AP Chemistry

Intermolecular Forces

Learn Intermolecular Forces in AP Chemistry from the production AIPH study guide.

Advanced Topics

In a nutshell: Intermolecular forces determine many physical properties of substances.

## Forces Between Molecules Intermolecular forces (IMFs) are weak attractions between molecules that affect physical properties like boiling and melting points, solubility, and evaporation. ### Types of Intermolecular Forces - **London Dispersion Forces:** Weakest; present in all molecules. - **Dipole-Dipole Interactions:** Between polar molecules. - **Hydrogen Bonding:** Strong type of dipole interaction, occurs when H is bonded to N, O, or F. ## Impact on Properties Stronger IMFs mean higher boiling/melting points. Water's high boiling point is due to hydrogen bonding! ## Everyday Connections - Water beads up on a car because of hydrogen bonding. - Butter is solid at room temperature due to weak London forces between its molecules.

Examples

  • Ice floats because of hydrogen bonding in water.
  • Perfume evaporates quickly due to weak London dispersion forces.

Key terms

Hydrogen Bond
A strong attraction between hydrogen and N, O, or F atoms in nearby molecules.
Dipole
A molecule with a partial positive and negative end.