must travel toward the site of reduction.

In an electrolytic cell the negative charge is on the cathode, while the positive charge is on the anode. Since an electrolytic cell requires energy to perpetuate the reaction, we are pushing the electrons against their potential gradient. The electrons, which are negatively charged, are traveling towards the cathode, which is also negatively charged.

4

Toward which pole do the electrons travel in an electrolytic cell?

Towards the cathode

Towards the anode

Towards the positive pole

More information is needed

The electrons do not travel; only the protons travel

Explanation

Reduction always occurs at the cathode, and oxidation always occurs at the anode. Since reduction is the addition of electrons, electrons must travel toward the site of reduction.

In an electrolytic cell the negative charge is on the cathode, while the positive charge is on the anode. Since an electrolytic cell requires energy to perpetuate the reaction, we are pushing the electrons against their potential gradient. The electrons, which are negatively charged, are traveling towards the cathode, which is also negatively charged.

5

How does an electrolytic cell differ from a galvanic cell?

The cathode is marked negative in an electrolytic cell

Oxidation takes place at the anode in an electrolytic cell, but at the cathode in a galvanic cell

Oxidation takes place at the anode in a galvanic cell, but at the cathode in an electrolytic cell

The cell potential is positive in an electrolytic cell

Explanation

Oxidation always takes place at the anode, regardless of the electrical cell type. The charges on the anode and cathode are reversed between galvanic and electrolytic cells. In electrolytic cells, the cathodes are marked negative and the anodes are marked positive. In galvanic cells, the reverse is true: cathodes are marked positive and anodes are marked negative.

6

How does an electrolytic cell differ from a galvanic cell?

The cathode is marked negative in an electrolytic cell

Oxidation takes place at the anode in an electrolytic cell, but at the cathode in a galvanic cell

Oxidation takes place at the anode in a galvanic cell, but at the cathode in an electrolytic cell

The cell potential is positive in an electrolytic cell

Explanation

Oxidation always takes place at the anode, regardless of the electrical cell type. The charges on the anode and cathode are reversed between galvanic and electrolytic cells. In electrolytic cells, the cathodes are marked negative and the anodes are marked positive. In galvanic cells, the reverse is true: cathodes are marked positive and anodes are marked negative.

7

Which of the following species is being produced at the anode?

Explanation

Remember: AN OX and RED CAT (the ANode is the site of OXidation, and REDuction takes place at the CAThode). Also remember OIL RIG (Oxidation Is Loss of electrons and Reduction Is Gain of electrons). The question asks us which species is produced at the cathode (site of reduction). Also, remember that electrons always flow from anode to cathode, and that galvanic cells are spontaneous reactions (positive ), and since electrons are negatively charged, they spontaneously flow from the anode (negative cell) to the cathode (positive cell) according to the law of attraction. is being produced at the anode because electrons are being transferred from the anode to the cathode. In this case, the lithium ions are gaining electrons to form solid lithium at the cathode. Solid potassium is losing electrons at the anode to form .

8

Which of the following species is being produced at the anode?

Explanation

Remember: AN OX and RED CAT (the ANode is the site of OXidation, and REDuction takes place at the CAThode). Also remember OIL RIG (Oxidation Is Loss of electrons and Reduction Is Gain of electrons). The question asks us which species is produced at the cathode (site of reduction). Also, remember that electrons always flow from anode to cathode, and that galvanic cells are spontaneous reactions (positive ), and since electrons are negatively charged, they spontaneously flow from the anode (negative cell) to the cathode (positive cell) according to the law of attraction. is being produced at the anode because electrons are being transferred from the anode to the cathode. In this case, the lithium ions are gaining electrons to form solid lithium at the cathode. Solid potassium is losing electrons at the anode to form .

9

Which of the following species would mostly likely be reduced, if placed in a galvanic cell with another species?

Explanation

Remember that reduced means to gain electron, while oxidized means to lose electrons.

Using the equation: , for a spontaneous reaction to occur, must be positive. With solid mercury as the product, any other solid can act as the reactants, and still give a positive , because it has the highest value.

As a result, the equation,, remains unchanged, and mercury ions will gain electrons and be reduced to liquid mercury. Any other paired equation must be inverted to give electrons.

10

Which of the following species would mostly likely be reduced, if placed in a electrochemical cell with another species?

Explanation

Using the equation: , for a spontaneous reaction to occur, must be positive. With chlorine ions as the product, any other solid can act as the reactants, and still give a positive , because it has the highest value. As a result, the equation,, remains unchanged, and chlorine gas will gain electrons and reduce to chlorine ions. Any other paired equation must be inverted to give electrons.

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