SECTION 1
Historical Context & Motivation
At the end of the nineteenth century, scientists believed that atoms were permanent, indivisible building blocks of matter. That view shattered in a single decade when researchers discovered that certain elements spontaneously emit invisible radiation. The phenomenon — radioactive decay — revealed that atomic nuclei can be unstable and will transform into entirely different elements over time. Understanding this process became essential not only for physics but also for medicine, archaeology, energy production, and environmental science.
1896 • Becquerel's Discovery
1898 • The Curies Isolate Radium
1903 • Rutherford Classifies Radiation
1907 • Half-Life Concept Formalised
1949 • Carbon-14 Dating
The central question that emerged from these discoveries was this: if nuclei decay at random, how can we make precise, reliable predictions about the amount of material remaining after a given time? The answer lies in the mathematics of exponential decay and the statistical nature of large populations of atoms. In IB Physics section E.3, you will learn to apply these tools to solve problems involving half-life, decay constant, and activity.
SECTION 2
Core Principles of Radioactive Decay
Radioactive decay is governed by a handful of powerful ideas. Each one helps explain why decay is predictable for large samples even though the behaviour of any single nucleus is completely random. These principles form the foundation for every calculation in this topic.
Random & Spontaneous
Half-Life (t₁/₂)
Decay Constant (λ)
Activity (A)
Exponential Decay Law
KEY TAKEAWAY
SECTION 3
Visualising Exponential Decay
The graph below shows how the number of undecayed nuclei (N) changes over time (t) for a radioactive sample. Notice how the curve never actually reaches zero — it just keeps halving. Each successive half-life reduces the remaining sample by another 50%.
The key feature of this graph is its shape: a smooth curve that drops steeply at first and then flattens out. This is characteristic of all exponential decay processes. The rate of decay is fastest when there are the most undecayed nuclei, and it slows down as fewer remain. Importantly, no matter how long you wait, the curve never reaches exactly zero — there is always some fraction remaining, though it becomes negligibly small after many half-lives.
SECTION 4
Mathematical Framework
The IB E.3 syllabus requires you to apply several interconnected equations. Each connects the number of undecayed nuclei, time, decay constant, and activity. Let's build them step by step.
EXPONENTIAL DECAY LAW
N = number of undecayed nuclei at time t; N₀ = initial number of nuclei; λ = decay constant (s−1); t = elapsed time (s); e ≈ 2.718 (Euler's number).
HALF-LIFE AND DECAY CONSTANT
t₁/₂ = half-life; ln 2 ≈ 0.693. This equation lets you convert between the half-life (easy to measure) and the decay constant (useful in calculations).
ACTIVITY
A = activity at time t (Bq); A₀ = initial activity; λ = decay constant; N = number of undecayed nuclei at time t. Since A is proportional to N, activity also decays exponentially.
HALF-LIFE SHORTCUT
This equivalent form avoids the exponential function. It is especially handy when the elapsed time is a whole number of half-lives, because you simply halve repeatedly.
IB Exam Tip
SECTION 5
Types of Radioactive Decay
When a nucleus decays, it emits one of several types of radiation. Understanding the differences matters for writing balanced nuclear equations and for predicting the resulting daughter nucleus. The diagram below summarises the three main types of decay and their effects on the nucleus.
| Property | Alpha (α) | Beta-minus (β⁻) | Gamma (γ) |
|---|---|---|---|
| Particle emitted | ⁴₂He nucleus | Electron (e⁻) + antineutrino | High-energy photon |
| Change in A (mass no.) | −4 | 0 | 0 |
| Change in Z (atomic no.) | −2 | +1 | 0 |
| Ionising power | Highest | Moderate | Lowest |
| Penetrating power | Lowest (paper) | Moderate (aluminium) | Highest (thick lead) |
Summary of the three main types of radioactive decay
SECTION 6
Worked Example — Half-Life Calculation
A sample of iodine-131 (used in thyroid treatment) has an initial activity of 8.0 × 10⁵ Bq. The half-life of iodine-131 is 8.02 days. Determine: (a) the decay constant λ, (b) the activity after 24 days, and (c) the time for the activity to drop to 1.0 × 10⁵ Bq.
Iodine-131 Decay Calculation
- 1
Step 1 — Identify Given Values
A₀ = 8.0 × 10⁵ Bq, t₁/₂ = 8.02 days. Convert the half-life to seconds for SI consistency if needed, but since the IB often works in convenient time units, we'll keep days here. - 2
Step 2 — Calculate the Decay Constant λ
Using the relation λ = ln 2 / t₁/₂: λ = 0.693 / 8.02 daysλ ≈ 0.0864 day⁻¹ - 3
Step 3 — Find Activity After 24 Days (Part b)
Apply A = A₀ × : A = 8.0 × 10⁵ × A = 8.0 × 10⁵ × A = 8.0 × 10⁵ × 0.1257A ≈ 1.0 × 10⁵ Bq - 4
Step 3 — Alternative Shortcut Check
24 days ÷ 8.02 days ≈ 3 half-lives. After 3 half-lives, the fraction remaining is (½)³ = ⅛. So A = 8.0 × 10⁵ × ⅛ = 1.0 × 10⁵ Bq. This confirms our exponential result. - 5
Step 4 — Find Time to Reach 1.0 × 10⁵ Bq (Part c)
Rearrange A = A₀ × for t: t = −ln(A / A₀) / λ t = −ln(1.0 × 10⁵ / 8.0 × 10⁵) / 0.0864 t = −ln(0.125) / 0.0864 t = 2.079 / 0.0864t ≈ 24.1 days (≈ 3 half-lives)
Strategy Note
SECTION 7
Strengths & Limitations of Decay Models
The exponential decay model is remarkably powerful, but like all models in physics it has both strengths and limitations. Understanding these will help you interpret exam questions correctly and avoid common mistakes.
| Strengths | Limitations |
|---|---|
| Accurately predicts average behaviour for large samples (billions of nuclei). | Cannot predict when a single specific nucleus will decay. |
| Half-life is constant and independent of external conditions (temperature, pressure, chemical bonding). | The continuous exponential model breaks down for very small numbers of nuclei, where statistical fluctuations dominate. |
| Simple mathematics (exponentials and logarithms) allow precise calculations. | Does not account for decay chains — the daughter nucleus may also be radioactive and decay further. |
| Widely applicable: medical imaging, carbon dating, nuclear power, geology. | Assumes a pure sample of one isotope; mixtures require summing multiple exponentials. |
Strengths and limitations of the simple exponential decay model
KEY TAKEAWAY
SECTION 8
Connections to Advanced Theory
The E.3 treatment of radioactive decay uses a semi-classical, statistical approach. At university level and in the IB HL extensions, these ideas connect to deeper physics. The table below maps what you know now to where these ideas lead.
| E.3 Concept (What You Know) | Advanced Extension |
|---|---|
| Half-life is a fixed property of each isotope. | Quantum tunnelling probability determines the half-life; heavier alpha particles must tunnel through a Coulomb barrier whose width depends on nuclear structure. |
| N = N₀ × assumes a single-step decay. | Decay chains (e.g., uranium-238 → radon-222 → polonium-218 → …) require solving coupled differential equations (Bateman equations). |
| Activity measured in becquerels (Bq). | Dose concepts (Gray, Sievert) weight activity by radiation type and tissue sensitivity for biological risk assessment. |
| Beta decay emits an electron and antineutrino. | The weak nuclear force mediates beta decay via W boson exchange — a key prediction of the electroweak theory. |
From E.3 to advanced nuclear physics
Even though these advanced topics are beyond the scope of the IB exam, knowing they exist can deepen your understanding. For instance, if a question asks why some nuclei have very long half-lives while others decay almost instantly, the answer lies in the quantum tunnelling probability — the thicker or higher the energy barrier, the less likely a particle is to escape the nucleus, and the longer the half-life.
SECTION 9
Practice Problems
Question 1: CONCEPTUAL
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Question 2: BASIC CALCULATION
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Question 3: INTERMEDIATE
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Question 4: APPLIED
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Question 5: CRITICAL THINKING
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SUMMARY
Summary — Radioactive Decay (E.3)
Summary
Radioactive decay is a random, spontaneous process in which unstable nuclei transform by emitting alpha particles, beta particles, or gamma rays. The number of undecayed nuclei follows the exponential decay law N = N₀ × , where λ (decay constant) is linked to the half-life by t₁/₂ = ln 2 / λ. The activity A = λN also decays exponentially and is measured in becquerels.
To solve IB problems, choose the appropriate equation, substitute known values, and rearrange for the unknown. Use the half-life shortcut N = N₀ × (½)ⁿ when time is a whole number of half-lives. Remember that the model applies to large populations of nuclei and cannot predict the behaviour of any single nucleus. Applications range from carbon dating and medical imaging to nuclear waste management.