Physical Chemistry 2 Quiz
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STATISTICAL THERMODYNAMICS
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A quantum system has equally spaced energy levels En=nℏωE_n = n\hbar\omega for n=0,1,2,...n = 0, 1, 2, ... The partition function at temperature TT is q=11−e−ℏω/kBTq = \frac{1}{1-e^{-\hbar\omega/k_BT}}. If a constant energy E0E_0 is added to all levels, making them En=E0+nℏωE_n = E_0 + n\hbar\omega, how does the heat capacity change?
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