Acids and Bases - AP Chemistry

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Question

All acids have which phase label?

Answer

Acids are soluble in water substance, but remember, only water gets the liquid (l) phase label. Since acids are almost always dissolved in water, we use the (aq) subscript at the end of the chemical formula to indicate its phase.

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Question

What is the Bronsted-Lowry definition of acids?

Answer

According to the Bronsted-Lowry definition, acids are hydrogen donors.

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Question

What is the definition of a Bronsted-Lowry base?

Answer

According to the Bronsted-Lowry definition, bases are hydrogen acceptors.

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Question

According to the Arrhenius definition, acids __________.

Answer

According to the Arrhenius definition, acids increase the concentration of hydrogen ions in a solution.

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Question

According to the Arrhenius definition __________.

Answer

According to theArrhenius definition, bases increase the concentration of hydroxide ions in a solution.

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Question

According to the Lewis definition, acids are __________.

Answer

According to the Lewis definition, acids are electron pair acceptors.

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Question

What is the Lewis definition of bases?

Answer

According to the Lewis definition, bases are electron pair donors.

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Question

What does amphoteric mean?

Answer

An amphoteric substance is one that can act either as an acid or a base. Amino acids are good examples of amphoteric substances; they have a carboxylic acid group that can be acidic, and an amino group that can be basic.

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Question

A buffer solution is a solution that __________.

Answer

A buffer solution is used to keep the pH of the solution within a relatively narrow range. It must resist change in pH upon addition of acids or bases. A weak acid is used to lower the pH in response to addition of base or removal of acid, and its conjugate base is used to raise the pH in response to addition of acid or removal of base.

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Question

There are __________ hydrogen ions in a solution with a pH of 3 than in a solution with a pH of 6.

Answer

Each whole number on the pH scale represents a factor of ten difference in concentration of hydrogen ions. We con verify this by finding the hydrogen ion concentrations for the two given pH values.

If we take the ratio of these values, we can see that there is a difference of 1000-times more protons in the solution with a pH of 3.

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Question

A sample of gastric juice has a pH of 2.5. What is the hydrogen ion concentration in this secretion?

Answer

The concentration of hydrogen ions must lie somewhere between and ; alternatively stated, it is between and . The pH of a solution with hydrogen ion concentration of will be 3, and the pH of a solution with hydrogen ion concentration will be 2; thus, our concentration must lie between these two values, since our pH is 2.5

To find the exact concentration, you must be familiar with the logarithmic scale. A difference of 0.5 is equivalent to a log of 3.

Our answer must therefore be , or .

We can calculate the pH in reverse to check our answer.

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Question

Sodium hydroxide is a strong base. What is the pH of a 0.02M sodium hydroxide solution?

Answer

Since sodium hydroxide is a strong base, it will dissociate completely in water. This means that the concentration of the base will be equal to the concentration of hydroxide ions after the reaction runs to completion.

We can find the concentration of hydroxide ions via stoichiometry. One hydroxide ion is created from each molecule of sodium hydroxide that dissociates.

Since we have the concentration of hydroxide ions, we can solve for the pOH of the solution.

The question asks us to find the pH of the solution, so we will need to convert pOH to pH. To do so, we simply subtract the pOH from 14.

The pH of the solution is 12.3. Because sodium hydroxide is a strong base, it makes sense that the pH is above 7.

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Question

Acids and bases can be described in three principal ways. The Arrhenius definition is the most restrictive. It limits acids and bases to species that donate protons and hydroxide ions in solution, respectively. Examples of such acids include HCl and HBr, while KOH and NaOH are examples of bases. When in aqueous solution, these acids proceed to an equilibrium state through a dissociation reaction.

All of the bases proceed in a similar fashion.

The Brønsted-Lowry definition of an acid is a more inclusive approach. All Arrhenius acids and bases are also Brønsted-Lowry acids and bases, but the converse is not true. Brønsted-Lowry acids still reach equilibrium through the same dissociation reaction as Arrhenius acids, but the acid character is defined by different parameters. The Brønsted-Lowry definition considers bases to be hydroxide donors, like the Arrhenius definition, but also includes conjugate bases such as the A- in the above reaction. In the reverse reaction, A- accepts the proton to regenerate HA. The Brønsted-Lowry definition thus defines bases as proton acceptors, and acids as proton donors.

The pH of a solution of is lowered from 4 to 3, and then from 3 to 2. Which of the following is the most accurate description of what happens during these transitions?

Answer

The pH scale is logarithmic. Every pH unit drop corresponds to a tenfold increase in protons.

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Question

Acids and bases can be described in three principal ways. The Arrhenius definition is the most restrictive. It limits acids and bases to species that donate protons and hydroxide ions in solution, respectively. Examples of such acids include HCl and HBr, while KOH and NaOH are examples of bases. When in aqueous solution, these acids proceed to an equilibrium state through a dissociation reaction.

All of the bases proceed in a similar fashion.

The Brønsted-Lowry definition of an acid is a more inclusive approach. All Arrhenius acids and bases are also Brønsted-Lowry acids and bases, but the converse is not true. Brønsted-Lowry acids still reach equilibrium through the same dissociation reaction as Arrhenius acids, but the acid character is defined by different parameters. The Brønsted-Lowry definition considers bases to be hydroxide donors, like the Arrhenius definition, but also includes conjugate bases such as the A- in the above reaction. In the reverse reaction, A- accepts the proton to regenerate HA. The Brønsted-Lowry definition thus defines bases as proton acceptors, and acids as proton donors.

A scientist is studying an aqueous sample of , and finds that the hydroxide concentration is . Which of the following is true?

Answer

Given the hydroxide ion concentration, we will need to work using pOH to find the pH. We know that the sum of pH and pOH is equal to 14.

Use our value for the concentration to find the pOH.

Now that we have the pOH, we can use it to solve for the pH.

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Question

Hydrochloric acid (HCl) is which of the following?

Answer

Strong acids and bases dissociate completely into ions when placed in an aqueous solution. In contrast, weak acids and bases do not completely dissociate.

There are only six strong acids: perchloric acid (HClO4), hydroiodic acid (HI), hydrobromic acid (HBr), hydrochloric acid (HCl), nitric acid (HNO3), and sulfuric acid (H2SO4).

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Question

What is the pOH of a aqueous solution of ?

Answer

The first step for this problem is to find the pH. We can then derive the pOH from the pH value.

The pH is given by the equation . Since hydrochloric acid is monoprotic, the concentration of the solution is equal to the concentration of protons.

Using this value and the pH equation, we can calculate the pH.

Now we can find the pOH. The sum of the pH and the pOH is always 14.

The pOH of the solution is 7.8.

Alternatively, a shortcut can be used to estimate the pH. If is in the form , then pH is roughly .

For this question, this shortcut gets us a pH of 6.4, which produces a pOH of 7.6; very close to the real answer!

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Question

An arterial blood sample from a patient has a pH of 7.4. One day later, the same patient has an arterial blood pH of 7.15. How many times more acidic is the patient's blood on the second day?

Answer

The equation to calculate pH is:

The normal pH of arterial blood is around 7.4. This reflects a concentration of hydrogen ions that can be found using the pH equation.

Using similar calculations for the second blood sample, we can find the hydrogen ion concentration again.

Now that we have both concentrations, can find the ratio of the acidity of the two samples.

You may know from biological sciences that this is approaching a lethal level of acidosis.

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Question

You are presented with a solution that has a pOH of 2.13. What is the pH of this solution?

Answer

pH and pOH are the log concentrations of protons and hydroxide ions, respectively.

The sum of pH and pOH is always 14. This is because the product of proton concentration and hydroxide concentration must always equal the equilibrium constant for the ionization of water, which is equal to .

In this question, we know that the pOH is equal to 2.13, allowing us to solve for the pH.

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Question

What is the pH for a 0.05M solution of hydrochloric acid?

Answer

Hydrochloric acid is a strong monoprotic acid, meaning that it will dissociate completely in solution and generate one proton from each acid molecule. This means that a 0.05M solution of hydrochloric acid will result in a 0.05M concentration of protons.

The equation for pH is as follows:

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Question

How does the Brønsted-Lowry theory of acids and bases describe acids?

Answer

There are three primary classifications of acids and bases.

Arrhenius acids yield protons when dissolved in solution, while Arrhenius bases yield hydroxide ions.

Brønsted-Lowry acids are protone donors, while Brønsted-Lowry bases are proton acceptors.

Lewis acids are electron acceptors, while Lewis bases are electron donors.

An acid that dissociates completely in solution is considered a strong acid due to its high Ka value.

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