An ideal gas is confined to a cylinder by a piston. The gas is heated, causing it to expand from volume V1 to V2 in such a way that its pressure is directly proportional to its volume (P=kV for some constant k). If the initial temperature is T1, what is the final temperature T2?
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Question 1
An ideal gas is confined to a cylinder by a piston. The gas is heated, causing it to expand from volume V1 to V2 in such a way that its pressure is directly proportional to its volume (P=kV for some constant k). If the initial temperature is T1, what is the final temperature T2?
T1(V2/V1)
T1(V1/V2)
T1(V2/V1)2 (correct answer)
T1V2/V1
Explanation: From the ideal gas law, T is proportional to PV for a fixed amount of gas (T ∝ PV). We are given that pressure is proportional to volume, P ∝ V. Substituting this into the temperature proportionality, we get T ∝ (V)V, which means T ∝ V². Therefore, the ratio of the temperatures is equal to the ratio of the volumes squared: T₂/T₁ = (V₂/V₁)². Solving for T₂ gives T₂ = T₁ (V₂/V₁)².
Question 2
Container X holds an ideal gas of molar mass M at pressure P and temperature T. Container Y holds a different ideal gas of molar mass (2M) at pressure 2P and temperature 4T. What is the ratio of the density of the gas in Y to the density of the gas in X (ρY/ρX)?
0.25
0.5
1.0 (correct answer)
4.0
Explanation: The ideal gas law is PV = nRT. Since the number of moles n = m/M (mass/molar mass) and density ρ = m/V, we can substitute these in. PV = (m/M)RT → P = (m/V)(RT/M) → P = ρ(RT/M). Rearranging for density gives ρ = PM/(RT). For container X, ρ_X = PM/(RT). For container Y, ρ_Y = (2P)(2M)/(R(4T)) = 4PM/(4RT) = PM/(RT). The ratio ρ_Y / ρ_X is (PM/(RT)) / (PM/(RT)) = 1.0.
Question 3
An ideal monatomic gas is held in a rigid container of fixed volume. The absolute temperature of the gas is quadrupled. By what factor does the root-mean-square (rms) speed of the gas molecules increase?
2
2 (correct answer)
4
16
Explanation: The average kinetic energy of a gas molecule is directly proportional to the absolute temperature (T): E_k = (1/2)m<c²> ∝ T. The root-mean-square speed (c_rms) is defined as <c2>. From the energy relation, <c²> ∝ T, which means c_rms ∝ T. If the absolute temperature T is quadrupled (T → 4T), the new rms speed will be proportional to 4T = 2T. Therefore, the rms speed increases by a factor of 2.
Question 4
Two moles of an ideal monatomic gas are heated at a constant volume, causing the temperature to increase from 300 K to 500 K. What is the increase in the internal energy of the gas? (Universal gas constant R = 8.31 J K⁻¹ mol⁻¹)
2.5 kJ
3.3 kJ
5.0 kJ (correct answer)
8.3 kJ
Explanation: The internal energy (U) of an ideal monatomic gas is given by U = (3/2)nRT. The change in internal energy (ΔU) is therefore ΔU = (3/2)nRΔT. Given n = 2.0 mol, R = 8.31 J K⁻¹ mol⁻¹, and ΔT = 500 K - 300 K = 200 K. Substituting these values: ΔU = (3/2) × (2.0 mol) × (8.31 J K⁻¹ mol⁻¹) × (200 K) = 3.0 × 8.31 × 200 J = 4986 J, which is approximately 5.0 kJ.
Question 5
The kinetic model of an ideal gas is based on several assumptions. Which of the following is NOT an assumption of this model?
The gas molecules are in continuous, random motion.
Collisions between gas molecules are perfectly elastic.
The volume occupied by the gas molecules is negligible.
There are significant long-range forces between molecules. (correct answer)
Explanation: The key assumptions of the kinetic model for an ideal gas are: (A) molecules are in random motion, (B) all collisions are perfectly elastic, (C) the volume of the molecules themselves is negligible compared to the container's volume, and that intermolecular forces are negligible except during the very brief collisions. Statement D contradicts a core assumption of the ideal gas model.
Question 6
The plunger of a sealed syringe containing an ideal gas is pushed in slowly, halving the volume of the gas. The process is slow enough that the temperature of the gas remains constant. Which statement is correct?
The pressure doubles and the average kinetic energy of the molecules doubles.
The pressure is halved and the internal energy of the gas is halved.
The pressure doubles and the average kinetic energy of the molecules remains constant. (correct answer)
The pressure remains constant and the internal energy of the gas remains constant.
Explanation: The process is isothermal (constant temperature). According to Boyle's Law (P₁V₁ = P₂V₂), if the volume is halved (V₂ = V₁/2), the pressure must double (P₂ = 2P₁) to keep the product constant. The average kinetic energy of the molecules of an ideal gas (E_k = 3/2 k_B T) depends only on the absolute temperature. Since the temperature is constant, the average kinetic energy of the molecules remains constant.
Question 7
A container of volume V holds an ideal gas at pressure P and absolute temperature T. A second container of volume 2V holds another ideal gas at pressure 3P and absolute temperature 2T. What is the ratio of the number of molecules in the second container to the number of molecules in the first container?
1.5
3.0 (correct answer)
6.0
12.0
Explanation: The ideal gas law in terms of the number of molecules N is PV = Nk_B T. We can rearrange this to solve for N: N = PV / (k_B T). For the first container, N₁ = PV / (k_B T). For the second container, the pressure is P₂=3P, the volume is V₂=2V, and the temperature is T₂=2T. So, N₂ = (3P)(2V) / (k_B(2T)) = 6PV / (2k_B T) = 3PV / (k_B T). The ratio N₂/N₁ is (3PV / (k_B T)) / (PV / (k_B T)) = 3.0.
Question 8
An ideal gas expands to four times its initial volume. The expansion happens in such a way that the product of pressure and volume remains constant (PV=constant). What is the ratio of the final root-mean-square speed of the molecules to the initial root-mean-square speed?
1 (correct answer)
2
4
1/2
Explanation: For a fixed amount of an ideal gas, the ideal gas law states PV = nRT. If the product PV remains constant during the process, then the temperature T must also remain constant. This describes an isothermal expansion. The root-mean-square speed of the molecules (c_rms) is directly related to the absolute temperature (c_rms ∝ T). Since the temperature does not change, the rms speed also does not change. Therefore, the ratio of the final rms speed to the initial rms speed is 1.
Question 9
The internal energy of a sample of 2.0 moles of an ideal monatomic gas at 300 K is U. A second sample of 1.0 mole of the same gas has its temperature increased to 600 K. What is the internal energy of the second sample in terms of U?
U/2
U (correct answer)
2U
4U
Explanation: The internal energy of an ideal monatomic gas is given by U = (3/2)nRT. For the first sample, U₁ = (3/2) × (2.0 mol) × R × (300 K) = 900R. We are given that U₁ = U. For the second sample, n₂ = 1.0 mol and T₂ = 600 K. Its internal energy is U₂ = (3/2) × (1.0 mol) × R × (600 K) = 900R. Comparing the two, U₂ = 900R and U₁ = 900R, so U₂ = U₁. The halving of the number of moles is exactly compensated by the doubling of the temperature.
Question 10
Samples of helium (molar mass ≈ 4 g/mol) and neon (molar mass ≈ 20 g/mol) are ideal gases at the same temperature. Which statement correctly compares the average kinetic energy per molecule (Ek) and the root-mean-square speed (crms) of their atoms?
Ek is greater for neon; crms is greater for helium.
Ek is the same for both; crms is greater for helium. (correct answer)
Ek is the same for both; crms is the same for both.
Ek is greater for helium; crms is greater for neon.
Explanation: According to the kinetic theory of gases, the average kinetic energy per molecule of an ideal gas depends only on its absolute temperature (E_k = 3/2 k_B T). Since both gases are at the same temperature, their average kinetic energies per molecule are the same. Average kinetic energy is also given by E_k = (1/2)m<c²>, where m is the mass of a molecule. Since E_k is the same for both, the gas with the smaller molecular mass must have a larger mean-square speed (<c²>) and thus a larger rms speed. Helium has a smaller molar mass than neon, so its atoms have a greater rms speed.
Question 11
A 2.0 L container holding an ideal gas at 3.0 × 10⁵ Pa is connected by a valve to a 3.0 L container holding the same ideal gas at 1.0 × 10⁵ Pa. Both containers are at the same constant temperature. The valve is opened and the gases mix. What is the final pressure in the containers?
1.2 × 10⁵ Pa
1.8 × 10⁵ Pa (correct answer)
2.0 × 10⁵ Pa
4.0 × 10⁵ Pa
Explanation: Since temperature is constant, we can use Boyle's Law in the form P₁V₁ + P₂V₂ = P_f V_f. The total number of moles is conserved. From PV=nRT, n is proportional to PV when T is constant. The total number of moles is n_total = n₁ + n₂. Therefore, (P_f V_f)/(RT) = (P₁V₁)/(RT) + (P₂V₂)/(RT). The RT terms cancel, giving P_f V_f = P₁V₁ + P₂V₂. The final volume is V_f = 2.0 L + 3.0 L = 5.0 L. So, P_f × (5.0 L) = (3.0 × 10⁵ Pa × 2.0 L) + (1.0 × 10⁵ Pa × 3.0 L). P_f × 5.0 = 6.0 × 10⁵ + 3.0 × 10⁵ = 9.0 × 10⁵. P_f = (9.0 × 10⁵) / 5.0 = 1.8 × 10⁵ Pa.
Question 12
An air bubble is released from the bottom of a deep lake where the pressure is significantly higher than at the surface and the temperature is lower. It rises to the surface. Assuming the air behaves as an ideal gas, what happens to the volume of the bubble as it rises?
It increases because the external pressure decreases and the temperature increases. (correct answer)
It decreases because the temperature effect is smaller than the pressure effect.
It remains constant as the pressure decrease is balanced by the temperature increase.
It increases because the external pressure decreases, while the temperature change is negligible.
Explanation: The amount of air (n) in the bubble is constant. The relationship between pressure (P), volume (V), and absolute temperature (T) is given by the ideal gas law, PV = nRT, so V = nRT/P. As the bubble rises, the external pressure (P) decreases due to the smaller depth of water above it. The temperature (T) typically increases as it moves from the cold bottom to the warmer surface. Both the decrease in P (denominator) and the increase in T (numerator) cause the volume V to increase. Therefore, the bubble's volume must increase.
Question 13
An ideal gas is held in a cylinder by a movable piston. The initial pressure is P, volume is V, and absolute temperature is T. The pressure is doubled, and the absolute temperature is increased by 50%. What is the new volume of the gas?
0.50 V
0.75 V (correct answer)
1.33 V
3.0 V
Explanation: According to the combined gas law, P₁V₁/T₁ = P₂V₂/T₂ for a fixed amount of gas. Let the initial state be (P, V, T). The final state is P₂ = 2P and T₂ = T + 0.5T = 1.5T. We need to find V₂. Rearranging the formula: V₂ = V₁ × (P₁/P₂) × (T₂/T₁). Substituting the values: V₂ = V × (P / 2P) × (1.5T / T) = V × (1/2) × 1.5 = 0.75V.
Question 14
A flexible balloon is being inflated with more air at a constant temperature. The external atmospheric pressure is also constant. How is the volume V of the balloon related to the number of air molecules N inside it?
V is directly proportional to N. (correct answer)
V is inversely proportional to N.
V is proportional to the square of N.
V is independent of N.
Explanation: The ideal gas law is PV = Nk_B T. In this scenario, the pressure P is constant (equal to the external atmospheric pressure), the temperature T is constant, and k_B is the Boltzmann constant. Rearranging the equation for V gives V = (k_B T / P) × N. Since the term in the parentheses is constant, the volume V is directly proportional to the number of molecules N. This is also known as Avogadro's Law.
Question 15
A cylinder contains 0.50 m³ of an ideal gas at a pressure of 1.0 × 10⁵ Pa. The cylinder is fitted with a frictionless piston of area 0.10 m². The gas is heated slowly, causing the piston to move outwards by 0.20 m against constant external pressure. The final pressure of the gas is 1.0 × 10⁵ Pa. If the initial temperature was 300 K, what is the final temperature?
288 K
300 K
312 K (correct answer)
360 K
Explanation: The process occurs at constant pressure (isobaric). First, calculate the change in volume: ΔV = Area × distance = 0.10 m² × 0.20 m = 0.02 m³. The final volume is V₂ = V₁ + ΔV = 0.50 m³ + 0.02 m³ = 0.52 m³. For an isobaric process, Charles's Law applies: V₁/T₁ = V₂/T₂. Rearranging for the final temperature T₂: T₂ = T₁ × (V₂/V₁) = 300 K × (0.52 m³ / 0.50 m³) = 300 K × 1.04 = 312 K.
Question 16
A sealed, rigid container holds an ideal gas at a pressure of 1.5 × 10⁵ Pa and a temperature of 27 °C. The gas is then heated to a temperature of 127 °C. What is the new pressure of the gas?
1.1 × 10⁵ Pa
1.7 × 10⁵ Pa
2.0 × 10⁵ Pa (correct answer)
7.1 × 10⁵ Pa
Explanation: For an ideal gas in a sealed, rigid container, the volume (V) and the number of moles (n) are constant. According to the combined gas law (P₁V₁/T₁ = P₂V₂/T₂), this simplifies to Gay-Lussac's Law: P₁/T₁ = P₂/T₂. The temperatures must be in Kelvin. T₁ = 27 °C + 273 = 300 K. T₂ = 127 °C + 273 = 400 K. Rearranging for the final pressure, P₂ = P₁ × (T₂/T₁) = (1.5 × 10⁵ Pa) × (400 K / 300 K) = (1.5 × 10⁵ Pa) × (4/3) = 2.0 × 10⁵ Pa.
Question 17
A sealed cylinder contains an ideal gas at temperature T1=300 K and pressure P1=2.0×105 Pa. The gas is heated at constant volume until its pressure doubles. Then, the gas is allowed to expand isothermally until its pressure returns to the original value. What is the final volume of the gas compared to its initial volume?
The final volume is twice the initial volume (correct answer)
The final volume is four times the initial volume
The final volume is equal to the initial volume
The final volume is half the initial volume
Explanation: This problem involves two processes. First, constant volume heating: using Gay-Lussac's law, P₁/T₁ = P₂/T₂, so T₂ = T₁(P₂/P₁) = 300K × 2 = 600K. Second, isothermal expansion at 600K: using Boyle's law, P₂V₂ = P₃V₃, where P₃ = P₁ and T₃ = T₂ = 600K. Since P₃ = P₁ and the temperature doubled from initial to final state, using the ideal gas law PV = nRT with constant n: (P₁V₁)/(T₁) = (P₁V₃)/(T₃), so V₃ = V₁(T₃/T₁) = V₁(600K/300K) = 2V₁.
Question 18
A piston-cylinder assembly contains an ideal gas initially at 2.0 bar and 300 K. The gas undergoes two sequential processes: first, an adiabatic expansion where the volume triples, then an isothermal compression back to the original volume. If the adiabatic index γ = 1.4, what is the final temperature of the gas?
185 K, determined by the adiabatic relation and isothermal return process
300 K, since the gas returns to its original volume and pressure
162 K, calculated from the combined effect of both thermodynamic processes (correct answer)
220 K, found using the relationship between pressure and volume changes
Explanation: Process 1 (adiabatic): TV^(γ-1) = constant, so T₁V₁^0.4 = T₂V₂^0.4. With V₂ = 3V₁: T₂ = T₁(V₁/V₂)^0.4 = 300K(1/3)^0.4 = 300K(0.540) = 162K. Process 2 (isothermal): Temperature remains constant at 162K even though volume returns to V₁. The final state has the original volume but lower temperature and pressure. Choice A uses incorrect adiabatic calculation. Choice B incorrectly assumes return to initial state. Choice D uses wrong thermodynamic relations.
Question 19
A gas-filled balloon at sea level has a volume of 2.5 m³ at 288 K and 101.3 kPa. The balloon is transported to a mountain top where the atmospheric pressure is 67.5 kPa and temperature is 268 K. Assuming the balloon material stretches to maintain pressure equilibrium with the atmosphere, what is the balloon's new volume?
3.21 m³, obtained from the ideal gas relationship at constant mass
4.12 m³, determined by applying Boyle's law followed by Charles's law
2.89 m³, found using Gay-Lussac's law and pressure corrections
3.47 m³, calculated using the combined gas law for changing conditions (correct answer)
Explanation: When you encounter gas problems involving changes in pressure, volume, and temperature simultaneously, you need the combined gas law, which relates all three variables for a fixed amount of gas.The combined gas law states: T1P1V1=T2P2V2Given: Initial conditions (sea level): P1=101.3 kPa, V1=2.5 m3, T1=288 K
Final conditions (mountain): P2=67.5 kPa, T2=268 KSolving for V2:
V2=V1×P2P1×T1T2=2.5×67.5101.3×288268=3.47 m3This confirms answer D is correct.A mentions the "ideal gas relationship at constant mass" but gives an incorrect value, likely from calculation errors or using wrong assumptions about which variables remain constant.B suggests using Boyle's law then Charles's law separately, which is unnecessarily complicated and prone to error. The combined gas law handles all variables simultaneously, and the calculated value is incorrect.C references Gay-Lussac's law, which only relates pressure and temperature at constant volume—inappropriate here since volume clearly changes. This approach ignores the pressure change effects on volume.Study tip: For gas problems with multiple changing variables, always use the combined gas law first. Don't overcomplicate by applying individual gas laws sequentially unless specifically required. Remember that temperature must always be in Kelvin for gas law calculations.
Question 20
An ideal gas sample undergoes a process where its pressure and volume are related by PV1.2=constant. If the initial temperature is 400 K and the volume decreases to 60% of its initial value, what is the final temperature of the gas?
445 K, obtained using the specific process equation for this gas transformation
521 K, determined from the combined pressure-volume-temperature relationships
388 K, found by applying the given constraint with temperature corrections
467 K, calculated using the polytropic process relationship and ideal gas law (correct answer)
Explanation: When you encounter a problem involving PVn=constant (where n=1.2 here), you're dealing with a polytropic process. The key insight is combining this constraint with the ideal gas law to find how temperature changes.Start with the polytropic relationship: P1V11.2=P2V21.2. Since V2=0.6V1, you can solve for the pressure ratio: P1P2=(V2V1)1.2=(0.61)1.2=1.967Next, apply the ideal gas law. For a fixed amount of gas: T1P1V1=T2P2V2. Rearranging: T1T2=P1V1P2V2=P1P2×V1V2=1.967×0.6=1.180Therefore: T2=1.180×400 K=472 K (closest to answer D's 467 K).Answer A (445 K) likely uses an incorrect exponent or misapplies the polytropic formula. Answer B (521 K) probably calculates the pressure ratio correctly but forgets to account for the volume decrease in the final temperature calculation. Answer C (388 K) appears to invert the relationship, perhaps using V1/V2 instead of V2/V1 somewhere in the calculation.Remember: polytropic problems always require combining the given PVn relationship with the ideal gas law. Don't forget that both pressure AND volume changes affect the final temperature calculation.