Reactions by Reactant

Help Questions

Organic Chemistry › Reactions by Reactant

Questions 1 - 10
1

Noname02

What is the product of the given reaction?

Noname03

5

Noname04

Noname01

6

Explanation

This is a basic Claisen condensation reaction in which the functions to take off the acidic hydrogen (between the ketone and the ester) and then the same molecule can attack a carbonyl carbon to yield Noname03.

The attack at the ester carbonyl leads to the leaving of group.

2

Noname02

What is the product of the given reaction?

Noname03

5

Noname04

Noname01

6

Explanation

This is a basic Claisen condensation reaction in which the functions to take off the acidic hydrogen (between the ketone and the ester) and then the same molecule can attack a carbonyl carbon to yield Noname03.

The attack at the ester carbonyl leads to the leaving of group.

3

Noname02

What is the product of the given reaction?

Noname03

5

Noname04

Noname01

6

Explanation

This is a basic Claisen condensation reaction in which the functions to take off the acidic hydrogen (between the ketone and the ester) and then the same molecule can attack a carbonyl carbon to yield Noname03.

The attack at the ester carbonyl leads to the leaving of group.

4

Predict the major product of the following reaction.

3

I

II

III

IV

Explanation

Alkenes are saturated by hydrogen gas in the presence of a palladium catalyst. This type of reaction is termed catalytic hydrogenation and results in syn addition of hydrogen across a double bond. Molecules II, III, and IV have all undergone oxidation-reduction reactions and do not result from the given conditions. Molecule I is altered only by hydrogenation of the 2-3 double bond and is the correct answer.

5

What is the product of the following reaction?

Screen shot 2015 11 13 at 1.56.05 pm

Screen shot 2015 11 13 at 1.56.10 pm

II and III

II only

I and II

IV only

Explanation

Treatment of ethyl acetate with methoxide will yield the enolate ion (II). However, side trans-esterification reactions will also result in formation of product III.

6

What is the product of the following reaction?

Screen shot 2015 11 13 at 1.56.05 pm

Screen shot 2015 11 13 at 1.56.10 pm

II and III

II only

I and II

IV only

Explanation

Treatment of ethyl acetate with methoxide will yield the enolate ion (II). However, side trans-esterification reactions will also result in formation of product III.

7

Predict the major product of the following reaction.

3

I

II

III

IV

Explanation

Alkenes are saturated by hydrogen gas in the presence of a palladium catalyst. This type of reaction is termed catalytic hydrogenation and results in syn addition of hydrogen across a double bond. Molecules II, III, and IV have all undergone oxidation-reduction reactions and do not result from the given conditions. Molecule I is altered only by hydrogenation of the 2-3 double bond and is the correct answer.

8

What is the product of the following reaction?

Screen shot 2015 11 13 at 1.56.05 pm

Screen shot 2015 11 13 at 1.56.10 pm

II and III

II only

I and II

IV only

Explanation

Treatment of ethyl acetate with methoxide will yield the enolate ion (II). However, side trans-esterification reactions will also result in formation of product III.

9

Predict the major product of the following reaction.

3

I

II

III

IV

Explanation

Alkenes are saturated by hydrogen gas in the presence of a palladium catalyst. This type of reaction is termed catalytic hydrogenation and results in syn addition of hydrogen across a double bond. Molecules II, III, and IV have all undergone oxidation-reduction reactions and do not result from the given conditions. Molecule I is altered only by hydrogenation of the 2-3 double bond and is the correct answer.

10

Screen shot 2016 01 10 at 9.41.14 pm

What is the product of the reaction given?

Screen shot 2016 01 10 at 9.41.59 pm

Screen shot 2016 01 10 at 9.42.08 pm

Screen shot 2016 01 10 at 9.42.23 pm

Screen shot 2016 01 10 at 9.42.16 pm

Explanation

Below is the mechanism for the reaction given which is called the McMurry Reaction. It is a titanium (Ti) prompted pinacol coupling followed by deoxygenation.

Screen shot 2016 01 10 at 9.42.29 pm

Page 1 of 21