Reactions by Reactant

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Organic Chemistry › Reactions by Reactant

Questions 1 - 10
1

Noname02

What is the product of the given reaction?

Noname03

5

Noname04

Noname01

6

Explanation

This is a basic Claisen condensation reaction in which the functions to take off the acidic hydrogen (between the ketone and the ester) and then the same molecule can attack a carbonyl carbon to yield Noname03.

The attack at the ester carbonyl leads to the leaving of group.

2

Noname02

What is the product of the given reaction?

Noname03

5

Noname04

Noname01

6

Explanation

This is a basic Claisen condensation reaction in which the functions to take off the acidic hydrogen (between the ketone and the ester) and then the same molecule can attack a carbonyl carbon to yield Noname03.

The attack at the ester carbonyl leads to the leaving of group.

3

Noname02

What is the product of the given reaction?

Noname03

5

Noname04

Noname01

6

Explanation

This is a basic Claisen condensation reaction in which the functions to take off the acidic hydrogen (between the ketone and the ester) and then the same molecule can attack a carbonyl carbon to yield Noname03.

The attack at the ester carbonyl leads to the leaving of group.

4

What is the product of the following reaction?

Screen shot 2015 11 13 at 1.56.05 pm

Screen shot 2015 11 13 at 1.56.10 pm

II and III

II only

I and II

IV only

Explanation

Treatment of ethyl acetate with methoxide will yield the enolate ion (II). However, side trans-esterification reactions will also result in formation of product III.

5

What is the product of the following reaction?

Screen shot 2015 11 13 at 1.56.05 pm

Screen shot 2015 11 13 at 1.56.10 pm

II and III

II only

I and II

IV only

Explanation

Treatment of ethyl acetate with methoxide will yield the enolate ion (II). However, side trans-esterification reactions will also result in formation of product III.

6

Predict the major product of the following reaction.

3

I

II

III

IV

Explanation

Alkenes are saturated by hydrogen gas in the presence of a palladium catalyst. This type of reaction is termed catalytic hydrogenation and results in syn addition of hydrogen across a double bond. Molecules II, III, and IV have all undergone oxidation-reduction reactions and do not result from the given conditions. Molecule I is altered only by hydrogenation of the 2-3 double bond and is the correct answer.

7

What is the product of the following reaction?

Screen shot 2015 11 13 at 1.56.05 pm

Screen shot 2015 11 13 at 1.56.10 pm

II and III

II only

I and II

IV only

Explanation

Treatment of ethyl acetate with methoxide will yield the enolate ion (II). However, side trans-esterification reactions will also result in formation of product III.

8

Predict the major product of the following reaction.

3

I

II

III

IV

Explanation

Alkenes are saturated by hydrogen gas in the presence of a palladium catalyst. This type of reaction is termed catalytic hydrogenation and results in syn addition of hydrogen across a double bond. Molecules II, III, and IV have all undergone oxidation-reduction reactions and do not result from the given conditions. Molecule I is altered only by hydrogenation of the 2-3 double bond and is the correct answer.

9

Predict the major product of the following reaction.

3

I

II

III

IV

Explanation

Alkenes are saturated by hydrogen gas in the presence of a palladium catalyst. This type of reaction is termed catalytic hydrogenation and results in syn addition of hydrogen across a double bond. Molecules II, III, and IV have all undergone oxidation-reduction reactions and do not result from the given conditions. Molecule I is altered only by hydrogenation of the 2-3 double bond and is the correct answer.

10

The compound below is reacted with . What is the final hybridization around the initially chiral center carbon when the reaction is complete?

Propanol

Explanation

The initially chiral carbon has an hybridization. Once treated with ,an oxidizing agent, the secondary alcohol in the compound is oxidized to a ketone. The central carbon is no longer a chiral center (a carbon with a double bond cannot be chiral), and the double bond (pi-bond) formed between carbon and oxygen gives the molecule an hybridization.

hybridization is formed with triple bonds, and an hybridization does not exist.

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