Organic Chemistry 1 Quiz
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MECHANISMS & REACTION FUNDAMENTALS
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The primary thermodynamic driving force for a 1,2-hydride or 1,2-alkyl shift in a carbocation is which of the following?
A
The relief of steric strain in the transition state of the shift.
B
The formation of a thermodynamically more stable carbocation intermediate.
C
An increase in entropy by breaking a C-C or C-H bond.
D
The requirement to achieve an anti-periplanar geometry for the subsequent step.
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