5TH GRADE SCIENCE • MATTER AND ITS INTERACTIONS

Chemical Reactions: When New Substances Form

Why does a shiny copper penny turn green over time — and can you prove it's become something entirely new?

The Phenomenon: The Mystery of the Green Penny

ANCHORING PHENOMENON

Here's the mystery: the green coating on the penny is not just dirty copper. Scientists have tested it and found that the green material is actually a completely different substance — one that wasn't there when the penny was brand new. Something happened to the copper to change it into something new.

A shiny new penny transforms into a green-coated old penny over time through a chemical reaction with air and moisture.
THINKING QUESTIONS

What Scientists Know: Chemical Reactions and New Substances

When you mix substances together — or expose them to heat, light, or air — one of two things can happen. Sometimes the substances just mix together without changing. You can still separate them, and each substance keeps its own properties. This is called a physical change. Think of mixing sand and salt: you still have sand and you still have salt, just sitting next to each other.

But sometimes something more dramatic happens. The starting substances actually react with each other, and entirely new substances form that have different properties than what you started with. This is called a chemical reaction. The original substances are gone — you can't just pull them apart again. The green coating on a penny is a perfect example: copper reacted with gases in the air and moisture to create a completely new substance called copper carbonate, which has different properties than pure copper.

1

New Properties = New Substance

When a chemical reaction occurs, the new substance has different properties than the starting materials. It might be a different color, produce gas bubbles, give off heat, or have a new smell. These are clues that a new substance has formed.
2

Evidence You Can Observe

Scientists look for observable evidence to determine whether a chemical reaction happened. Key signs include: color change, gas production (bubbles), temperature change, new smell, and formation of a solid from two liquids (called a precipitate).
3

Not All Changes Are Chemical

Crushing, dissolving, melting, or freezing a substance changes its form but does not create a new substance. Dissolving sugar in water is a physical change — the sugar is still sugar, and you can get it back by evaporating the water. The key test: are the properties different?
4

Weight Is Conserved

In a chemical reaction, the total weight of the starting substances equals the total weight of the new substances. Matter doesn't appear or disappear — it rearranges into new substances. If you weigh everything before and after, the numbers match.
KEY TAKEAWAY
KEY TAKEAWAY

Let's Investigate: Testing for New Substances

What scientists do: Constructing Explanations from Evidence

Scientists don't just guess whether a new substance has formed — they gather evidence by carefully observing what happens before, during, and after mixing substances. They record changes in color, temperature, gas production, and other properties. Then they use that evidence to construct an explanation about whether a chemical reaction occurred.

Investigation question: When you combine baking soda and vinegar, does a new substance form? How do you know?

Materials:

  • Baking soda (white powder)
  • Vinegar (clear liquid with a sour smell)
  • A clear cup or jar
  • A thermometer (optional)
  • A kitchen scale

Procedure:

  • Observe the baking soda and vinegar separately. Record their color, smell, texture, and temperature.
  • Weigh the cup with baking soda and the vinegar separately. Record the total starting weight.
  • Pour the vinegar into the cup of baking soda and immediately observe what happens.
  • Record all changes you observe: bubbles, temperature, color, smell, sound.
  • After the reaction stops, observe the remaining substance. Has anything changed?
  • Weigh the cup and its contents again. Compare to the starting weight.

What you would observe: Immediate fizzing and bubbling (gas production!), a temperature drop (the mixture gets colder), and after the reaction, a clear liquid remains that tastes salty — very different from sour vinegar. The gas that escaped is carbon dioxide, a substance that wasn't there before.

Five types of evidence that indicate a new substance has formed in a chemical reaction.

What We Discovered: Using Evidence to Build Explanations

Let's go back to our baking soda and vinegar investigation. Before mixing, we had two substances with known properties: baking soda is a white, odorless solid; vinegar is a clear liquid with a strong sour smell. After mixing, several pieces of evidence told us that new substances formed.

First, we saw vigorous bubbling. Those bubbles were filled with carbon dioxide gas — a substance that didn't exist in either the baking soda or the vinegar by itself. Second, the temperature dropped, which tells us energy was absorbed during the reaction. Third, after the fizzing stopped, the liquid remaining in the cup tasted salty, not sour — it had different properties than the vinegar we started with. The remaining liquid was actually a new substance: sodium acetate dissolved in water.

Now here's the critical scientific thinking: not every change means a new substance formed. If you dissolve salt in water, the water looks clear and different — but that's a physical change. You can boil the water away and get your salt crystals back, exactly the same as before. The properties of the salt didn't change. With our baking soda and vinegar reaction, though, you cannot get the baking soda and vinegar back from the products. The change is irreversible because new substances with new properties were created.

PropertyBefore Reaction (Starting Substances)After Reaction (New Substances)Evidence of New Substance?
AppearanceWhite powder + clear liquidClear liquid only (solid dissolved)✓ Different
SmellNo smell (baking soda) + sour (vinegar)Very mild, not sour✓ Different
TasteBitter (baking soda) + sour (vinegar)Salty✓ Different
Gas produced?No gas presentCarbon dioxide gas (bubbles)✓ New substance
TemperatureRoom temperature (about 22°C)Cooler (about 17°C)✓ Energy change

Each row of this data table is a piece of evidence. Individually, one change might not prove a new substance formed. But when we look at multiple pieces of evidence together — a new color, new smell, new taste, gas production, and temperature change — the case becomes very strong. Scientists always look for multiple lines of evidence before concluding that a chemical reaction took place.

Physical Change vs. Chemical Change — comparison of examples and key features.

Patterns and Connections: Cause and Effect

The crosscutting concept in this lesson is Cause and Effect. In science, events have causes that generate observable patterns. When two substances interact in a chemical reaction, the cause is the interaction between the substances, and the effect is the formation of new substances with new properties. Scientists design tests to identify these cause-and-effect relationships — they don't just assume a reaction happened; they look for the evidence.

This same pattern — cause and effect — shows up across all areas of science. Let's look at how cause-and-effect thinking helps scientists in different fields.

Science AreaCauseEffect (Observable Evidence)How Scientists Know
Physical ScienceIron is exposed to oxygen and waterReddish-brown rust forms on the surfaceNew color, new texture, crumbles easily — different properties than iron
Life ScienceA plant receives no sunlightLeaves turn yellow, plant stops growingObservable changes in color and growth pattern — evidence that the plant's food-making process stopped
Earth ScienceAcid rain falls on limestone rockRock surface fizzes and wears awayGas production (bubbles) and erosion of rock — a chemical reaction between acid and limestone
Everyday LifeBread dough is baked in an ovenDough turns into bread with a brown crustNew color, new texture, new smell — the dough has chemically changed
KEY TAKEAWAY
KEY TAKEAWAY

Real-World Connections: Chemical Reactions All Around You

Chemical reactions aren't just something that happens in science labs. They're happening all around you, every single day — and now you have the tools to spot the evidence!

1

🍳 In the Kitchen

When you cook an egg, the clear, runny egg white turns solid and white. This is a chemical reaction — heat causes proteins in the egg to rearrange and form new substances. The evidence? New color (clear → white), new texture (liquid → solid), and you can't un-cook the egg. Similarly, when bread rises, yeast creates carbon dioxide gas (bubbles in the dough!) through a chemical reaction.
2

🏗️ In Construction

Concrete starts as a wet, gray mixture. Over time, a chemical reaction between water and cement powder creates new hard, solid substances that bind the gravel and sand together. Engineers monitor this chemical reaction carefully because the evidence — hardness and temperature increase — tells them whether the concrete is curing properly and will be strong enough to support a building.
3

🔋 In Technology

The battery in your phone or tablet works because of chemical reactions happening inside it. Substances inside the battery react with each other, and this reaction produces electrical energy. When the battery "dies," it means the chemical reaction has used up the starting substances. Rechargeable batteries can reverse this reaction — a rare example of a chemical change that can go both ways!
4

🛡️ In Protecting Things

Engineers use their understanding of chemical reactions to prevent unwanted ones. They coat steel bridges with paint to keep oxygen and water away from the iron, preventing the chemical reaction that causes rust. They add special chemicals to food to slow down the reactions that cause spoiling. Understanding what causes a chemical reaction helps engineers stop it when they need to.

Key Vocabulary Review

  • Chemical reaction — A process in which one or more substances interact and are changed into new substances with different properties.
  • Physical change — A change in the form or appearance of a substance that does not create a new substance. The original substance can usually be recovered.
  • Properties — Characteristics of a substance that can be observed or measured, such as color, smell, texture, melting point, and whether it dissolves in water.
  • Evidence — Observations, data, or information that support or help explain a claim. Scientists use evidence to determine whether a chemical reaction occurred.
  • Gas production — The formation of bubbles or fizzing during a reaction, which indicates that a new gaseous substance has been created.
  • Precipitate — A solid that forms when two liquids are mixed together, indicating that a new substance has been created.
  • Conservation of matter — The principle that the total weight of substances before a reaction equals the total weight of substances after a reaction. Matter is not created or destroyed — it rearranges.

Practice: Test Your Understanding

1
Maria mixes baking soda and vinegar together in a bowl. She notices bubbles forming, the mixture fizzing, and the bowl feels cold to the touch. What is the BEST evidence that a new substance has formed?
2
Jake leaves his steel bicycle outside in the rain for several weeks. He notices a flaky, reddish-brown coating forming on the metal parts. Which observation is the BEST evidence that a new substance has formed on the bicycle?
3
A student heats a marshmallow over a campfire. The white marshmallow turns black and gives off a smoky smell. The student says, 'A new substance formed.' Which evidence BEST supports this claim?
4
In science class, students do two activities. In Activity 1, they dissolve sugar in warm water. In Activity 2, they mix milk with lemon juice and observe white clumps forming. Which statement CORRECTLY identifies where a new substance formed?
5
Priya is investigating whether new substances form in different situations. She records these observations: Situation 1: Crushing a cracker into small pieces. Situation 2: Cutting an apple and watching the white inside turn brown after 20 minutes. Situation 3: Freezing orange juice into popsicles. In which situation does the evidence BEST support that a new substance formed?

What's Next?

WHAT'S NEXT?
Varsity Tutors • 5th Grade Science (NGSS) • Chemical Reactions: New Substances